Parametric Analysis and Optimization of a High Temperature Fuel Cell: Supercritical CO2 Turbine Hybrid System

2008 ◽  
Author(s):  
D. Sa´nchez ◽  
R. Chacartegui ◽  
A. Mun˜oz ◽  
T. Sa´nchez
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Hybrid Systems ◽  
Hybrid System ◽  
Operating Temperature ◽  
Inlet Temperature ◽  
Brayton Cycle ◽  
Molten Carbonate ◽  
Turbine Inlet Temperature

The integration of high temperature fuel cells — molten carbonate and solid oxide — and gas turbine engines for efficient power generation is not new. Different strategies for integrating both systems have been proposed in the past ten years and there are some field tests being run presently. However, the commercial availability of such power systems seems to be continuously delayed, probably due to cost and reliability problems. The materials used in high temperature fuel cells are expensive and their cost is not decreasing at the expected pace. In fact, it looks as if they had reached stabilization. Therefore, there seems to be agreement that operating at a lower temperature might be the only way to achieve more competitive costs to enter the market, as metallic materials could then be used. From the point of view of conventional hybrid systems, decreasing the operating temperature of the cell would affect the efficiency of the bottoming cycle dramatically, as long as turbine inlet temperature is a critical parameter for the performance of a Brayton cycle. This is the reason why hybrid systems perform better with solid oxide fuel cells operating at 1000 °C than with molten carbonate cells at 650 °C typically. This work presents a hybrid system comprising a high temperature fuel cell, either SOFC or MCFC, and a bottoming Brayton cycle working with supercritical carbon dioxide. A parametric analysis is done where all the parameters affecting the performance of the hybrid system are studied, with emphasis in the bottoming cycle. For the Brayton cycle: pressure ratio, expansion and compression efficiencies, recuperator effectiveness, pressure losses, turbine inlet temperature... For the fuel cell: fuel utilization, current density, operating temperature, etc. From this analysis, optimum operating point and integration scheme are established and, after this, a comparison with conventional hybrid systems using similar fuel cells is done. Results show that, although the fuel cell is not pressurized in the CO2 based system, its performance is similar to the best conventional cycle. Furthermore, if lower operating temperatures are considered for the fuel cell, the new system performs better than any of the conventional.

Performance Analysis on SOFC-HCCI Engine Hybrid System

2012 ◽  
Author(s):  
Sung Ho Park ◽  
Young Duk Lee ◽  
Sang Gyu Kang ◽  
Kook Young Ahn
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Hybrid Systems ◽  
Hybrid System ◽  
Gas Turbines ◽  
Waste Heat ◽  
Metal Catalyst ◽  
Molten Carbonate ◽  
Hcci Engine ◽  
Ci Engines

Fuel cell systems are currently regarded as a promising type of energy conversion system. Various types of fuel cell have been developed and investigated worldwide for portable, automotive, and stationary applications. In particular, in the case of large-scale stationary applications, the high-temperature fuel cells known as the molten carbonate fuel cell (MCFC) and the solid oxide fuel cell (SOFC) have been used as a power source due to their higher efficiency compared to low-temperature fuel cells. Because SOFCs have many advantages, including a high power density, low corrosion, and operability without a metal catalyst, many efforts to develop a SOFC hybrid system have been undertaken. SOFC hybrid systems with a gas turbine or engine show improved system efficiency through their utilization of waste heat and unreacted fuel. Especially, the internal combustion engine has the advantage of robustness, easy maintenance, and a low cost compared to gas turbines, this type is more adaptable for use in a hybrid system with a SOFC. However, the engine should be operated stably at a high air fuel ratio because the SOFC anode exhaust gas has a low fuel concentration. The homogeneous charge compression ignition (HCCI) engine has both the advantages of SI and CI engines. Moreover, the lean burn characteristics of the HCCI engine make it a strong candidate for SOFC hybrid systems. The objective of this work is to develop a novel cycle composed of a SOFC and a HCCI engine. In order to optimize the SOFC-HCCI hybrid system, a system analysis is conducted here using the commercial software Aspen Plus®. The SOFC model is validated with experimental data. The engine model is developed based on an empirical equation that considers the ignition delay time. The performance of the hybrid system is compared with that of a SOFC stand-alone system to confirm the optimization of the system. This study will be useful for the development of a new type of hybrid system which uses a fuel cell and an optimized system.

