scholarly journals Temperature sensing and actuating capabilities of polymeric shape memory composite containing thermochromic particles

2015 ◽  
Vol 44 (4) ◽  
pp. 224-231 ◽  
Author(s):  
Haibao Lu ◽  
Yongtao Yao ◽  
Long Lin
Keyword(s):  
Shape Memory ◽  
Information Dissemination ◽  
Shape Memory Polymer ◽  
Thermomechanical Properties ◽  
Temperature Sensing ◽  
Content Type ◽  
Thermally Responsive ◽  
Shape Memory Composites ◽  
Potential Applications ◽  
Shape Memory Composite

Purpose – This paper aims to create and to study multifunctional shape memory polymer (SMP) composites having temperature-sensing and actuating capabilities by embedding thermochromic particles within the polymer matrix. Design/methodology/approach – The multifunctional materials were fabricated following a process consisting of blending (of the thermochromic particles and the SMP at various ratios), mixing, degasing, moulding and thermal curing, prepared by incorporating thermochromic particles within the polymer. The effect of the thermochromic particles on the thermomechanical properties and thermally responsive shape memory effect of the resulting multifunction SMP composites were characterised and interpreted. Findings – It was found that exposure of the composites to temperatures above 70°C led to a pronounced change of their colour that was recorded by the thermal and electrical actuation approaches and was reproducibly reversible. It was also found that the colour of the composites was independent of the mechanical state of the SMP. Such effects enabled monitoring of the onset of the set/release temperature of the SMP matrix. Furthermore, the combination of thermochromic additive and the SMP resulted in significantly improved thermomechanical strength, absorption of infrared radiation and the temperature distribution of the SMP composites. Research limitations/implications – The temperature-sensing and actuating capabilities of the polymeric shape memory composites developed through this study will help to extend the field of potential applications of such composites to fields including sensors, actuators, security labels and information dissemination, where colour indication is an advantageous feature. Originality/value – The SMP composites capable of temperature sensing and actuating are novel.

scholarly journals Thermomechanical performance and shape recovery behaviour of shape memory polymer nanocomposite incorporated with hexagonal boron nitride

2017 ◽  
Vol 46 (1) ◽  
pp. 79-83 ◽  
Author(s):  
Zhenghong Li ◽  
Haibao Lu ◽  
Yongtao Yao ◽  
Long Lin
Keyword(s):  
Thermal Conductivity ◽  
Shape Memory ◽  
Shape Recovery ◽  
Hexagonal Boron Nitride ◽  
Shape Memory Polymer ◽  
Polymer Nanocomposite ◽  
Thermomechanical Properties ◽  
Content Type ◽  
Thermally Responsive ◽  
Thermally Actuated

Purpose The purpose of this paper is to develop an effective approach to significantly improve the thermomechanical properties of shape memory polymer (SMP) nanocomposites that show fast thermally responsive shape recovery. Design/methodology/approach Hexagonal boron nitrides (h-BNs) were incorporated into polymer matrix in an attempt to improve the thermal conductivity and thermally responsive shape recovery behaviour of SMP, respectively. Thermally actuated shape recovery behaviour was recorded and monitored instrumentally. Findings The results show that both glass transition temperature (Tg) and thermomechanical properties of the SMP nanocomposites have been progressively improved with increasing concentration of h-BNs. Analytical results also suggest that the fast-responsive recovery behaviour of the SMP nanocomposite incorporated with h-BNs was due to the increased thermal conductivity. Research limitations/implications A simple way for fabricating SMP nanocomposites with enhanced thermally responsive shape recovery based on the incorporation of h-BNs was developed. Originality/value The outcome of this study may help fabrication of SMP nanocomposites with fast responsive recovery behaviour.

Characristics of Shape Memory Composites Combined with Shape Memory Alloy and Shape Memory Polymer

2013 ◽  
Vol 705 ◽  
pp. 169-172
Author(s):  
Xue Feng ◽  
Li Min Zhao ◽  
Xu Jun Mi
Keyword(s):  
Shape Memory ◽  
Room Temperature ◽  
Shape Recovery ◽  
Volume Fraction ◽  
Shape Memory Polymer ◽  
Young Modulus ◽  
Thermomechanical Properties ◽  
The Matrix ◽  
Shape Memory Composites ◽  
Shape Fixity

In order to develop high functionality of shape memory materials, the shape memory composites combined with TiNi wire and shape memory epoxy were prepared, and the mechanical and thermomechanical properties were studied. The results showed the addition of TiNi wire increased the Young modulus and breaking strength both at room temperature and at elevated temperature. The composites maintained the rates of shape fixity and shape recovery close to 100%. The maximum recovery stress increased with increasing TiNi wire volume fraction, and obtained almost 3 times of the matrix by adding 1vol% TiNi wire.

