Platinum-group Mineral (PGM) and Base-metal Sulphide (BMS) Inclusions in Chromitites of the Zedang Ophiolite, Southern Tibet, China and their Petrogenetic Significance

AbstractAn intimate lithostratigraphic and lithodemic connection between syn-orogenic rock masses inside the different lithotectonic units of the 2.0–1.8 Ga (Svecokarelian) orogen, Sweden, is proposed. A repetitive cyclic tectonic evolution occurred during the time period c. 1.91–1.75 Ga, each cycle lasting about 50–55 million years. Volcanic rocks (c. 1.91–1.88 Ga) belonging to the earliest cycle are host to most of the base metal sulphide and Fe oxide deposits inside the orogen. Preservation of relict trails of continental magmatic arcs and intra-arc basins is inferred, with differences in the depth of basin deposition controlling, for example, contrasting types of base metal sulphide deposits along different trails. The segmented geometry of these continental magmatic arcs and intra-arc basins is related to strike-slip movement along ductile shear zones during transpressive events around and after 1.88 Ga; late orogenic folding also disturbed their orientation on a regional scale. A linear northwesterly orogenic trend is suggested prior to this structural overprint, the strike-slip movement being mainly parallel to the orogen. A solely accretionary orogenic model along an active margin to the continent Fennoscandia, without any trace of a terminal continent–continent collision, is preferred. Alternating retreating and advancing subduction modes that migrated progressively outboard and southwestwards in time account for the tectonic cycles.

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Nipalarsite, Ni8Pd3As4, a new platinum-group mineral from the Monchetundra Intrusion, Kola Peninsula, Russia

Mineralogical Magazine ◽

10.1180/mgm.2019.70 ◽

2019 ◽

Vol 83 (6) ◽

pp. 837-845 ◽

Cited By ~ 3

Author(s):

Tatiana L. Grokhovskaya ◽

Oxana V. Karimova ◽

Anna Vymazalová ◽

František Laufek ◽

Dmitry A. Chareev ◽

...

Keyword(s):

Kola Peninsula ◽

Empirical Formula ◽

Layered Intrusion ◽

Mean Value ◽

Platinum Group Mineral ◽

X Ray Diffraction ◽

Wavelength Dispersive Spectroscopy ◽

Group Mineral ◽

X Ray ◽

Platinum Group

AbstractNipalarsite, Ni8Pd3As4, is a new platinum-group mineral discovered in the sulfide-bearing orthopyroxenite of the Monchetundra layered intrusion, Kola Peninsula, Russia (67°52′22″N, 32°47′60″E). Nipalarsite forms anhedral grains (5–80 µm in size) in intergrowths with sperrylite, kotulskite, hollingworthite, isomertieite, menshikovite, palarstanide, nielsenite and monchetundtraite enclosed in pentlandite, anthophyllite, actinolite and chlorite. Nipalarsite is brittle, has a metallic lustre and a grey streak. In plane-polarised light, nipalarsite is light grey with a blue tinge. Reflectance values in air (in %) are: 46.06 at 470 nm, 48.74 at 546 nm, 50.64 at 589 nm and 54.12 at 650 nm. Values of VHN20 fall between 400.5 and 449.2 kg.mm–2, with a mean value of 429.9 kg.mm–2, corresponding to a Mohs hardness of ~4. The average result of 27 electron microprobe wavelength dispersive spectroscopy analyses of nipalarsite is (wt.%): Ni 44.011, Pd 28.74, Fe0.32, Cu 0.85, Pt 0.01, Au 0.05, As 25.42, Sb 0.05, Te 0.39, total 99.85. The empirical formula (normalised to 15 atoms per formula unit) is: (Ni8.10Fe0.06)Σ8.16(Pd2.94Cu0.18)Σ3.12(As3.68Te0.03)Σ3.71 or, ideally, Ni8Pd3As4. Nipalarsite is cubic, space group Fm$\bar{3}$m, with a = 11.4428(9) Å, V = 1498.3(4) Å3 and Z = 8. The strongest lines in the powder X-ray diffraction pattern of synthetic Ni8Pd3As4 [d, Å (I) (hkl)] are: 2.859(10)(004), 2.623(6)(313), 2.557(6)(024), 2.334(11)(224), 2.201(35)(115,333), 2.021(100)(044), 1.906(8)(006,244) and 1.429(7)(008). The crystal structure was solved and refined from the single-crystal X-ray diffraction data of synthetic Ni8Pd3As4. The relation between natural and synthetic nipalarsite is illustrated by an electron back-scattered diffraction study of natural nipalarsite. The density calculated on the basis of the empirical formula of nipalarsite is 9.60 g.cm–3. The mineral name corresponds to the three main elements: Ni, Pd and As.

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