Synthesis of the ternary metal carbide solid‐solution ceramics by polymer‐derived‐ceramic route

2020 ◽  
Vol 103 (5) ◽  
pp. 2970-2974 ◽  
Author(s):  
Honghua Liu ◽  
Bin Du ◽  
Yanhui Chu
2009 ◽  
Vol 24 (5) ◽  
pp. 1815-1819 ◽  
Author(s):  
Y. Dai ◽  
J.H. Li ◽  
X.L. Che ◽  
B.X. Liu

An n-body Ni–Nb–Ta potential is constructed to conduct molecular dynamics simulations using 129 solid solution models with various compositions. Comparing the relative stability of solid solutions versus their disordered counterparts, simulations determine two critical solid-solubility lines, which define a region in the composition triangle. If an alloy is located inside the defined region, a disordered state is energetically favored; if it is located outside, a crystalline solid solution is preserved. The region is therefore named as the metallic glass-forming region.


2021 ◽  
Vol 8 ◽  
Author(s):  
Jithesh Kavil ◽  
Jobin Varghese ◽  
Govind Raj Kovummal

BaZr0.2[Ti(1-x)Mgx/3Ta2x/3]0.8O3 (x = 0.0, 0.05, 0.1, 0.2, 0.4, 0.6, 0.8, 1.0) (BZTMT) ceramics were prepared through conventional solid state ceramic route. The crystal structure and microstructure of the compounds were investigated respectively using XRD and SEM. The dielectric properties were measured in the frequency range of 100 Hz–1 MHz. The ferroelectric Curie temperature of BaZr0.2Ti0.8O3 (x = 0) shifted from 21°C to -10°C with the addition of minute amount of dopant (x = 0.025) and the paraelectric transition temperature is diffusive in nature. The relative permittivity and dielectric loss of BZTMT at 1 MHz varies from 5205 to 24 and 1.8 × 10–2 to 2.0 × 10–5 respectively, as the value of x increases from 0 to 1.


2018 ◽  
Vol 44 (7) ◽  
pp. 8476-8483 ◽  
Author(s):  
Xin’gang Luan ◽  
Sen Chang ◽  
Ralf Riedel ◽  
Laifei Cheng

2019 ◽  
Vol 102 (8) ◽  
pp. 4956-4962 ◽  
Author(s):  
Tongqi Wen ◽  
Shanshan Ning ◽  
Da Liu ◽  
Beilin Ye ◽  
Honghua Liu ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (6) ◽  
pp. 2634-2639 ◽  
Author(s):  
Eva M. Campo ◽  
Jonathan Poplawsky ◽  
Anamaris Meléndez ◽  
Joshua L. Robles-García ◽  
Idalia Ramos ◽  
...  

2013 ◽  
Vol 22 ◽  
pp. 207-216
Author(s):  
PRAKASH SINGH ◽  
PRABHAKAR SINGH ◽  
OM PARKASH ◽  
DEVENDRA KUMAR

Various compositions with x=0.01, 0.05, 0.10, 0.20 and 0.30 in the system SrTi 1-x Mn x O 3 were prepared by solid state ceramic route. Compositions with x ≤ 0.10 were found to be single phase solid solution. In this paper, the result of investigations on the effect of manganese substitution in SrTiO 3 on dielectric behaviour for the compositions with x ≤ 0.10, which form single phase solid solution have been reported. Average grain size is small, this may be due to segregation of dopant at grainboundaries. Dielectric measurements were made in the temperature range 150–500K. Measurements of dielectric properties show that there is not much space charge polarisation across the grains and grainboundaries interface. This space charge polarisation only occurs at high temperature and one observes large dispersion of dielectric constant and dissipation factor. At low temperatures, dielectric behaviour follows the character of SrTiO 3 with only difference in the values of dielectric constant.


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