4D-printed parametric façade in architecture: prototyping a self-shaping skin using programmable two-way shape memory composite (TWSMC)

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Hwang Yi
Keyword(s):  
Shape Memory ◽  
Parametric Design ◽  
Shape Memory Polymer ◽  
Design Procedure ◽  
Building Design ◽  
Scale Model ◽  
Optimal Arrangement ◽  
Content Type ◽  
Physical Scale ◽  
Shape Memory Composite

PurposeThis study aims to present an architectural application of 4D-printed climate-adaptive kinetic architecture and parametric façade design.Design/methodology/approachThis work investigates experimental prototyping of a reversibly self-shaping façade, by integrating the parametric design approach, smart material and 4D-printing techniques. Thermo-responsive building skin modules of two-way shape memory composite (TWSMC) was designed and fabricated, combining the shape memory alloy fibers (SMFs) and 3D-printed shape memory polymer matrices (SMPMs). For geometry design, deformation of the TWSMC was simulated with a dimension-reduced mathematical model, and an optimal arrangement of three different types of TWSMC modules were designed and fabricated into a physical scale model.FindingsModel-based experiments show robust workability and formal reversibility of the developed façade. Potential utility of this module for adaptive building design and construction is discussed based on the results. Findings help better understand the shape memory phenomena and presented design-inclusive technology will benefit architectural communities of smart climate-adaptive building.Originality/valueTwo-way reversibility of 4D-printed composites is a topic of active research in material science but has not been clearly addressed in the practical context of architectural design, due to technical barriers. This research is the first architectural presentation of the whole design procedure, simulation and fabrication of the 4D-printed and parametrically movable façade.

Technology and application of shape memory polymers in textiles

2017 ◽  
Vol 21 (2) ◽  
pp. 86-100 ◽  
Author(s):  
J.N. Chakraborty ◽  
Priyanka Kumari Dhaka ◽  
Akshit Vikram Sethi ◽  
Md Arif
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymers ◽  
Physical Nature ◽  
Wool Fabric ◽  
Limited Information ◽  
Magnetic Shape Memory ◽  
Specific Stimulus ◽  
Content Type ◽  
Thermally Responsive ◽  
Shape Memory Composites

Purpose Shape memory polymers (SMPs) respond with a change in their shape against a specific stimulus by memorizing their original shape and are reformed after deformation most often by changing the temperature of the surrounding without additional mechanical efforts. In the coming years, these polymers indeed will be in limelight to manufacture textile materials which will retain their shape even after prolonged use under disturbed conditions. This study aims at defining shape memory materials and polymers as well as their technological characteristics and also highlights application in various fields of textiles. Design/methodology/approach The methodology used to explain these SMPs have been carried out starting with the discussion on their properties, their physical nature, types, viz., shape memory alloys (SMAs), shape memory ceramics, shape memory hybrid, magnetic shape memory alloy, shape memory composites, shape memory gels and SMP along with properties of each type. Other related details of these polymers, such as their advantages, structure and mechanism, shape memory functionality, thermally responsive SMPs and applications, have been detailed. Findings It has been observed that the SMPs are very important in the fields of wet and melt-spun fibers to offer novel and functional properties, cotton and wool fabric finishing, to produce SMP films, foams and laminated textiles, water vapor permeable and breathable SMP films, etc. Originality/value The field of SMPs is new, and very limited information is available to enable their smooth production and handling.

scholarly journals Fabrication of free-standing octagon-shaped carbon nanofibre assembly for electrical actuation of shape memory polymer nanocomposites

2015 ◽  
Vol 44 (3) ◽  
pp. 157-164 ◽  
Author(s):  
Haibao Lu ◽  
Yongtao Yao ◽  
Shipeng Zhu ◽  
Yunhua Yang ◽  
Long Lin
Keyword(s):  
Shape Memory ◽  
Composite Laminates ◽  
Shape Memory Polymer ◽  
Thermomechanical Properties ◽  
Structure Design ◽  
Free Standing ◽  
Electric Voltage ◽  
Filtration Method ◽  
Content Type ◽  
Carbon Nanofibre

Purpose – The purpose of this paper is a study aimed at overcoming the interface issue between nanopaper and polymer matrix in shape-memory polymer (SMP) composite laminates caused by their large dissimilarity in electrical/thermal conductive properties. The study attempted to develop an effective approach to fabricate free-standing carbon nanofibre (CNF) assembly in octagon shape formation. The structure design and thermal conductive performance of the resulting octagon-shaped CNF assembly were optimised and simulated. Design/methodology/approach – The CNF nanopaper was prepared based on a filtration method. The SMP nanocomposites were fabricated by incorporating these CNF assemblies with epoxy-based SMP resin by a resin-transfer modelling technique. Thermal conductivity of the octagon-shaped CNF assembly was simulated using the ANSYS FLUENT software for structure design and optimisation. The effect of the octagon-shaped CNF on the thermomechanical properties and thermally responsive shape-memory effect of the resulting SMP nanocomposites were characterised and interpreted. Findings – The CNF template incorporated with SMP to achieve Joule heating triggered shape recovery at a low electric voltage of 3-10 V, due to which the electrical resistivity of SMP nanocomposites was significantly improved and lowered to 0.20 O·cm by the CNF template. It was found that the octagon CNF template with 2 mm width of skeleton presented a highest thermally conductive performance to transfer resistive heat to the SMP matrix. Research limitations/implications – A simple way for fabricating electro-activated SMP nanocomposites has been developed by using an octagon CNF template. Low electrical voltage actuation in SMP has been achieved. Originality/value – The fabricated CNF template, the structure design and analysis of dynamic thermomechanical properties of SMP are novel.

