Magnetic moments and curie temperatures of (Fe, Ni)<inf>80</inf>(P, B)<inf>20</inf>amorphous alloys

1977 ◽  
Vol 13 (3) ◽  
pp. 988-991 ◽  
Author(s):  
J. Becker ◽  
F. Luborsky ◽  
J. Walter
1986 ◽  
Vol 28 (1-4) ◽  
pp. 499-502 ◽  
Author(s):  
P. Deppe ◽  
A. Kowalski ◽  
M. Rosenberg ◽  
K. Fukamichi

1975 ◽  
Vol 30 (5) ◽  
pp. 645-655
Author(s):  
Peter Brill

Abstract The paramagnetic susceptibility of four PdAgFe alloy series containing 1, 3, 5 and 7 at. % Fe have been measured between 20° and 150 °C. On the basis of a band filling model the local moment contribution to the susceptibility has been evaluated according to a Curie -Weiss law. Assuming that the iron atoms donate 3 electrons and the silver atoms 1 electron to the Pd 4d band, the effective magnetic moments and the paramagnetic Curie temperatures of all the alloys can be represented by a single curve against the electron concentration. The effective magnetic moment is consistent with an Fe moment of 5.92 μB localized on the iron sites and a Pd moment varying with electron concentration and temperature. The same turns out to be true for the ferromagnetic region where the saturation moment, obtained on PdFe alloys and a PdAgFe alloy by different authors, is considered to arise from a localized Fe moment of 5 μB and a concentration dependent Pd moment. The molecular field coefficient for the interaction between the Fe moments and the Pd 4d electrons is found to be 850 mol/cm3 at 385 K and 1200 mol/cm3 at 0 K. Finally, the iron moment suggested in this work is contrasted with the moment derived from neutron diffraction measurements.


2003 ◽  
Vol 58 (6) ◽  
pp. 497-500 ◽  
Author(s):  
Gunter Kotzybaa ◽  
Ratikanta Mishrab ◽  
Rainer Pöttgena

The Mo2FeB2 type magnesium intermetallics RE2Cu2Mg (RE = Y, La, Pr, Nd) were synthesized from the elements by reactions in sealed tantalum tubes in a high-frequency furnace. Temperature-dependent magnetic susceptibility measurements of Y2Cu2Mg and La2Cu2Mg indicate Pauli paramagnetism. Pr2Cu2Mg and Nd2Cu2Mg show Curie-Weiss behaviour with experimental magnetic moments of 3.67(2) μB/Pr and 3.47(2) μB/Nd, respectively. Both compounds are ordered ferromagnetically at Curie temperatures of 12.0(5) (Pr2Cu2Mg) and 43.0(5) K (Nd2Cu2Mg). Pr2Cu2Mg shows a very complex magnetization behavior with an additional magnetic transition around 2.5 T. The neodymium compound shows a pronounced square loop behavior in the magnetization at 4.5 K with a high remanent magnetization of 1.55(1) μB/Nd atom and a coercive field of 0.31(1) T.


1970 ◽  
Vol 48 (23) ◽  
pp. 2857-2867 ◽  
Author(s):  
A. Rosencwaig

A statistical model based on the concept of localized canting, originally proposed by Geller and coworkers, is developed to account for the magnetic properties of substituted ferrimagnets. This model is used to determine the exchange parameter ratios Jdd/Jdd and Jaa/Jad in YIG systems by evaluating the magnetic moments and Curie temperatures of two classes of singly substituted YIG over the entire substitution range. Good agreement with experimental data is obtained with the physically reasonable exchange parameter ratios of [Formula: see text] and Jaa/Jad *~ 0.07. It is also shown that both the Yafet-Kittel and the Nowik models may be regarded as particular limiting cases of the new model.


