scholarly journals The influence of temperature and charge-discharge rate on open circuit voltage hysteresis of an LFP Li-ion battery

Author(s):  
Anup Barai ◽  
W. Dhammika Widanage ◽  
Andrew McGordon ◽  
Paul Jennings
2021 ◽  
Vol 896 ◽  
pp. 53-59
Author(s):  
Yi Yang Shen

The development of next generation Li ion battery has attracted many attentions of researchers due to the rapidly increasing demands to portable energy storage devices. General Li metal/alloy anodes are confronted with challenges of dendritic crystal formation and slow charge/discharge rate. Recently, the prosperity of two-dimensional materials opens a new window for the design of battery anode. In the present study, MoS2/graphene heterostructure is investigate for the anode application of Li ion battery using first-principles calculations. The Li binding energy, open-circuit voltage, and electronic band structures are acquired for various Li concentrations. We found the open-circuit voltage decreases from ~2.28 to ~0.4 V for concentration from 0 to 1. Density of states show the electrical conductivity of the intercalated heterostructures can be significantly enhanced. The charge density differences are used to explain the variations of voltage and density of states. Last, ~0.43 eV diffusion energy barrier of Li implies the possible fast charge/discharge rate. Our study indicate MoS2/graphene heterostructure is promising material as Li ion battery anode.


Author(s):  
Venkata Nagarjun PM ◽  
Hirshik Ram S ◽  
Pratik Uthan ◽  
Veeramani V ◽  
Senthilkumar Subramaniam

2019 ◽  
Vol 128 ◽  
pp. 01022
Author(s):  
Tanilay Özdemir ◽  
Ali Amini ◽  
Özgür Ekici ◽  
Murat Köksal

In this study, an axisymmetric computational lumped model is used to investigate the thermal and electrical behavior of a cylindrical Lithium-ion (Li–ion) battery during various discharging processes at 0-20-50°C operating temperatures. A typical cylindrical Li–ion cell consists ofmultiple spiral layers, on the other hand, the model employs the lumped battery interface approach in COMSOL Multiphysics to reduce the computational effort. In the lumped approach, layers of different materials are approximated as a uniform material with effective properties. Among other parameters, the Open Circuit Voltage (OCV) as a function of the State of Charge (SOC) is determined experimentally andused as input to the model. The model is then used to analyze the effects of the correlations of various parameters on the transient electrical and thermal responses of the battery and validated by comparing predicted results with experimental data.


Author(s):  
Xiuling Wang

Abstract Li-ion battery is becoming a popular energy storage device in Hybrid Electric Vehicles (HEV) and Electric Vehicles (EV) due to its high energy density, high voltage and low self-discharge rate. The major concerns in designing Li-ion batteries are their life, performance and safety, which have close relations to their thermal behaviors. The temperature of Li-ion batteries rises during charge/discharge process. It goes faster especially with high charge/discharge rate during fast charging procedure. In this research, CFD models are developed based on ANSYS/FLUENT MSMD battery model coupled with electrochemical submodel-Newman, Tiedeman, Gu and Kim (NTGK) empirical model. Detailed simulation results are obtained in battery thermal and electrochemical behavior for different bi-cell electrode and current collector tab configurations. The temperature, potential, current density distribution at the battery length scale are determined, temperature gradient distribution is computed, and the maximum temperature at different discharge rate are also compared. The thermal investigation can provide valuable input for Li-ion battery design and analysis, especially for fast-charging batteries where heat distribution and cooling is critical for the battery design.


Author(s):  
Puspita Ningrum ◽  
Novie Ayub Windarko ◽  
Suhariningsih Suhariningsih

Abstract— Battery is one of the important components in the development of renewable energy technology. This paper presents a method for estimating the State of Charge (SoC) for a 4Ah Li-ion battery. State of Charge (SoC) is the status of the capacity in the battery in the form of a percentage which makes it easier to monitor the battery during use. Coulomb calculations are widely used, but this method still contains errors during integration. In this paper, SoC measurement using Open Circuit Voltage Compensation is used for the determination of the initial SoC, so that the initial SoC reading is more precise, because if the initial SoC reading only uses a voltage sensor, the initial SoC reading is less precise which affects the next n second SoC reading. In this paper, we present a battery management system design or commonly known as BMS (Battery Management System) which focuses on the monitoring function. BMS uses a voltage sensor in the form of a voltage divider circuit and an ACS 712 current sensor to send information about the battery condition to the microcontroller as the control center. Besides, BMS is equipped with a protection relay to protect the battery. The estimation results of the 12volt 4Ah Li-ion battery SoC with the actual reading show an error of less than 1%.Keywords—Battery Management System, Modified Coulomb Counting, State of Charge.


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