Contradicting Geometrical Concepts in Pore Size Analysis Attained with Electron Microscopy and Mercury Intrusion

It has been reported that improving electrical conductivity and maintaining stable structure during discharge/charge process are challenge for Si to be used as an anode for lithium ion batteries (LIB). To address this problem, milkweed (MW) was carbonized to prepare hollow carbon microtubes (HCMT) derived from biomass as an anode template for LIB. In order to improve electrical conductivity, various materials such as chitosan (CTS), agarose, and polyvinylidene fluoride (PVDF) are used as carbon source (C1, C2, and C3) by carbonization. Carbon coated HCMT@Si composits, HCMT@Si@C1, HCMT@Si@C1@C2, and HCMT@Si@C1@C3, have been successfully synthesized. Changes in structure and crystallinity of HCMT@Si composites were characterized by using X-ray diffraction (XRD). Specific surface area for samples was calculated by using BET (Brunauer–Emmett–Teller). Also, pore size and particle size were obtained by particle and pore size analysis system. The surface morphology was evaluated using high resolution scanning electron microscopy (HR-SEM), Field Emission transmission electron microscopy (TEM). The thermal properties of HCMT@Si composites were analyzed by thermogravimetric analysis (TGA). Our research was performed to study the synthesis and electrochemical performance of Si composite with HCMT by the carbonization of natural micro hollow milkweed to form an inner space. After carbonization at 900 °C for 2 h in N2 flow, inner diameter of HCMT obtained was about 10 μm. The electrochemical tests indicate that HCMT@Si@C1@C3 exhibits discharge capacity of 932.18 mAh/g at 0.5 A/g after 100 cycles.

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A multilayer thickness relationship applicable to pore size analysis of silica gel

Journal of Applied Chemistry and Biotechnology ◽

10.1002/jctb.5020230103 ◽

2007 ◽

Vol 23 (1) ◽

pp. 19-27 ◽

Cited By ~ 5

Author(s):

Badie S. Girgis

Keyword(s):

Pore Size ◽

Silica Gel ◽

Size Analysis ◽

Pore Size Analysis

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Nanoscale Pore Structure Characterization and Permeability of Mudrocks and Fine-Grained Sandstones in Coal Reservoirs by Scanning Electron Microscopy, Mercury Intrusion Porosimetry, and Low-Field Nuclear Magnetic Resonance

Geofluids ◽

10.1155/2018/2905141 ◽

2018 ◽

Vol 2018 ◽

pp. 1-20 ◽

Cited By ~ 8

Author(s):

Na Zhang ◽

Fangfang Zhao ◽

Pingye Guo ◽

Jiabin Li ◽

Weili Gong ◽

...

Keyword(s):

Electron Microscopy ◽

Pore Size ◽

Mercury Intrusion Porosimetry ◽

Mercury Intrusion ◽

Rock Samples ◽

Fine Grained ◽

Low Field ◽

Water Saturated ◽

Pore Types ◽

Scanning Electron

Porosity and permeability of two typical sedimentary rocks in coal bearing strata of underground coal mines in China, i.e., mudrocks and fine-grained sandstones, were comprehensively investigated by multiple experimental methods. Measured porosity averages of the helium gas porosity (φg), MIP porosity (φMIP), water porosity (φw), and NMR porosity (φNMR) of the twelve investigated rock samples range from 1.78 to 16.50% and the measured gas permeabilities (Kg) range from 0.0003 to 2.4133 mD. Meanwhile, pore types, pore morphologies, and pore size distributions (PSD) were determined by focused ion beam scanning electron microscopy (FIB-SEM), mercury intrusion porosimetry (MIP), and low-field nuclear magnetic resonance (NMR). FIB-SEM image analyses showed that the mineral matrix pores including interparticle (interP) and intraparticle (intraP) pores with varied morphologies are the dominant pore types of the investigated rock samples while very few organic matter (OM) pores were observed. Results of the MIP and the full water-saturated NMR measurements showed that the PSD curves of the mudrock samples mostly present a unimodal pattern and nanopores with pore diameter less than 0.1 μm are their predominant pore type, while the PSD curves of the fine-grained sandstone samples are featured by a bimodal distribution. Furthermore, comparison of the full water-saturated and irreducible-water-saturated NMR measurements indicated that pores in the mudrocks are solely adsorption pores (normally pore size < 0.1 μm) whereas apart from a fraction of adsorption pores, a large part of the pores in the sandstone sample with relatively high porosity are seepage pores (normally pore size > 0.1 μm). Moreover, the PSD curves of NMR quantitatively converted from the NMR T2 spectra by T2Pc and weighted arithmetic mean (WAM) methods are in good agreement with the PSD curves of MIP. Finally, the applicability of three classic permeability estimation models based on MIP and NMR data to the investigated rock samples was evaluated.

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