Astronomical pacing of relative sea level during Oceanic Anoxic Event 2: Preliminary studies of the expanded SH#1 Core, Utah, USA

2019 ◽  
Vol 131 (9-10) ◽  
pp. 1702-1722 ◽  
Author(s):  
Matthew M. Jones ◽  
Bradley B. Sageman ◽  
Rosie L. Oakes ◽  
Amanda L. Parker ◽  
R. Mark Leckie ◽  
...  
Keyword(s):  
Carbon Cycle ◽  
Sea Level ◽  
Carbon Isotope ◽  
Geochemical Data ◽  
Relative Sea Level ◽  
Data Set ◽  
Sequence Stratigraphic ◽  
Oceanic Anoxic Event ◽  
Oceanic Anoxic Event 2 ◽  
Anoxic Event

AbstractProximal marine strata of the North American Western Interior Basin (WIB) preserve a rich record of biotic turnover during Oceanic Anoxic Event 2 (OAE2; ca. 94 Ma), a pronounced Late Cretaceous carbon cycle perturbation interpreted to reflect global warming, widespread hypoxia, and possible ocean acidification. To develop a more robust synthesis of paleobiologic and geochemical data sets spanning this Earth-life transition, we drilled the 131 m Smoky Hollow #1 Core (SH#1), on the Kaiparowits Plateau of southern Utah, USA, recovering the Cenomanian–Turonian Boundary (CTB) interval in the Tropic Shale Formation. A 17.5 m positive excursion in high-resolution bulk carbon isotope chemostratigraphy (δ13Corg) of SH#1 characterizes the most expanded OAE2 record recovered from the mid-latitudes of the WIB.Depleted values in a paired carbonate carbon isotope (δ13Ccarb) chemostratigraphy cyclically punctuate the OAE2 excursion. These depletions correspond to intervals in the core with a higher degree of carbonate diagenesis and correlate well to an existing sequence stratigraphic framework of flooding surfaces in the shoreface facies of the Markagunt Plateau (∼100 km west). We detect statistically significant evidence for astronomical cycles in the δ13Ccarb data set, imparted by diagenesis at flooding surfaces, and develop a floating astronomical time scale (ATS) for the study interval. Stable eccentricity cycles (405 k.y.) align with stratigraphic sequences and associated trends in sedimentation rate, and short eccentricity cycles (∼100 k.y.) pace nested parasequences. These results confirm an astronomical signal and, therefore, climatic forcing of relative sea level during OAE2 in the WIB. Furthermore, cross-basin correlation of the ATS and expanded δ13C chemostratigraphy of SH#1 suggests that these transgressive-regressive parasequences modulated siliciclastic sediment delivery in the seaway and contributed to deposition of prominent rhythmically bedded CTB units across the WIB, including the Bridge Creek Limestone. The presented approach to analysis of these proximal offshore siliciclastic facies links early diagenetic influences on chemostratigraphy to astronomically modulated sequence stratigraphic horizons, and helps to resolve rates of paleobiologic and paleoenvironmental change during a significant Mesozoic carbon cycle perturbation.

Carbon isotope and sequence stratigraphy of the upper Isachsen Formation on Axel Heiberg Island (Nunavut, Canada): High Arctic expression of oceanic anoxic event 1a in a deltaic environment

2021 ◽  
Author(s):  
Wolf Dummann ◽  
Claudia Schröder-Adams ◽  
Peter Hofmann ◽  
Janet Rethemeyer ◽  
Jens O. Herrle
Keyword(s):  
Carbon Isotope ◽  
Sedimentary Environment ◽  
High Arctic ◽  
Geochemical Data ◽  
Sea Level Changes ◽  
Sequence Stratigraphic ◽  
Oceanic Anoxic Event ◽  
Stratigraphic Framework ◽  
Anoxic Event ◽  
Sverdrup Basin