Novel Dynamic Quasi-3-Dimensional High Temperature Fuel Cell Model With Internal Manifolding

2010 ◽  
Author(s):  
Dustin McLarty ◽  
Scott Samuelsen ◽  
Jack Brouwer
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Cell Model ◽  
Single Cells ◽  
Internal Heat ◽  
Transient Temperature ◽  
Inlet Temperature ◽  
Molten Carbonate ◽  
Internal Reforming

High temperature fuel cells have demonstrated potential for a wide array of energy applications while meeting future efficiency and emission targets. Earlier works captured either steady state performance of stacks or transient behavior of single cells. This work develops a model that can simulate and spatially resolve transient temperature, pressure and species distributions for a simulated fuel cell stack in a computationally efficient manner. The novel model accounts for internal manifolding of fuel and oxidant streams and predicts two dimensional fields associated with the dynamic operation of a single high temperature fuel cell. The MatLab-Simulink® model calculates dynamic performance for both solid oxide and molten carbonate fuel cells that utilize both direct and indirect internal reforming. This paper presents dynamic response characteristics to perturbations in power, fuel utilization and composition, and investigates control strategies that minimize PEN temperature variations and fluctuations during the transient responses. Air flow and inlet temperature controls are sufficient to control average PEN temperature, but internal heat transfer dynamics substantially change the spatial temperature distribution dynamics at different operational power densities.

A New Concept for High Temperature Fuel Cell Hybrid Systems Using Supercritical Carbon Dioxide

2009 ◽  
Vol 6 (2) ◽  
Author(s):  
D. Sánchez ◽  
R. Chacartegui ◽  
F. Jiménez-Espadafor ◽  
T. Sánchez
Keyword(s):  
Carbon Dioxide ◽  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Supercritical Carbon Dioxide ◽  
Hybrid Systems ◽  
Cell Hybrid ◽  
Gas Turbines ◽  
Solid Oxide ◽  
Molten Carbonate

Hybrid power systems based on high temperature fuel cells are a promising technology for the forthcoming distributed power generation market. For the most extended configuration, these systems comprise a fuel cell and a conventional recuperative gas turbine engine bottoming cycle, which recovers waste heat from the cell exhaust and converts it into useful work. The ability of these gas turbines to produce useful work relies strongly on a high fuel cell operating temperature. Thus, if molten carbonate fuel cells or the new generation intermediate temperature solid oxide fuel cells are used, the efficiency and power capacity of the hybrid system decrease dramatically. In this work, carbon dioxide is proposed as the working fluid for a closed supercritical bottoming cycle, which is expected to perform better for intermediate temperature heat recovery applications than the air cycle. Elementary fuel cell lumped-volume models for both solid oxide and molten carbonate are used in conjunction with a Brayton cycle thermodynamic simulator capable of working with open/closed and air/carbon dioxide systems. This paper shows that, even though the new cycle is coupled with an atmospheric fuel cell, it is still able to achieve the same overall system efficiency and rated power than the best conventional cycles being currently considered. Furthermore, under certain operating conditions, the performance of the new hybrid systems beats that of existing pressurized fuel cell hybrid systems with conventional gas turbines. From the results, it is concluded that the supercritical carbon dioxide bottoming cycle holds a very high potential as an efficient power generator for hybrid systems. However, costs and balance of plant analysis will have to be carried out in the future to check its feasibility.

High Efficiency Gas Turbine Based Power Cycles—A Study of the Most Promising Solutions: Part 2—A Parametric Performance Evaluation

2008 ◽  
Author(s):  
Rakesh K. Bhargava ◽  
Michele Bianchi ◽  
Stefano Campanari ◽  
Andrea De Pascale ◽  
Giorgio Negri di Montenegro ◽  
...  
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbine ◽  
High Efficiency ◽  
Combined Cycle ◽  
Development Work ◽  
Brayton Cycle ◽  
Molten Carbonate ◽  
Water Steam

In general, two approaches have been used in the gas turbine industry to improve Brayton cycle performance. One approach includes increasing Turbine Inlet Temperature (TIT) and cycle pressure ratio (β), but it is quite capital intensive requiring extensive research and development work, advancements in cooling (of turbine blades and hot gas path components) technologies, high temperature materials and NOx reducing methods. The second approach involves modifying the Brayton cycle. However, this approach did not become very popular because of the development of high efficiency gas turbine (GT) based combined cycle systems in spite of their high initial cost. This paper discusses another approach that has gained lot of momentum in recent years in which modified Brayton cycles are used with humidification or water/steam injection, termed “wet Cycles”, resulting in lower cost/kW power system, or with fuel cells, obtaining “hybrid Cycles”; the cycle efficiency can be comparable with a corresponding combined cycle system including better part-load operational characteristics. Such systems, that include advanced Steam Injected cycle and its variants (STIG, ISTIG, etc.), Recuperated Water Injection cycle (RWI), humidified air turbine cycle (HAT) and Cascaded Humidified Advanced Turbine (CHAT) cycle, Brayton cycle with high temperature fuel cell, Molten Carbonate Fuel Cell (MSFC) or Solid Oxide Fuel Cells (SOFC) and combinations of these with the modified Brayton cycles, have not yet become commercially available as more development work is required. The main objective of this paper is to provide a detailed parametric thermodynamic cycle analysis of the above mentioned cycles and discussion of their comparative performance including advantages and limitations.

