Lake Ohrid’s tephrochronological dataset reveals 1.36 Ma of Mediterranean explosive volcanic activity

Tephrochronology relies on the availability of the stratigraphical, geochemical and geochronological datasets of volcanic deposits, three preconditions which are both often only fragmentary accessible. This study presents the tephrochronological dataset from the Lake Ohrid (Balkans) sediment succession continuously reaching back to 1.36 Ma. 57 tephra layers were investigated for their morphological appearance, geochemical fingerprint, and (chrono-)stratigraphic position. Glass fragments of tephra layers were analyzed for their major element composition using Energy-Dispersive-Spectroscopy and Wavelength-Dispersive Spectroscopy and for their trace element composition by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry. Radiometric dated equivalents of 16 tephra layers and orbital tuning of geochemical proxy data provided the basis for the age-depth model of the Lake Ohrid sediment succession. The age-depth model, in turn, provides ages for unknown or undated tephra layers. This dataset forms the basis for a regional stratigraphic framework and provides insights into the central Mediterranean explosive volcanic activity during the last 1.36 Ma.

Crystalline Quality, Composition Homogeneity, Tellurium Precipitates/Inclusions Concentration, Optical Transmission, and Energy Band Gap of Bridgman Grown Single-Crystalline Cd1−xZnxTe (0 ≤ x ≤ 0.1)

Cd1−xZnxTe (0 ≤ x ≤ 0.1) ingots were obtained by Bridgman’s method using two different speeds in order to find the optimal conditions for single-crystalline growth. Crystalline quality was studied by chemical etching, the elemental composition by wavelength dispersive spectroscopy (WDS), tellurium (Te) precipitates/inclusions concentration by differential scanning calorimetry (DSC), optical transmission by Fourier transformed infrared spectrometry (FTIR), and band gap energy (Egap) by photoluminescence (PL). It was observed that the ingots grown at a lower speed were those of the best crystalline quality, having at most three grains of different crystallographic orientation. The average dislocations density in all of them were similar and correspond to materials of good quality. EPMA results indicated that the homogeneity in the composition was excellent in the ingots central part. The concentration of Te precipitates/inclusions in all ingots was below the instrument (DSC) detection limit, 0.25% wt/wt. In the case of wafers from Cd0.96Zn0.04Te and Cd0.90Zn0.10Te ingots, the optical transmission was better than that of commercial materials and varied between 60% and 70%, while for pure CdTe, the transmission range was between 50% and 55%, the latter being decreased by the presence of Te precipitates/inclusions. The band gap energy Eg of different wafers was experimentally obtained by PL measurements at 76 K. We observed that Eg increased with the Zn concentration of the wafers, following a linear regression comparable to those proposed in the literature, and consistent with the results obtained with other techniques.

Interplay between melt infiltration and strain localization in the lower lithosphere of San Quintin, Baja California

<p>How strain localizes in the lower crust and upper mantle to accommodate transcurrent plate motions is not well understood. Here we focus on a suite of lower crustal and upper mantle xenoliths from the San Quintin Volcanic Field (SQVF) in Baja California, Mexico, located along transcurrent faults at the margin of the Pacific plate. Previous work has suggested that in addition to significant strain localization, the lower lithosphere below SQVF has experienced partial melting, possibly through shear heating. The presence of even minor amounts of melt could significantly affect the deformation mechanisms accommodating strain. While previous studies of SQVF have largely focused on deformation in the upper mantle, less is known about strain localization in the lower crust. We have analyzed the composition and microstructures of nine xenoliths using wavelength dispersive spectroscopy (WDS) and electron backscatter diffraction (EBSD) to elucidate the relationship between melt infiltration and deformation in the lower crust of this actively-deforming region.</p><p>We categorize the suite of SQVF xenoliths into two textural and chemical groups: Group 1, consisting of undeformed mafic cumulates, and Group 2, consisting of foliated ultramafic peridotites and mafic granulites. Symplectites and corona textures with olivine-orthopyroxene-clinopyroxene+spinel symplectite-plagioclase layering preserved in Group 2 samples are interpreted to have resulted from basaltic melt infiltration during deformation. The orientation of the shape preferred orientations (SPO) of spinel and orthopyroxene grains relative to foliation in Group 2 samples is consistent with experimental studies of crystallization during melt infiltration. Evidence for deformation is also preserved in the form of moderate crystallographic preferred orientations (CPO), present in plagioclase, orthopyroxene, and olivine. Oxide weight percentages, calculated using electron microprobe data and modal phase abundances from WDS maps, were used to construct pseudosections in order to estimate equilibrium temperatures and pressures. The range of pressures across samples suggest a changing degree of deformation and degree of rock-melt interaction with depth in the lower crust of Baja California.</p>

Phase transformation from PbS to PbSe:S in hot-wall deposition of nanocomposite thin film with evaporation sources of PbS and ZnSe

Simultaneous evaporation of PbS and ZnSe using hot-wall deposition was investigated to prepare nanocomposite thin films. X-ray diffraction patterns indicated that the films formed a phase mixture of ZnSe and PbSe, suggesting that an evaporation source of PbS phase-transformed to PbSe during a film deposition. Wavelength-dispersive spectroscopy indicated that the composite contains a small amount of S below 1 at.%. High-angle annular dark-field scanning transmission electron microscopy and line scan analysis in electron energy-loss spectroscopy indicated that PbSe nanocrystals were dispersed in a ZnSe, while S tended to segregate in ZnSe matrix. Photocurrent spectra indicated that peak position at approximately 460 nm shifted toward a shorter wavelength as Pb concentration increased.

