High Efficiency Gas Turbine Based Power Cycles—A Study of the Most Promising Solutions: Part 2—A Parametric Performance Evaluation

2008 ◽  
Author(s):  
Rakesh K. Bhargava ◽  
Michele Bianchi ◽  
Stefano Campanari ◽  
Andrea De Pascale ◽  
Giorgio Negri di Montenegro ◽  
...  
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbine ◽  
High Efficiency ◽  
Combined Cycle ◽  
Development Work ◽  
Brayton Cycle ◽  
Molten Carbonate ◽  
Water Steam

In general, two approaches have been used in the gas turbine industry to improve Brayton cycle performance. One approach includes increasing Turbine Inlet Temperature (TIT) and cycle pressure ratio (β), but it is quite capital intensive requiring extensive research and development work, advancements in cooling (of turbine blades and hot gas path components) technologies, high temperature materials and NOx reducing methods. The second approach involves modifying the Brayton cycle. However, this approach did not become very popular because of the development of high efficiency gas turbine (GT) based combined cycle systems in spite of their high initial cost. This paper discusses another approach that has gained lot of momentum in recent years in which modified Brayton cycles are used with humidification or water/steam injection, termed “wet Cycles”, resulting in lower cost/kW power system, or with fuel cells, obtaining “hybrid Cycles”; the cycle efficiency can be comparable with a corresponding combined cycle system including better part-load operational characteristics. Such systems, that include advanced Steam Injected cycle and its variants (STIG, ISTIG, etc.), Recuperated Water Injection cycle (RWI), humidified air turbine cycle (HAT) and Cascaded Humidified Advanced Turbine (CHAT) cycle, Brayton cycle with high temperature fuel cell, Molten Carbonate Fuel Cell (MSFC) or Solid Oxide Fuel Cells (SOFC) and combinations of these with the modified Brayton cycles, have not yet become commercially available as more development work is required. The main objective of this paper is to provide a detailed parametric thermodynamic cycle analysis of the above mentioned cycles and discussion of their comparative performance including advantages and limitations.

Power Cycle Integration and Efficiency Increase of Molten Carbonate Fuel Cell Systems

2005 ◽  
Vol 3 (4) ◽  
pp. 375-383 ◽  
Author(s):  
Petar Varbanov ◽  
Jiří Klemeš ◽  
Ramesh K. Shah ◽  
Harmanjeet Shihn
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbines ◽  
Waste Heat ◽  
Combined Cycle ◽  
Molten Carbonate Fuel Cell ◽  
Steam Turbines ◽  
Molten Carbonate ◽  
Carbonate Fuel Cell

A new view is presented on the concept of the combined cycle for power generation. Traditionally, the term “combined cycle” is associated with using a gas turbine in combination with steam turbines to better utilize the exergy potential of the burnt fuel. This concept can be broadened, however, to the utilization of any power-generating facility in combination with steam turbines, as long as this facility also provides a high-temperature waste heat. Such facilities are high temperature fuel cells. Fuel cells are especially advantageous for combined cycle applications since they feature a remarkably high efficiency—reaching an order of 45–50% and even close to 60%, compared to 30–35% for most gas turbines. The literature sources on combining fuel cells with gas and steam turbines clearly illustrate the potential to achieve high power and co-generation efficiencies. In the presented work, the extension to the concept of combined cycle is considered on the example of a molten carbonate fuel cell (MCFC) working under stationary conditions. An overview of the process for the MCFC is given, followed by the options for heat integration utilizing the waste heat for steam generation. The complete fuel cell combined cycle (FCCC) system is then analyzed to estimate the potential power cost levels that could be achieved. The results demonstrate that a properly designed FCCC system is capable of reaching significantly higher efficiency compared to the standalone fuel cell system. An important observation is that FCCC systems may result in economically competitive power production units, comparable with contemporary fossil power stations.

High Efficiency Gas Turbine Based Power Cycles—A Study of the Most Promising Solutions: Part 1—A Review of the Technology

2008 ◽  
Author(s):  
Rakesh K. Bhargava ◽  
Michele Bianchi ◽  
Stefano Campanari ◽  
Andrea De Pascale ◽  
Giorgio Negri di Montenegro ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Gas Turbine ◽  
Gas Turbines ◽  
High Performance ◽  
High Efficiency ◽  
Water Injection ◽  
Thermodynamic Cycle ◽  
Brayton Cycle ◽  
Molten Carbonate ◽  
Power Cycles