Fuel-Cell Hybrid Systems to Generate Shipboard Electrical Power

2009 ◽  
Author(s):  
W. J. Sembler ◽  
S. Kumar
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Air Quality ◽  
Hybrid Systems ◽  
Hybrid System ◽  
Cell Hybrid ◽  
Electrical Power ◽  
History Of ◽  
Marine Applications ◽  
Fuel Cell Hybrid

The reduction of shipboard airborne emissions has been receiving increased attention due to the desire to improve air quality and reduce the generation of greenhouse gases. The use of a fuel cell could represent an environmentally friendly way for a ship to generate in-port electrical power that would eliminate the need to operate diesel-driven generators or use shore power. This paper includes a brief description of the various types of fuel cells in use today, together with a review of the history of fuel cells in marine applications. In addition, the results of a feasibility study conducted to evaluate the use of a fuel-cell hybrid system to produce shipboard electrical power are presented.

Compared Thermal Modeling of Anode- and Electrolyte-Supported SOFC-Gas Turbine Hybrid Systems

2020 ◽  
Vol 18 (1) ◽  
Author(s):  
Abdulrazzak Akroot ◽  
Lutfu Namli ◽  
Hasan Ozcan
Keyword(s):  
Fuel Cell ◽  
Hybrid Systems ◽  
Hybrid System ◽  
Operating Temperature ◽  
Power Production ◽  
Solid Oxide ◽  
System Model ◽  
Oxide Fuel ◽  
System Operation ◽  
And Performance

Abstract In this study, two solid oxide fuel cell (SOFC) hybrid systems (anode-supported model (ASM) and electrolyte-supported model (ESM)) is developed in matlab® and compared. The hybrid system model is considered to investigate the impacts of various operating parameters such as SOFC operating temperature and steam/carbon ratio on power production and performance of the hybrid system where it is projected that results can be utilized as guidelines for optimal hybrid system operation. According to the findings, a maximum 695 kW power is produced at 750 °C operating temperature for the anode-supported model, whereas 627 kW power is produced at 1000 °C for the electrolyte-supported model. The highest electrical efficiencies for the anode-supported model and the electrolyte-supported model are 64.6% and 58.3%, respectively. Besides, the lower value of the steam to carbon ratio is favorable for increased power output from the fuel cell and consequently a high SOFC efficiency.

Simulation of Distributive Generation Using Fuel Cell Hybrid Systems

2006 ◽  
Author(s):  
Brian Wolf ◽  
Shripad Revankar
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Hybrid Systems ◽  
Hybrid System ◽  
Cell Hybrid ◽  
Cell Model ◽  
Initial Step ◽  
Parametric Studies ◽  
Key Issues ◽  
Fuel Cell Hybrid

Fuel cell hybrid technology has the potential to significantly change our current energy infrastructure. Past studies have shown that the combination of fuel cells and turbines can produce power at remarkably high efficiencies with low levels of pollution. The work presented in this paper is an initial step to further development of a hybrid system model. The fuel cell model discussed is used to perform parametric studies to aid in the optimization of a hybrid system. This paper provides an overview of fuel cell hybrid systems and distributive generation. A fuel cell model is implemented in SIMULINK using basic balance equations. Key issues of modeling specifically high temperature fuel cells are discussed along with their transient response and how it may affect the performance of a distributive generation system.

Power Cycle Integration and Efficiency Increase of Molten Carbonate Fuel Cell Systems

2005 ◽  
Vol 3 (4) ◽  
pp. 375-383 ◽  
Author(s):  
Petar Varbanov ◽  
Jiří Klemeš ◽  
Ramesh K. Shah ◽  
Harmanjeet Shihn
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbines ◽  
Waste Heat ◽  
Combined Cycle ◽  
Molten Carbonate Fuel Cell ◽  
Steam Turbines ◽  
Molten Carbonate ◽  
Carbonate Fuel Cell

A new view is presented on the concept of the combined cycle for power generation. Traditionally, the term “combined cycle” is associated with using a gas turbine in combination with steam turbines to better utilize the exergy potential of the burnt fuel. This concept can be broadened, however, to the utilization of any power-generating facility in combination with steam turbines, as long as this facility also provides a high-temperature waste heat. Such facilities are high temperature fuel cells. Fuel cells are especially advantageous for combined cycle applications since they feature a remarkably high efficiency—reaching an order of 45–50% and even close to 60%, compared to 30–35% for most gas turbines. The literature sources on combining fuel cells with gas and steam turbines clearly illustrate the potential to achieve high power and co-generation efficiencies. In the presented work, the extension to the concept of combined cycle is considered on the example of a molten carbonate fuel cell (MCFC) working under stationary conditions. An overview of the process for the MCFC is given, followed by the options for heat integration utilizing the waste heat for steam generation. The complete fuel cell combined cycle (FCCC) system is then analyzed to estimate the potential power cost levels that could be achieved. The results demonstrate that a properly designed FCCC system is capable of reaching significantly higher efficiency compared to the standalone fuel cell system. An important observation is that FCCC systems may result in economically competitive power production units, comparable with contemporary fossil power stations.

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