Hafnium in Nuclear Fuel Cladding Used Both as Oxidation Protection and Burnable Absorber

Author(s):  
Jiři Závorka ◽  
Radek Škoda

The problem with higher nuclear fuel enrichment is its high initial reactivity. It has a negative effect on the peaking factor, which is one of the license conditions. The second major problem is the ability to control the reactivity of the reactor, and thereby maintaining the multiplication factor in the core equal to 1. Long-term control of the reactivity in PWR reactors is typically conducted by the concentrated boric acid (H3BO3) in the coolant; its highest possible concentration is determined by the requirement to maintain a negative reactivity coefficient. Another option are burnable absorbers. This work deals with usage of hafnium as an advanced type of burnable absorber. Based on the model of computing code UWB1 for the study of burnable absorbers, a new cladding of nuclear fuel is designed with a thin protective layer made of hafnium. This cladding is used as a burnable absorber that helps reducing excess of fuel reactivity and prolongs the life of the fuel assemblies, which increases economic coefficient of the use of nuclear power plants. This cladding would also work as a protective layer increasing endurance and safety of nuclear power plants. Today zirconium alloys are exclusively used for this purpose. The main disadvantages of zirconium alloys include rapid high temperature oxidation of zirconium — a highly exothermic reaction between zirconium and water steam at temperatures above 800 °C. During this reaction hydrogen and inconsiderable amount of heat are released. Hydrogen excess, released heat, and damaged cover of fuel may deepen the severity and consequences of possible accidents. Another disadvantage of zirconium alloys is their gradual oxidation under standard operating conditions and ZrH formation, which leads to cladding embrittlement.

2018 ◽  
Vol 4 (2) ◽  
pp. 119-125
Author(s):  
Vadim Naumov ◽  
Sergey Gusak ◽  
Andrey Naumov

The purpose of the present study is the investigation of mass composition of long-lived radionuclides accumulated in the fuel cycle of small nuclear power plants (SNPP) as well as long-lived radioactivity of spent fuel of such reactors. Analysis was performed of the published data on the projects of SNPP with pressurized water-cooled reactors (LWR) and reactors cooled with Pb-Bi eutectics (SVBR). Information was obtained on the parameters of fuel cycle, design and materials of reactor cores, thermodynamic characteristics of coolants of the primary cooling circuit for reactor facilities of different types. Mathematical models of fuel cycles of the cores of reactors of ABV, KLT-40S, RITM-200M, UNITERM, SVBR-10 and SVBR-100 types were developed. The KRATER software was applied for mathematical modeling of the fuel cycles where spatial-energy distribution of neutron flux density is determined within multi-group diffusion approximation and heterogeneity of reactor cores is taken into account using albedo method within the reactor cell model. Calculation studies of kinetics of burnup of isotopes in the initial fuel load (235U, 238U) and accumulation of long-lived fission products (85Kr, 90Sr, 137Cs, 151Sm) and actinoids (238,239,240,241,242Pu, 236U, 237Np, 241Am, 244Cm) in the cores of the examined SNPP reactor facilities were performed. The obtained information allowed estimating radiation characteristics of irradiated nuclear fuel and implementing comparison of long-lived radioactivity of spent reactor fuel of the SNPPs under study and of their prototypes (nuclear propulsion reactors). The comparison performed allowed formulating the conclusion on the possibility in principle (from the viewpoint of radiation safety) of application of SNF handling technology used in prototype reactors in the transportation and technological process layouts of handling SNF of SNPP reactors.


Author(s):  
Koushik A. Manjunatha ◽  
Andrea Mack ◽  
Vivek Agarwal ◽  
David Koester ◽  
Douglas Adams

Abstract The current aging management plans of passive structures in nuclear power plants (NPPs) are based on preventative maintenance strategies. These strategies involve periodic, manual inspection of passive structures using nondestructive examination (NDE) techniques. This manual approach is prone to errors and contributes to high operation and maintenance costs, making it cost prohibitive. To address these concerns, a transition from the current preventive maintenance strategy to a condition-based maintenance strategy is needed. The research presented in this paper develops a condition-based maintenance capability to detect corrosion in secondary piping structures in NPPs. To achieve this, a data-driven methodology is developed and validated for detecting surrogate corrosion processes in piping structures. A scaled-down experimental test bed is developed to evaluate the corrosion process in secondary piping in NPPs. The experimental test bed is instrumented with tri-axial accelerometers. The data collected under different operating conditions is processed using the Hilbert-Huang Transformation. Distributional features of phase information among the accelerometers were used as features in support vector machine (SVM) and least absolute shrinkage and selection operator (LASSO) logistic regression methodologies to detect changes in the pipe condition from its baseline state. SVM classification accuracy averaged 99% for all models. LASSO classification accuracy averaged 99% for all models using the accelerometer data from the X-direction.


2014 ◽  
Vol 56 (5) ◽  
pp. 501-514 ◽  
Author(s):  
N. D. Goletskii ◽  
B. Ya. Zilberman ◽  
Yu. S. Fedorov ◽  
A. S. Kudinov ◽  
A. A. Timoshuk ◽  
...  

Kerntechnik ◽  
2004 ◽  
Vol 69 (3) ◽  
pp. 84-87
Author(s):  
H. R. V. de Oliveira ◽  
A. S. Martinez

1981 ◽  
Vol 11 ◽  
Author(s):  
Roger Thunvik ◽  
Carol Braester

The possibility of permanent burial of radioactive waste from nuclear power plants, is studied in Sweden at the KBS (Nuclear Fuel Safety) - project. Definite repository sites have not yet been selected, but the general principles of construction regarding the layout have been devised (KBS).


2019 ◽  
pp. 82-87
Author(s):  
Ya. Kostiushko ◽  
O. Dudka ◽  
Yu. Kovbasenko ◽  
A. Shepitchak

The introduction of new fuel for nuclear power plants in Ukraine is related to obtaining a relevant license from the regulatory authority for nuclear and radiation safety of Ukraine. The same approach is used for spent nuclear fuel (SNF) management system. The dry spent fuel storage facility (DSFSF) is the first nuclear facility created for intermediate dry storage of SNF in Ukraine. According to the design based on dry ventilated container storage technology by Sierra Nuclear Corporation and Duke Engineering and Services, ventilated storage containers (VSC-VVER) filled with SNF of VVER-1000 are used, which are located on a special open concrete site. Containers VSC-VVER are modernized VSC-24 containers customized for hexagonal VVER-1000 spent fuel assemblies. The storage safety assessment methodology was created and improved directly during the licensing process. In addition, in accordance with the Energy Strategy of Ukraine up to 2035, one of the key task is the further diversification of nuclear fuel suppliers. Within the framework of the Executive Agreement between the Government of Ukraine and the U.S. Government, activities have been underway since 2000 on the introduction of Westinghouse fuel. The purpose of this project is to develop, supply and qualify alternative nuclear fuel compatible with fuel produced in Russia for Ukrainian NPPs. In addition, a supplementary approach to safety analysis report is being developed to justify feasibility of loading new fuel into the DSFSF containers. The stated results should demonstrate the fulfillment of design criteria under normal operating conditions, abnormal conditions and design-basis accidents of DSFSF components.  Thus, the paper highlights both the main problems of DSFSF licensing and obtaining permission for placing new fuel types in DSFSF.


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