Vitreous Tesserae from the Four Seasons Mosaic of the S. Aloe Quarter in Vibo Valentia–Calabria, Italy: A Chemical Characterization

This work reports the results of the archaeometrical investigation performed on twenty glass tesserae collected in 2018, during the restoration of the Four Seasons mosaic, which dates between the second and the third century AD, in the archaeological area of the S. Aloe quarter in Vibo Valentia (Calabria, Italy). The coloured glass tesserae were analysed through a micro-analytical approach using an Electron Probe Micro Analyser with Wavelength-Dispersive Spectroscopy (EPMA-WDS) and Laser Ablation with Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). The aims of the study were (1) the determination of the chemical composition and the technology of glass mosaic tesserae production; (2) the individuation of colouring and opacifying agents used for the production of the glass tesserae. The glasses show the typical soda–lime–silica composition. EPMA-WDS results prove the use of Sn–Pb antimonates to create yellow glass, and of cuprite to obtain the red colour. Copper and cobalt were employed in both green and blue glasses to produce different shades of colour (grey, tints of green, dark and light blue).

Influence of ZrB2 on Microstructure and Properties of Steel Matrix Composites Prepared by Spark Plasma Sintering

In this study, four composites with different ZrB2 content were made by the Spark Plasma Sintering (SPS/FAST) technique. The sintering process was carried out at 1373 K for 5 min under an argon atmosphere. The effect of ZrB2 reinforcing phase content on the density, microstructure, and mechanical and tribological properties of composites was investigated. The results were compared with experimental data obtained for 316L austenitic stainless steel without the reinforcing phase. The results showed that the ZrB2 content significantly affected the tested properties. With the increasing content of the ZrB2 reinforcing phase, there was an increase in the Young’s modulus and hardness and an improvement in the abrasive wear resistance of sintered composites. In all composites, new fine precipitates were formed and distributed in the steel matrix and along the grain boundaries. Microstructural analysis (Scanning Electron Microscopy (SEM), Wavelength Dispersive Spectroscopy (WDS)) has revealed that the fine precipitates chromium contained chromium as well as boron.

Low-Temperature Crystal Chemistry of Hingganite-(Y), from the Wanni Glacier, Switzerland

Hingganite from the Wanni glacier (Switzerland) was studied by means of energy dispersive and wavelength-dispersive spectroscopy, Raman spectroscopy, and low-temperature single-crystal X-ray diffraction. According to its chemical composition, the investigated mineral should be considered as hingganite-(Y). It showed a relatively high content of Gd, Dy, and Er and had limited content of lighter rare-earth element (REE), which is typical for Alpine gadolinite group minerals. The most intense Raman bands were 116, 186, 268, 328, 423, 541, 584, 725, 923, 983, 3383, and 3541 cm−1. Based on data of low-temperature [(−173)–(+7) °C] in situ single-crystal X-ray diffraction, it was shown that the hingganite-(Y) crystal structure was stable in the studied temperature range and no phase transitions occurred. Hingganite-(Y) demonstrated low volumetric thermal expansion (αV = 9(2) × 10−6 °C−1) and had a high thermal expansion anisotropy up to compression along one of the directions in the layer plane. Such behavior is caused by the shear deformations of its monoclinic unit cell.

Quantitative automated mineralogy to constrain metamorphic processes using ZEISS Mineralogic

<p>The Scanning Electron Microscope (SEM) is the most prolific piece of analytical equipment in the Earth Sciences, therefore quantitative mineral chemistry obtained directly from the SEM has the potential to streamline many geological fields. Mineral chemistry provides direct constraints on geological processes that are used in a wide variety of Earth Science disciplines. As a result, major element analysis of rock forming minerals have been one of the major contributors to geochemistry for decades. Electron beam techniques have been the most widely used method of obtaining in situ major element chemistry, dominated by the quantitative Wavelength Dispersive Spectroscopy (WDS) employed by the Electron Probe Micro Analyser (EMPA). More rapid, and typically more qualitative Energy Dispersive Spectroscopy (EDS) major element measurements are often obtained on a standard SEM instrument.</p><p>The relative simplicity of the EDS technique saw the growth of automated mineralogy systems beginning in the 1980’s. The peaks of EDS spectra are characteristic of the major elements present, and therefore lookup tables can be used to match the spectra to known mineral compositions and provide a likely mineralogy in both grain mounts and mapped thin sections. The automated mineral analysis technique remained essentially unchanged for decades, with an experienced operator required for many of the analytical tasks, such as creating the files for matching spectra to known minerals, processing the data, and interpreting complex phases and solid solutions (e.g. Fe/Mg-bearing silicates).</p><p>The ZEISS Mineralogic automated quantitative mineralogy (AQM) takes a new approach, using EDS detectors, but following an analytical protocol more closely aligned with EPMA. A combination of matrix corrections, peak deconvolution, and standard calibration means that peak intensities are converted directly into wt% element directly at the time of analysis. The result is a data output that can be immediately interpreted, even for minerals not previously analysed, by both new and experienced users.</p><p>Here we demonstrate the use of the ZEISS Mineralogic system for mapping thin sections from high grade metamorphic rocks. The bulk chemistry of the entire thin section, as well as individual mineral compositions can be used to constrain P-T conditions directly from the SEM, without the need for an additional step of obtaining mineral chemistry from an EPMA. With quantitative analysis at every pixel, major element profiles can be obtained at any point in the thin section, and P-T can therefore be determined from any domain within the mapped section. This approach makes the use of P-T pseudosections possible with greater speed and flexibility than has previously been possible.</p>