<p>Oceanic anoxic event (OAE) 1a documents a major perturbation of the Early Cretaceous global carbon cycle with severe consequences for the ocean-climate-biosphere system. While numerous studies over the past decades have provided a relatively detailed picture of the environmental repercussions of OAE 1a at low and mid-latitudes, studies from high latitudes, in particular the High Arctic, are limited. In this study, we present a high-resolution carbon isotopic and sequence stratigraphic framework for the lower to lower upper Aptian interval of the Isachsen Formation of the High Arctic Sverdrup Basin (Canada). These data enable us to precisely locate the stratigraphic position of OAE 1a in a deltaic sedimentary environment. The carbon isotope record allows, for the first time, identification of the different carbon isotope segments (CISs) of OAE 1a in the Sverdrup Basin and thereby correlation of the High Arctic record with sections from lower latitudes. Based on this improved chemostratigraphy, we revise the age of upper Paterson Island, Rondon, and Walker Island Members, important regional lithostratigraphic marker units. Whole-rock geochemical data record two episodes of marine incursion into the Sverdrup Basin during OAE 1a (CISs Ap3 and Ap6), which are interpreted as regional maximum flooding surfaces. This information is used in conjunction with detailed sedimentological logs and geochemical grain-size proxies to refine the sequence stratigraphic framework for the upper Isachsen Formation. We propose that transgressive-regressive cycles in the Sverdrup Basin were mainly controlled by the combined effects of eustatic sea-level changes and regional tectonic uplift, potentially related to the emplacement of Alpha Ridge, which culminated at ca. 122 Ma during CIS Ap9.</p>

scholarly journals Carbon isotope and sequence stratigraphy of the upper Isachsen Formation on Axel Heiberg Island (Nunavut, Canada): High Arctic expression of oceanic anoxic event 1a in a deltaic environment

Geosphere ◽  
2020 ◽  
Author(s):  
W. Dummann ◽  
C. Schröder-Adams ◽  
P. Hofmann ◽  
J. Rethemeyer ◽  
J.O. Herrle
Keyword(s):  
Carbon Isotope ◽  
Sedimentary Environment ◽  
High Arctic ◽  
Geochemical Data ◽  
Sea Level Changes ◽  
Sequence Stratigraphic ◽  
Oceanic Anoxic Event ◽  
Stratigraphic Framework ◽  
Anoxic Event ◽  
Sverdrup Basin

The Early Cretaceous oceanic anoxic event (OAE) 1a documents a major perturbation of the global carbon cycle with severe consequences for the ocean-climate-biosphere system. While numerous studies over the past decades have provided a relatively detailed picture of the environmental repercussions of OAE 1a at low and mid-latitudes, studies from high latitudes, in particular the High Arctic, are limited. In this study, we present a high-resolution carbon isotopic and sequence stratigraphic framework for the lower to lower upper Aptian interval of the Isachsen Formation of the High Arctic Sverdrup Basin (Canada). These data enable us to precisely locate the stratigraphic position of OAE 1a in a deltaic sedimentary environment. The carbon isotope record allows, for the first time, identification of the different carbon isotope segments (CISs) of OAE 1a in the Sverdrup Basin and thereby correlation of the High Arctic record with sections from lower latitudes. Based on this improved chemostratigraphy, we revise the age of upper Paterson Island, Rondon, and Walker Island Members, important regional lithostratigraphic marker units. Whole-rock geochemical data record two episodes of marine incursion into the Sverdrup Basin during OAE 1a (CISs Ap3 and Ap6), which are interpreted as regional maximum flooding surfaces. This information is used in conjunction with detailed sedimentological logs and geochemical grain-size proxies to refine the sequence stratigraphic framework for the upper Isachsen Formation. We propose that transgressive-regressive cycles in the Sverdrup Basin were controlled mainly by the combined effects of eustatic sea-level changes and regional tectonic uplift, potentially related to the emplacement of Alpha Ridge, which culminated at ca. 122 Ma during CIS Ap9.

Onset of Oceanic Anoxic Event 2 in the Lower Saxony Basin – Insights fromhigh-resolution stable isotope stratigraphy and geochemical modelling

2021 ◽  
Author(s):  
Pia Müller ◽  
Ulrich Heimhofer ◽  
Christian Ostertag-Henning
Keyword(s):  
Organic Matter ◽  
High Resolution ◽  
Stable Isotope ◽  
Carbon Cycle ◽  
Geochemical Modelling ◽  
Positive Anomaly ◽  
Lower Saxony ◽  
Data Set ◽  
Oceanic Anoxic Event ◽  
Anoxic Event