2003 ◽  
Vol 17 (05n06) ◽  
pp. 235-244
Author(s):  
V. SIMON ◽  
R. POP ◽  
N. N. PUŞCAŞ

Results concerning the structural, optical and magnetic properties of x Fe 2 O 3 · (100 - x)[3 Bi 2 O 3 · 2 PbO ] glasses (0 = x = 20 mol%) are reported. The transparence in the infrared range was investigated. The homogeneous absorption cross section was determined from the optical absorption spectra using the density matrix formalism of the McCumber theoretical model. From the temperature dependence of reciprocal magnetic susceptibility, negative paramagnetic Curie temperatures have been found suggesting the antiferromagnetic nature of the magnetic interaction between the iron ions in the studied samples. The iron ions occur both in the (II) and (III) valence state. The Fe 2+/ Fe 3+ ratio was determined from the experimental values of the magnetic moments for all samples. The glass transition temperature with increasing Fe 2 O 3 content was also investigated.


2019 ◽  
Vol 61 (3) ◽  
pp. 472
Author(s):  
В.Г. Плещев ◽  
Н.В. Селезнева

AbstractThis is a pioneering work on the synthesis of molybdenum diselenides intercalated by chromium atoms. Their magnetic properties are studied at various intercalant concentrations, temperatures, and magnetic fields. The temperature dependences of effective magnetic moments and positive paramagnetic Curie temperatures in the paramagnetic region evidence the feasible ferromagnetic interactions between intercalated atoms. The existence of low-temperature ferromagnetic state in Cr_ x МоSe_2 is confirmed by hysteresis phenomena in temperature and field dependences of magnetization and magnetic susceptibility.


Author(s):  
O.K. Kuvandikov ◽  
◽  
N.I. Leonyuk ◽  
V.V. Malsev ◽  
M.M. Kuzmin ◽  
...  

Temperature dependence of the magnetic susceptibility has been studied for rare-earth borates NdCr3(BO3)4, SmCr3(BO3)4 and LuCr3(BO3)4 by the Faradey method in the wide temperature range (300-1200 K). The dependence for each phase follows the Curi - Weis law. The Curie temperatures, Neel temperatures and magnetic moments corresponding to the chemical formula of the crystals, have been found.


2006 ◽  
Vol 20 (26) ◽  
pp. 1677-1683
Author(s):  
P. LUCACI ◽  
E. CULEA

Magnetic behavior and structural data of the U(T x Al 1-x)2 compounds, where T = Co, Ni and Mn , were reported. Magnetic measurements were performed in the temperature range 4.2–800 K and magnetic fields up to 7 T. The gradual replacement of Al by Co , Ni and Mn ions leads to the decrease of the effective magnetic moments per uranium ion, and of the paramagnetic Curie temperatures in absolute magnitude. This composition evolution of the two magnetic parameters of the U(T x Al 1-x)2 compounds suggests a gradual suppression of the spin fluctuations with replacing the Al ions by T ions.


Author(s):  
Joachim Barth ◽  
Gerhard H. Fecher ◽  
Benjamin Balke ◽  
Tanja Graf ◽  
Andrey Shkabko ◽  
...  

In this work, the theoretical and experimental investigations of Co 2 Ti Z ( Z =Si, Ge or Sn) compounds are reported. Half-metallic ferromagnetism is predicted for all three compounds with only two bands crossing the Fermi energy in the majority channel. The magnetic moments fulfil the Slater–Pauling rule and the Curie temperatures are well above room temperature. All compounds show a metallic-like resistivity for low temperatures up to their Curie temperature, above the resistivity changes to semiconducting-like behaviour. A large negative magnetoresistance (MR) of 55 per cent is observed for Co 2 TiSn at room temperature in an applied magnetic field of μ 0 H =4 T , which is comparable to the large negative MRs of the manganites. The Seebeck coefficients are negative for all three compounds and reach their maximum values at their respective Curie temperatures and stay almost constant up to 950 K. The highest value achieved is −52 μVK −1 for Co 2 TiSn, which is large for a metal. The combination of half-metallicity and the constant large Seebeck coefficient over a wide temperature range makes these compounds interesting materials for thermoelectric applications and further spincaloric investigations.


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