Comparative Study of DC and RF Sputtered MoSe2 Coatings Containing Carbon—An Approach to Optimize Stoichiometry, Microstructure, Crystallinity and Hardness

Low stoichiometry, low crystallinity, low hardness and incongruencies involving the reported microstructure have limited the applicability of TMD-C (Transition metal dichalcogenides with carbon) solid-lubricant coatings. In this work, optimized Mo–Se–C coatings were deposited using confocal plasma magnetron sputtering to overcome the above-mentioned issues. Two different approaches were used; MoSe2 target powered by DC (direct current) or RF (radio frequency) magnetron sputtering. Carbon was always added by DC magnetron sputtering. Wavelength dispersive spectroscopy displayed Se/Mo stoichiometry of ~2, values higher than the literature. The Se/Mo ratio for RF-deposited coatings was lower than for their DC counterparts. Scanning electron microscopy showed that irrespective of the low carbon additions, the Mo–Se–C coatings were highly compact with no vestiges of columnar growth due to optimal bombardment of sputtered species. Application of substrate bias further improved compactness at the expense of lower Se/Mo ratio. X-ray diffraction, transmission electron microscopy, and Raman spectroscopy confirmed the presence of MoSe2 crystals, and (002) basal planes. Even very low carbon additions led to an improvement of the hardness of the coatings. The work reports a comparison between RF and DC sputtering of MoSe2 coatings with carbon and provides a guideline to optimize the composition, morphology, structure, and mechanical properties.

Nipalarsite, Ni8Pd3As4, a new platinum-group mineral from the Monchetundra Intrusion, Kola Peninsula, Russia

Nipalarsite, Ni8Pd3As4, is a new platinum-group mineral discovered in the sulfide-bearing orthopyroxenite of the Monchetundra layered intrusion, Kola Peninsula, Russia (67°52′22″N, 32°47′60″E). Nipalarsite forms anhedral grains (5–80 µm in size) in intergrowths with sperrylite, kotulskite, hollingworthite, isomertieite, menshikovite, palarstanide, nielsenite and monchetundtraite enclosed in pentlandite, anthophyllite, actinolite and chlorite. Nipalarsite is brittle, has a metallic lustre and a grey streak. In plane-polarised light, nipalarsite is light grey with a blue tinge. Reflectance values in air (in %) are: 46.06 at 470 nm, 48.74 at 546 nm, 50.64 at 589 nm and 54.12 at 650 nm. Values of VHN20 fall between 400.5 and 449.2 kg.mm–2, with a mean value of 429.9 kg.mm–2, corresponding to a Mohs hardness of ~4. The average result of 27 electron microprobe wavelength dispersive spectroscopy analyses of nipalarsite is (wt.%): Ni 44.011, Pd 28.74, Fe0.32, Cu 0.85, Pt 0.01, Au 0.05, As 25.42, Sb 0.05, Te 0.39, total 99.85. The empirical formula (normalised to 15 atoms per formula unit) is: (Ni8.10Fe0.06)Σ8.16(Pd2.94Cu0.18)Σ3.12(As3.68Te0.03)Σ3.71 or, ideally, Ni8Pd3As4. Nipalarsite is cubic, space group Fm$\bar{3}$m, with a = 11.4428(9) Å, V = 1498.3(4) Å3 and Z = 8. The strongest lines in the powder X-ray diffraction pattern of synthetic Ni8Pd3As4 [d, Å (I) (hkl)] are: 2.859(10)(004), 2.623(6)(313), 2.557(6)(024), 2.334(11)(224), 2.201(35)(115,333), 2.021(100)(044), 1.906(8)(006,244) and 1.429(7)(008). The crystal structure was solved and refined from the single-crystal X-ray diffraction data of synthetic Ni8Pd3As4. The relation between natural and synthetic nipalarsite is illustrated by an electron back-scattered diffraction study of natural nipalarsite. The density calculated on the basis of the empirical formula of nipalarsite is 9.60 g.cm–3. The mineral name corresponds to the three main elements: Ni, Pd and As.