Commercially available gas turbines have been mostly designed based on the simple Brayton cycle and despite the enormous advancements made in their components design, materials technology, blade cooling methods, etc., thermodynamic performance achievable for this simple cycle is limited. Numerous variants to the basic Brayton cycle viz., Recuperated (REC), Inter-Cooled (IC), Re-Heat (RH), steam injected (STIG) and their combinations have been proposed, extensively discussed in the literature since the early stages of gas turbine development and few of them have been successfully implemented. New variants not yet implemented in commercial engines and still in various stages of the development with potential for additional performance improvement are: advanced Steam Injected cycle and its variants (such as Inter-cooled Steam Injected, (ISTIG)), Recuperated Water Injection cycle (RWI), Humidified Air Turbine (HAT) cycle and Cascaded Humidified Advanced Turbine (CHAT) cycle, Brayton cycle with high temperature fuel cells (Molten Carbonate Fuel Cells (MCFC) and Solid Oxide Fuel Cells (SOFC)) and their combinations with the available modified Brayton cycles. The main objective of this paper (Part 1 of the two-part paper) is to provide a comprehensive review of high performance (with most promising solutions) complex gas turbine cycles, describing their main characteristics, benefits and drawbacks in comparison with the simple Brayton cycle. Detailed parametric thermodynamic cycle analyses for the selected high efficiency cycles under development are presented in Part 2 of this paper.

scholarly journals Exergy analysis of combined cycle of gas turbine and solid oxide fuel cell in different compression ratios

2016 ◽  
Vol 4 (2) ◽  
pp. 43
Author(s):  
Esmaeel Fatahian ◽  
Navid Tonekaboni ◽  
Hossein Fatahian
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Energy Production ◽  
High Efficiency ◽  
Production Systems ◽  
New Technology ◽  
Electrical Energy ◽  
Combined Cycle ◽  
Advantages And Disadvantages

Due to the growing trend of energy consumption in the world uses of methods and new energy production systems with high efficiency and low emissions have been prioritized. Today, with the development of different systems of energy production, different techniques such as the use of solar energy, wind energy, fuel cells, micro turbines and diesel generators in cogeneration have been considered, each of these methods has its own advantages and disadvantages. Having a reliable energy generation system, inexpensive and availability the use of fuel cells as a major candidate has been introduced. Fuel cells converting chemical energy to electrical energy that today are one as a new technology in energy production are considered. In this paper fuel cell compression ratios 4, 4.1 and 4.2 at an ambient temperature of 298 K have been simulated and ultimately optimum ratio 4.1 for modeling has been selected. All components of cycle, including the stack of fuel cell, combustion chamber, air compressors, recuperator and gas turbine was evaluated from the viewpoint of exergy and exergy destruction rate was calculated by EES software.

Electrochemical Carbon Separation in a SOFC-MCFC Poly-Generation Plant With Near-Zero Emissions

2017 ◽  
Author(s):  
Luca Mastropasqua ◽  
Stefano Campanari ◽  
Jack Brouwer
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Carbon Capture ◽  
Large Scale ◽  
High Efficiency ◽  
Molten Carbonate Fuel Cell ◽  
Small Scale ◽  
Total Efficiency ◽  
Molten Carbonate

High temperature fuel cells have been studied as a suitable solution for Carbon Capture and Storage (CCS) purposes at a large scale (>100 MW). However, their modularity and high efficiency at small-scale make them an interesting solution for Carbon Capture and Utilisation at the distributed generation scale when coupled to appropriate use of CO2 (i.e., for industrial uses, local production of chemicals etc.). These systems could be used within low carbon micro-grids to power small communities in which multiple power generating units of diverse nature supply multiple products such as electricity, cooling, heating and chemicals (i.e., hydrogen and CO2). The present work explores fully electrochemical power systems capable of producing a highly pure CO2 stream and hydrogen. In particular, the proposed system is based upon integrating a Solid Oxide Fuel Cell (SOFC) with a Molten Carbonate Fuel Cell (MCFC). The use of these high temperature fuel cells has already been separately applied in the past for CCS applications. However, their combined use is yet unexplored. Moreover, both industry and US national laboratories have expressed their interest in this solution. The reference configuration proposed envisions the direct supply of the SOFC anode outlet to a burner which, using the cathode depleted air outlet, completes the oxidation of the unconverted species. The outlet of the burner is then fed to the MCFC cathode inlet which separates the CO2 from the stream. Both the SOFC and MCFC anode inlets are supplied with pre-reformed and desulfurized natural gas. The MCFC anode outlet, which is characterised by a high concentration of CO2, is fed to a CO2 separation line in which a two-stage Water Gas Shift (WGS) reactor and a PSA/membrane system respectively convert the remaining CO into H2 and remove the H2 from the exhaust stream. This has the significant advantage of achieving the required CO2 purity for liquefaction and long-range transportation without requiring the need of cryogenic or distillation plants. Moreover, the highly pure H2 stream can either be sold as transportation fuel or a valuable chemical. Furthermore, different configurations are considered with the final aim of increasing the Carbon Capture Ratio (CCR) and maximising the electrical efficiency. Moreover, the optimal power ratio between SOFC and MCFC stacks is also explored. Complete simulation results are presented, discussing the proposed plant mass and energy balances and showing the most attractive configurations from the point of view of total efficiency and CCR.

