Entropic Driving Forces of Ferrites for Two-Step Thermochemical Water and Carbon Dioxide Splitting

2021 ◽  
Author(s):  
Shang Zhai ◽  
Kipil Lim ◽  
Sai Gopalakrishnan ◽  
Jimmy Rojas ◽  
Kevin Stone ◽  
...  
2016 ◽  
Vol 30 (8) ◽  
pp. 6654-6661 ◽  
Author(s):  
Brandon J. Hathaway ◽  
Rohini Bala Chandran ◽  
Adam C. Gladen ◽  
Thomas R. Chase ◽  
Jane H. Davidson

2021 ◽  
pp. 117282
Author(s):  
André Guerra ◽  
Adam McElligott ◽  
Chong Yang Du ◽  
Milan Marić ◽  
Alejandro D. Rey ◽  
...  

2016 ◽  
Vol 18 (34) ◽  
pp. 23587-23595 ◽  
Author(s):  
D. A. Dimitrakis ◽  
N. I. Tsongidis ◽  
A. G. Konstandopoulos

Effect of Nickel ions on reduction energy and charge distribution of oxygen – neighbouring ions in NiFe2O4 for solar fuels.


Author(s):  
Luke J. Venstrom ◽  
Jane H. Davidson

The heterogeneous hydrolysis/oxidation of zinc vapor is proposed as a promising reaction path for the exothermic step in two-step Zn/ZnO solar thermochemical water and carbon dioxide splitting cycles. This approach circumvents mass transfer limitations encountered in the oxidation of solid or liquid zinc, promising rapid hydrogen/carbon monoxide production rates and complete conversion of zinc. In this paper, a parametric thermodynamic analysis is presented to quantify the penalty of generating zinc vapor as well as the benefit of achieving complete conversion of zinc via the heterogeneous oxidation of zinc vapor. The penalty for generating zinc vapor is a reduction in water splitting efficiency from 36% to 27% and a reduction in carbon dioxide splitting efficiency from 39% to 31%. However, with heat recuperation this penalty can be avoided. The benefit of completely converting zinc via the heterogeneous oxidation of zinc vapor is an increase in efficiency from ∼6% to 27% and 31% for water and carbon dioxide splitting, respectively.


2010 ◽  
Vol 96 (14) ◽  
pp. 143110 ◽  
Author(s):  
R. Garcia ◽  
N. S. Losilla ◽  
J. Martínez ◽  
R. V. Martinez ◽  
F. J. Palomares ◽  
...  

Author(s):  
Yannan Zhou ◽  
Jixia Huang ◽  
Mingxiang Huang ◽  
Yicheng Lin

To spatially analyze the effects of the major drivers on carbon dioxide equivalent (CO2eq) emissions in Inner Mongolia, a typical area with high CO2eq emissions in China, this paper quantitatively investigates the factors that affect county-level CO2eq emissions and the corresponding spatial mechanisms. Based on a spatial panel econometric model with related energy and economic data from 101 counties in Inner Mongolia between 2007 and 2012, four main results are obtained: (a) The CO2eq emissions in Inner Mongolia rapidly increased at an average annual growth rate of 7.27% from 2007 to 2012, increasing from 287.69 million tons to 510.47 million tons. (b) The county-level CO2eq emissions in Inner Mongolia increased, but the growth rate decreased annually. Additionally, CO2eq emissions are highly heterogeneous in the region. (c) Geographic factors were the main cause of the spatial spillover effects related to county-level CO2eq emissions. Specifically, the levels of urbanization and technological progress were conducive to CO2eq emission reductions, and the economic growth and industrial structure had the opposite effect in Inner Mongolian counties. (d) Technological progress had a significant spatial spillover effect in Inner Mongolian counties, and the effects of other factors were not significant. Implementing relevant strategies that focus on the inter-county interactions among the driving forces of CO2eq emissions could promote energy savings and emission reductions in Inner Mongolia.


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