Kinetics of Coloration in Hydrogenated Vanadium Pentoxide Films under an Internal Electrochromic Effect

2018 ◽  
Vol 44 (9) ◽  
pp. 779-782
Author(s):  
S. V. Burdyukh ◽  
O. Ya. Berezina ◽  
P. P. Boriskov ◽  
A. L. Pergament ◽  
D. S. Yakovleva
Author(s):  
С.В. Бурдюх ◽  
О.Я. Березина ◽  
П.П. Борисков ◽  
А.Л. Пергамент ◽  
Д.С. Яковлева

AbstractThe kinetics of coloration in thin hydrogenated vanadium pentoxide films under the internal electrochromic effect is studied alongside with the influence of their hydrogenation by means of plasma-immersion ion implantation on this process. The variant of uniform implantation and the nonuniform case when a film is partially subjected to ion treatment are considered. Based on the experiments on measuring the electrochromically colored surface area growth rate and the passing current, it has been revealed that the electrochromic effect becomes much stronger in the nonuniform variant, when the cathode is placed on the nonhydrogenated part of a film, and the anode is located on its hydrogenated part.


1996 ◽  
Vol 453 ◽  
Author(s):  
I. A. Konovalov ◽  
V. B. Nechitajlo ◽  
E. Shushakova

AbstractReversible coloration occurs in tungsten trioxide (WO3) films when double injection of electrons and ions is provided in its volume. Experiments were performed in electrochemical cell with liquid electrolyte, where protons were used for injection in amorphous WO3 films. Kinetics of electrochromic coloration process was studied in spectral range of 300 nm to 1200 nm. Dependence of optical density on injected charge was found to be different in various spectral regions for coloring and bleaching. Infrared vibrational spectra of electro-chemically colored crystalline and amorphous WO3 were obtained. Electronic structure features of amorphous WO3 related to electorchromism are discussed.


2007 ◽  
Vol 25 (5) ◽  
pp. 335-345
Author(s):  
Narayandas Ganguly ◽  
Kallakuri Janakiram ◽  
Nabinkrishna Nag ◽  
Sudhirkumar Bhattacharyya

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