Comparison Between MCFC/Gas Turbine and MCFC/Steam Turbine Combined Power Plants

2003 ◽  
Author(s):  
Roberto Bove ◽  
Piero Lunghi
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Steam Turbine ◽  
Gas Turbine ◽  
Power Plants ◽  
High Efficiency ◽  
Electric Energy ◽  
Thermodynamic Efficiency ◽  
Molten Carbonate ◽  
Advantages And Disadvantages

Worldwide, the main power source to produce electric energy is represented by fossil fuels, principally used at the present time in large combustion power plants. The main environmental impacts of fossil fuel-fired power plants are the use of non-renewable resources and pollutants emissions. An improvement in electric efficiency would yield a reduction in emissions and resources depletion. In fact, if efficiency is raised, in order to produce an amount unit of electric energy, less fuel is required and consequently less pollutants are released. Moreover, higher efficiency leads to economic savings in operating costs. A generally accepted way of improving efficiency is to combine power plants’ cycles. If one of the combined plants is represented by a fuel cell, both thermodynamic efficiency and emissions level are improved. Fuel cells, in fact, are ultra-clean high efficiency energy conversion devices because no combustion occurs in energy production, but only electrochemical reactions and consequently no NOx and CO are produced inside the cell. Moreover, the final product of the reaction is water that can be released into the atmosphere without particular problems. Second generation fuel cells (Solid Oxide FC and Molten Carbonate FC) are particularly suitable for combining cycles, due to their high operating temperature. In previous works, the authors had analyzed the possibility of combining Molten Carbonate Fuel Cell (MCFC) plant with a Gas Turbine and then a MCFC with a Steam Turbine Plant. Results obtained show that both these configurations allow to obtain high conversion efficiencies and reduced emissions. In the present work, a comparison between MCFC-Gas Turbine and MCFC-Steam Turbine is conducted in order to evaluate the main advantages and disadvantages in adopting one solution instead of the other one.

scholarly journals Developmental Status of Hybrids

1999 ◽  
Author(s):  
Abbie Layne ◽  
Scott Samuelsen ◽  
Mark Williams ◽  
Patricia Hoffman
Keyword(s):  
Power Generation ◽  
Fuel Cells ◽  
Fuel Cell ◽  
Gas Turbine ◽  
High Efficiency ◽  
Combined Cycle ◽  
Pollutant Emission ◽  
Distributed Power Generation ◽  
Power Generation Technology ◽  
Generation Technology

Fuel cells are emerging as a major new power generation technology that is particularly suitable for distributed power generation, high-efficiency, and low pollutant emission. An interesting combined cycle, the “HYBRID,” has recently been scoped “on paper” that portends the potential of ultra-high efficiency (approaching 80%) in which a gas turbine is synergistically combined with a fuel cell into a unique combined cycle. This paper introduces hybrid technology to the gas turbine community as a whole, and summarizes the current and projected activities associated with this emerging concept.

Parametric Analysis and Optimization of a High Temperature Fuel Cell: Supercritical CO2 Turbine Hybrid System

2008 ◽  
Author(s):  
D. Sa´nchez ◽  
R. Chacartegui ◽  
A. Mun˜oz ◽  
T. Sa´nchez
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Hybrid Systems ◽  
Hybrid System ◽  
Operating Temperature ◽  
Inlet Temperature ◽  
Brayton Cycle ◽  
Molten Carbonate ◽  
Turbine Inlet Temperature

The integration of high temperature fuel cells — molten carbonate and solid oxide — and gas turbine engines for efficient power generation is not new. Different strategies for integrating both systems have been proposed in the past ten years and there are some field tests being run presently. However, the commercial availability of such power systems seems to be continuously delayed, probably due to cost and reliability problems. The materials used in high temperature fuel cells are expensive and their cost is not decreasing at the expected pace. In fact, it looks as if they had reached stabilization. Therefore, there seems to be agreement that operating at a lower temperature might be the only way to achieve more competitive costs to enter the market, as metallic materials could then be used. From the point of view of conventional hybrid systems, decreasing the operating temperature of the cell would affect the efficiency of the bottoming cycle dramatically, as long as turbine inlet temperature is a critical parameter for the performance of a Brayton cycle. This is the reason why hybrid systems perform better with solid oxide fuel cells operating at 1000 °C than with molten carbonate cells at 650 °C typically. This work presents a hybrid system comprising a high temperature fuel cell, either SOFC or MCFC, and a bottoming Brayton cycle working with supercritical carbon dioxide. A parametric analysis is done where all the parameters affecting the performance of the hybrid system are studied, with emphasis in the bottoming cycle. For the Brayton cycle: pressure ratio, expansion and compression efficiencies, recuperator effectiveness, pressure losses, turbine inlet temperature... For the fuel cell: fuel utilization, current density, operating temperature, etc. From this analysis, optimum operating point and integration scheme are established and, after this, a comparison with conventional hybrid systems using similar fuel cells is done. Results show that, although the fuel cell is not pressurized in the CO2 based system, its performance is similar to the best conventional cycle. Furthermore, if lower operating temperatures are considered for the fuel cell, the new system performs better than any of the conventional.