An investigation on electro-induced shape memory performances of CE/EP/CB/SCF composites applied for deployable structure

2020 ◽  
Vol 40 (3) ◽  
pp. 203-210 ◽  
Author(s):  
Tianning Ren ◽  
Guangming Zhu ◽  
Yi Liu ◽  
Xiao Hou
Keyword(s):  
Carbon Black ◽  
Shape Memory ◽  
Memory Performance ◽  
Shape Memory Polymer ◽  
Content Increase ◽  
Deployable Structure ◽  
Shape Memory Properties ◽  
Shape Memory Composites ◽  
Shape Memory Composite ◽  
Short Carbon

AbstractThe objective of this work is to investigate the thermomechanical, electrical, and shape-memory properties of bisphenol A-type cyanate ester (BACE)/polybutadiene epoxy (PBEP)/carbon black (CB) composite and assess its feasibility applied for deployable structure. Using a BACE/PBEP polymer as matrix and superconducting carbon black (CB) and short carbon fibers (SCFs) as reinforcing material, the shape memory composite was prepared by compression molding. The effects of CB and SCF content on the shape memory properties of the composites were investigated. The results demonstrate that the glass transition temperature (Tg) and the storage modulus of the composites increases as SCFs content increase. Because of the synergic effect of CB and SCFs, the shape memory composites exhibit excellent shape memory performance, and the shape recovery ratio is about 100%. With the increase in SCF content, the recovery time decreased, and the volume electrical resistivity of the composite could decrease by adding a small amount of SCFs. According to the above results, a shape memory polymer composite deployable structure was prepared.

Investigate of Electrical Conductivity of Shape-Memory Polymer Filled with Carbon Black

2008 ◽  
Vol 47-50 ◽  
pp. 714-717 ◽  
Author(s):  
Xin Lan ◽  
Jin Song Leng ◽  
Yan Ju Liu ◽  
Shan Yi Du
Keyword(s):  
Electrical Conductivity ◽  
Carbon Black ◽  
Shape Memory ◽  
Shape Recovery ◽  
Volume Fraction ◽  
Shape Memory Polymer ◽  
Recovery Process ◽  
Thermomechanical Properties ◽  
Electrically Conductive ◽  
New System

A new system of thermoset styrene-based shape-memory polymer (SMP) filled with carbon black (CB) is investigated. To realize the electroactive stimuli of SMP, the electrical conductivity of SMP filled with various amounts of CB is characterized. The percolation threshold of electrically conductive SMP filled with CB is about 3% (volume fraction of CB), which is much lower than many other electrically conductive polymers. When applying a voltage of 30V, the shape recovery process of SMP/CB(10 vol%) can be realized in about 100s. In addition, the thermomechanical properties are also characterized by differential scanning calorimetery (DSC).

Thermomechanical properties of shape memory polymer subjected to tension in various conditions

2009 ◽  
Vol 6 (2) ◽  
pp. 189-205 ◽  
Author(s):  
Elzbieta A. Pieczyska ◽  
Wojciech K. Nowacki ◽  
Hisaaki Tobushi ◽  
Shunichi Hayashi
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Thermomechanical Properties

Modeling size-dependent thermal-mechanical behaviors of shape memory polymer Timoshenko micro-beam

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Fei Zhao ◽  
Xueyao Zheng ◽  
Shichen Zhou ◽  
Bo Zhou ◽  
Shifeng Xue
Keyword(s):  
Size Effect ◽  
Shape Memory ◽  
Couple Stress Theory ◽  
Shape Memory Polymer ◽  
Modified Couple Stress Theory ◽  
Mechanical Behaviors ◽  
Equilibrium Equations ◽  
Content Type ◽  
Size Dependent ◽  
Beam Height

PurposeIn this paper, a three-dimensional size-dependent constitutive model of SMP Timoshenko micro-beam is developed to describe the micromechanical properties.Design/methodology/approachAccording to the Hamilton's principle, the equilibrium equations and boundary conditions of the model are established and according to the modified couple stress theory, the model is available to capturing the size effect because of the material length scale parameter. Based on the model, the simply supported beam was taken for example to be solved and simulated.FindingsResults show that the size effect of SMP micro-beam is more obvious when the dimensionless beam height is similar or the larger of the value of loading time. The rigidity and strength of the SMP beam decrease with the increasing of the dimensionless beam height or the loading time. The viscous property of SMP micro-beam plays a more important role with the larger dimensionless beam height. And the smaller the dimensionless beam height is, the more obvious the shape memory effect of the SMP micro-beam is.Originality/valueThis work implies prediction of size-dependent thermo-mechanical behaviors of the SMP micro-beam and will provide a theoretical basis for design SMP microstructures in the field of micro/nanomechanics.

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