<p>The Oceanic Anoxic Event (OAE) 2 spanning the Cenomanian-Turonian boundary (93.5 Ma)<br>represents a major perturbation of the global carbon cycle and is marked by organic-rich<br>sediments deposited under oxygen-depleted conditions. In many studies the eruption of the<br>Caribbean LIP is considered to be the cause for rapidly increasing CO2 concentrations and<br>resulting global warming accompanied by widespread oceanic anoxia. In the Lower Saxony<br>Basin of northern Germany, the deposits of the OAE 2 are exposed in several industry drill<br>cores. In this study, the lower part of the OAE 2 has been studied in the HOLCIM 2011-3 drill<br>core. Sedimentary rocks are composed of limestones, marly limestones, marls and black<br>shales and have been analysed with a high-resolution stable isotope approach<br>(approximately one sample every 2 cm) combined with geochemical modelling. Using stable<br>carbon isotopes, bulk rock parameters and petrographic analysis, the onset of OAE 2 has<br>been investigated in detail. The high-resolution δ<sup>13</sup>C curve exhibits overall stable values<br>around 3 ‰ before the onset of the Plenus event. This background level is interrupted by<br>three short-lived and small but significant negative carbon isotope excursions (CIEs) down to<br>δ<sup>13</sup>C values of 2.5 ‰, 2.7 ‰ and 1.9 ‰. Immediately before the main rise in the Plenus bed,<br>a longer-lasting negative CIE down to 2.8 ‰ is observed, preceding the large positive CIE of<br>the OAE 2 to values of 5.2 ‰ over 33 ka. Thereafter, the δ<sup>13</sup>C values decrease to 3.5 ‰ over<br>a period of approximately 130 ka. The results can be correlated with the lower-resolution<br>data set of Voigt et al. (2008) but enable a more accurate characterization of the subtle<br>features of the CIE and hence events before and during this time interval. Carbon cycle<br>modelling with the modelling software SIMILE using a model based on Kump & Arthur (1999)<br>reveals that the negative excursion before the Plenus bed can be explained by a massive<br>volcanic pulse releasing of 0.95*10<sup>18</sup> mol CO2 within 14 ka. This amount corresponds to only<br>81 % of the calculated volume of CO<sub>2</sub> release during emplacement of the Caribbean LIP by<br>Joo et al. (2020). In the model the volcanic exhalation increases atmospheric CO<sub>2</sub><br>concentrations. This will increase global temperatures, intensify the hydrological cycle and<br>thus increase nutrient input into the ocean, resulting in an expansion of the oxygen minimum<br>zone, the development of anoxic conditions and an increase in the preservation potential for<br>organic material. In the model enhanced primary productivity and organic matter preservation<br>can be controlled by the implemented riverine phosphate input and the preservation factor for<br>organic matter. For the positive anomaly, the riverine phosphate input must be nearly<br>doubled (from 0.01 μmol/kg PO<sub>4 </sub>to 0.019 μmol/kg) for the period of the increasing δ<sup>13</sup>C<br>values (app. 33 ka), with a concomitant rise of the preservation factor from 1 % to 2 %. This<br>model scenario accurately reproduces the major features of the new high-resolution δ<sup>13</sup>C<br>record over the onset of the OAE 2 CIE.</p>

Major palaeoenvironmental upheavals in both marine and terrestrial realms during the Toarcian oceanic anoxic event: a multi-proxy approach

2020 ◽  
Author(s):  
Francesca Galasso ◽  
Susanne Feist­Burkhardt ◽  
Annette Schmid- Röhl ◽  
Stefano Benasconi ◽  
Elke Schneebeli-Hermann
Keyword(s):  
Carbon Isotope ◽  
Seawater Temperature ◽  
Black Shales ◽  
Land Plants ◽  
Open Pit ◽  
Large Igneous Province ◽  
Isotopic Study ◽  
Data Set ◽  
Oceanic Anoxic Event ◽  
Anoxic Event

<p>The Toarcian oceanic anoxic event (TOAE) ~183 Ma is not only associated with oceanic anoxia and rapid seawater temperature increase but also with a marine mass extinction event. These biotic and environmental upheavals are linked to the emplacement of the Karoo-Ferrar large igneous province. Negative carbon excursions and widespread deposition of black shales are typical for Toarcian sedimentary successions.</p><p>The occurrence and growth of dinoflagellates is influenced by environmental factors like oxygen content, salinity, temperature and nutrient availability. For land plants, changes in dominance structure of ecosystems reflected in spore pollen assemblages can be indicative of ecological disturbance. Thus species composition (and morphology) of dinoflagellates and land plants can be used to understand major environmental perturbations.</p><p>An extensively studied TOAE section is the former Rohrbach Zement quarry at Dotternhausen (today Larfarge-Holcim) with comprehensive data of carbon isotope analyses, total organic and inorganic carbon content and rock eval analysis.<br>The Dotternhausen quarry is not accessible anymore but a new open pit in Dormettingen ~2 km NW of Dotternhausen offers excellent outcrop conditions. Litho- and biostratigraphy of the new section is well documented and calibrated to the old Dotternhausen section on subzone levels. Comparison of the two sites showed that sedimentology, geochemistry and faunal data are laterally constant. <br>Palynological analysis of 59 outcrop samples from the Dormettingen section yielded an excellent quantitative data set of the Early Toarcian Posidonienschiefer sediments. Here we provide a high-resolution, multi-proxy study of this section including chemostratigraphy, particulate organic matter and palynology in order to understand the environmental conditions during the TOAE.</p><p>Carbon isotopic study reveals a negative excursion during the TOAE, varying between -33.49‰ and -26.5‰, with a negative shift in the Falciferum Zone (Elengatum, Exeratum and Elegans Subzone) concurrent with the dinoflagellate "blackout".  The vegetation shows significant changes from a mixed assemblage of pollen and spores in the lower part of the section, to exclusively spore-bearing during the negative carbon isotope excursion. The isotopic signal, the marine dinoflagellate “blackout” and the changes in terrestrial vegetation indicate/document major palaeoenvironmental upheavals in both the marine and terrestrial realms.</p>