Comparison of a Multi-Megawatt High Temperature Fuel Cell System With Reciprocating Engines and Aero-Derivative Gas Turbines

2008 ◽  
Author(s):  
Georgia C. Karvountzi ◽  
Paul F. Duby
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Gas Turbines ◽  
Cell System ◽  
Combined Cycle ◽  
Simple Cycle ◽  
Fuel Cell System

High temperature fuel cells can be successfully integrated in a simple cycle or in a combined cycle configuration and achieve lower heating value (LHV) efficiencies greater than gas turbines and reciprocating engines. A simple cycle fuel cell system reaches 50 to 51% LHV efficiencies. A fuel cell system integrated with gas and steam turbines in a hybrid system could lead to LHV efficiencies of 70% to 72%. An aero-derivative gas turbine that is the most efficient simple cycle gas turbine achieves 40% to 46% thermal efficiency and a new generation reciprocating engine 39% to 42%. Upon integration in a combined cycle configuration with steam injection, aero-derivative gas turbines potentially reach LHV efficiencies of 55% to 58%. The purpose of the present paper is to compare initially the performance of a stand alone fuel cell with a stand alone gas turbine and a stand alone reciprocating engine. Then the fuel cell is integrated in a hybrid system and it is compared with a gas turbine combined cycle plant. The system sizes explored are 5MW in the stand alone case, and 20MW, 30MW, 60MW, 100MW and 200MW in the hybrid / combined cycle case. The performance of the hybrid system was reviewed under different ambient temperatures (0° F–90° F) and site elevations (0 ft–3000 ft). High temperature fuel cells are more efficient and have lower emissions than gas turbines and reciprocating engines. However fuel cells cannot be used for peak power generation due to long start-up time or load following applications.

Assessment of the Potential of Combined Micro Gas Turbine and High Temperature Fuel Cell Systems

2002 ◽  
Author(s):  
Dieter Bohn ◽  
Nathalie Po¨ppe ◽  
Joachim Lepers
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Advanced Materials ◽  
Cell Systems ◽  
Micro Gas Turbine ◽  
Technological Assessment

The present paper reports a detailed technological assessment of two concepts of integrated micro gas turbine and high temperature (SOFC) fuel cell systems. The first concept is the coupling of micro gas turbines and fuel cells with heat exchangers, maximising availability of each component by the option for easy stand-alone operation. The second concept considers a direct coupling of both components and a pressurised operation of the fuel cell, yielding additional efficiency augmentation. Based on state-of-the-art technology of micro gas turbines and solid oxide fuel cells, the paper analyses effects of advanced cycle parameters based on future material improvements on the performance of 300–400 kW combined micro gas turbine and fuel cell power plants. Results show a major potential for future increase of net efficiencies of such power plants utilising advanced materials yet to be developed. For small sized plants under consideration, potential net efficiencies around 70% were determined. This implies possible power-to-heat-ratios around 9.1 being a basis for efficient utilisation of this technology in decentralised CHP applications.

scholarly journals Effect of Cell Size on the Performance and Temperature Distribution of Molten Carbonate Fuel Cells

Energies ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1361 ◽  
Author(s):  
Jae-Hyeong Yu ◽  
Chang-Whan Lee
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Gas Flow ◽  
High Efficiency ◽  
Cross Flow ◽  
Current Density Distribution ◽  
Maximum Temperature ◽  
Similar Distribution ◽  
Molten Carbonate ◽  
Molten Carbonate Fuel Cells

Molten carbonate fuel cells (MCFCs) are high-operating-temperature fuel cells with high efficiency and fuel diversity. Electrochemical reactions in MCFCs are exothermic. As the size of the fuel cells increases, the amount of the heat from the fuel cells and the temperature of the fuel cells increase. In this work, we investigated the relationship between the fuel cell stack size and performance by applying computational fluid dynamics (CFD). Three flow types, namely co-flow, cross-flow, and counter-flow, were studied. We found that when the size of the fuel cells increased beyond a certain value, the size of the fuel cell no longer affected the cell performance. The maximum fuel cell temperature converged as the size of the fuel cell increased. The temperature and current density distribution with respect to the size showed a very similar distribution. The converged maximum temperature of the fuel cells depended on the gas flow condition. The maximum temperature of the fuel cell decreased as the amount of gas in the cathode size increased.

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