scholarly journals Global household energy model: a multivariate hierarchical approach to estimating trends in the use of polluting and clean fuels for cooking

2020 ◽  
Vol 69 (4) ◽  
pp. 815-839
Author(s):  
Oliver Stoner ◽  
Gavin Shaddick ◽  
Theo Economou ◽  
Sophie Gumy ◽  
Jessica Lewis ◽  
...  
Keyword(s):  
Energy Model ◽  
Hierarchical Approach ◽  
Household Energy ◽  
Clean Fuels

Hydrogen Atom Transfer Reaction Free Energy as a Predictor of Abiotic Nitroaromatic Reduction Rate Constants: A Comprehensive Analysis

2019 ◽  
Author(s):  
Dominic Di Toro ◽  
Kevin P. Hickey ◽  
Herbert E. Allen ◽  
Richard F. Carbonaro ◽  
Pei C. Chiu
Keyword(s):  
Free Energy ◽  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Energy Model ◽  
Second Order ◽  
Transfer Model ◽  
Atom Transfer ◽  
Order Rate ◽  
Linear Free Energy ◽  
Free Energy Model

<div>A linear free energy model is presented that predicts the second order rate constant for the abiotic reduction of nitroaromatic compounds (NACs). For this situation previously presented models use the one electron reduction potential of the NAC reaction. If such value is not available, it has been has been proposed that it could be computed directly or estimated from the electron affinity (EA). The model proposed herein uses the Gibbs free energy of the hydrogen atom transfer (HAT) as the parameter in the linear free energy model. Both models employ quantum chemical computations for the required thermodynamic parameters. The available and proposed models are compared using second order rate constants obtained from five investigations reported in the literature in which a variety of NACs were exposed to a variety of reductants. A comprehensive analysis utilizing all the NACs and reductants demonstrate that the computed hydrogen atom transfer model and the experimental one electron reduction potential model have similar root mean square errors and residual error probability distributions. In contrast, the model using the computed electron affinity has a more variable residual error distribution with a significant number of outliers. The results suggest that a linear free energy model utilizing computed hydrogen transfer reaction free energy produces a more reliable prediction of the NAC abiotic reduction second order rate constant than previously available methods. The advantages of the proposed hydrogen atom transfer model and its mechanistic implications are discussed as well.</div>

Injuries and Occupational Safety

2017 ◽  
Author(s):  
Dawn N. Castillo ◽  
Timothy J. Pizatella ◽  
Nancy A. Stout
Keyword(s):  
United States ◽  
Ionizing Radiation ◽  
Occupational Safety ◽  
Occupational Injury ◽  
Occupational Injuries ◽  
Mechanical Energy ◽  
The United States ◽  
Hierarchical Approach ◽  
Safety Hazards ◽  
Injury Control

This chapter describes occupational injuries and their prevention. It describes in detail the causes of injuries and epidemiology of injuries. Occupational injuries are caused by acute exposure in the workplace to safety hazards, such as mechanical energy, electricity, chemicals, and ionizing radiation, or from the sudden lack of essential agents, such as oxygen or heat. This chapter describes the nature and the magnitude of occupational injuries in the United States. It provides data on risk of injuries in different occupations and industries. Finally, it discusses prevention of injuries, using a hierarchical approach to occupational injury control.

Designing shoe tread for friction performance: a hierarchical approach

2021 ◽  
Vol 13 (sup1) ◽  
pp. S97-S99
Author(s):  
Kurt E. Beschorner ◽  
Emily E. Meehan ◽  
Arian Iraqi ◽  
Sarah L. Hemler
Keyword(s):  
Hierarchical Approach ◽  
Friction Performance
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