The Oceanic Anoxic Event 2 organic record in the South Iberian Paleomargin.

2021 ◽  
Author(s):  
Carolina Fonseca ◽  
João Graciano Mendonça Filho ◽  
Matías Reolid ◽  
Luís Vítor Duarte ◽  
Carine Lézin
Keyword(s):  
Sea Level ◽  
Source Area ◽  
First Record ◽  
Marine Phytoplankton ◽  
The South ◽  
Oceanic Anoxic Event ◽  
Organic Facies ◽  
Oceanic Anoxic Event 2 ◽  
Anoxic Event ◽  
Marine System

<p>The Cenomanian—Turonian boundary is marked by one of the warmest periods of the Mesozoic, associated with high <em>p</em>CO<sub>2</sub> levels and global sea-level highstands. Coupled to these extreme conditions is a massive magmatic episode, the establishment of worldwide marine anoxia, the deposition of organic-rich facies, and perturbations of the global carbon cycle, the so-called Oceanic Anoxic Event 2 (OAE2). In order to define the organic facies variability, this stratigraphic interval was analysed in the Baños de la Hedionda, a reference section positioned in the W part of the Internal Subbetic, representing the sedimentary record of a pelagic plateau located in the most distal part of the South Iberian Paleomargin. Regarding this goal, a high resolution study was developed on the Capas Blancas Formation (Capas Blancas, Black radiolaritic shales, and Boquerón members – Mb.), using organic petrographic and geochemical techniques. Carbon isotopic profile, for the isolated kerogen (δ<sup>13</sup>C<sub>kerogen</sub>), displays a positive excursion of ~2.5‰ observed in the Black radiolaritic shales Mb., which is in accordance with the worldwide recognized trend for the OAE2 isotopic record.</p><p>The pre-OAE2 is represented by the Capas Blancas Mb., with the majority of the samples of this unit showing no organic matter (OM) recovery (0.01—0.57 wt.% total organic carbon; TOC). Palynofacies analysis displayed an association co-dominated by the Amorphous and Palynomorph groups. The Amorphous Group is characterized mostly by marine phytoplankton-derived amorphous OM (AOM), while the Palynomorph Group is co-dominated by freshwater microplankton (Zygnemataceae and <em>Closteriu</em><span><em>m</em>) and choanoflagellates, with some specimens of marine microplankton, sporomorphs, and zoomorphs being also identified. The mixture of freshwater and marine components suggest deposition in a platform environment with shallow depths and oscillating oxygen regimen (oxic to dysoxic conditions). The freshwater components are most likely transported into the marine system due to the lower amorphization state, with the source area being in high proximity.</span></p><p>The OAE2, represented by the Black radiolaritic shales Mb., is characterized by a dominance of: (i) marine phytoplankton-derived AOM; (ii) plate-like bacterial AOM; and, (iii) sheet-like bacterial AOM with a cratered aspect (0.36—31.48 wt.% TOC). Choanoflagelates (with high degree of amorphization) at the base of the unit, zooclasts, sporomorphs, and solid bitumen are also present. The change in the organic facies suggests the occurrence of a transgressive phase. This organic facies is indicative of a relative sea level rise, with O<sub>2</sub> conditions deteriorating with the emplacement of reducing conditions, possibly related to an increase in primary productivity.</p><p>The post-OAE2, recognized in the Boquerón Mb., is characterized by a co-dominance of marine phytoplankton-derived AOM and palynomorphs, namely zoomorphs, and high percentages of opaque phytoclasts (below 0.25 wt.% TOC). Nevertheless, kerogen displays a reworked character and, therefore, data should be used with caution.</p><p>Furthermore, this study constitutes the first record of <em>Closterium</em> in sediments from the Cretaceous, and the first identification of choanoflagellates, the closest living relatives of Metazoa, in the fossil record.</p>

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