Thermodynamic estimation of the Rehbinder effect in the case of adsorption according to the Frumkin isotherm

2017 ◽  
Vol 53 (3) ◽  
pp. 393-403 ◽  
Author(s):  
E. M. Podgaetskii
2002 ◽  
Vol 67 (11) ◽  
pp. 1579-1588 ◽  
Author(s):  
Dorota Sieńko ◽  
Dorota Gugała ◽  
Jolanta Nieszporek ◽  
Joanna Jankowska ◽  
Jadwiga Saba

The results of thermodynamic analysis of o-toluidine adsorption on a mercury electrode in the presence of various butan-1-ol amounts complete our previous studies on properties of mixed adsorption layers of toluidine isomers-butan-1-ol. The values of the relative surface excess Γ'°T obtained for o-toluidine show that adsorption of this compound decreases with increasing of butan-1-ol concentration. Analysis of adsorption parameters derived from the Frumkin isotherm indicates that in the presence of 0.33 M BuOH in 1 M NaClO4 with adjusted pH 3 as supporting electrolyte, ∆G0 values for o-toluidine are the highest and, at the same time, the strongest repulsive interaction occurs. In the presence of 0.11 M butan-1-ol, smaller values of ∆G0 for o-toluidine correspond to weaker repulsive interaction. Therefore the change of the Γ'°T value for o-toluidine as a function of butan-1-ol concentration is the result of mutual changes of ∆G0 and interaction constant A between adsorbate molecules.


Author(s):  
Pamela Allison Manco Urbina ◽  
Marcello Berto ◽  
Pierpaolo Greco ◽  
Matteo Sensi ◽  
Simone Borghi ◽  
...  

Label free biosensors based on electrolyte gated organic transistors (EGOTs) are ultra-sensitive and versatile sensing devices. The dose curve represents the change of the sensor signal as a function of...


1966 ◽  
Vol 181 (1) ◽  
pp. 687-705 ◽  
Author(s):  
P. L. Barlow

It has previously been suggested that the reduction in cutting forces obtained by the presence of fluids such as CCl4 on the backface or free surface of the forming chip was due to diffusion of the fluid into the body of the chip in the region of the shear zone. In the present work, experiments with carbon tetrachloride tagged with carbon-14 and with carbon tetrachloride tagged with chlorine-36 were performed with the object of assessing the extent of diffusion of lubricants into the chip when present on the free surface only. The results obtained disprove former hypotheses and suggest that the reduced cutting force is due solely to chemical reaction at the surface of the chip. Confirmation of the sensitivity of the surface of the deforming shear zone to change in surface condition was obtained by removing metal from this region by an electropolishing technique during slow speed cutting. By varying the electropolishing conditions increased or decreased cutting forces could be obtained. It is proposed that the result both of chemical reaction at the surface and of surface removal is to reduce the strain-hardening rate of the metal undergoing shear by reducing the surface barrier to the flow of dislocations out of the metal. The association of the surface reaction of carbon tetrachloride with a change in the strain-hardening characteristics of the metal in the shear zone leads to a classification of the backface phenomenon as a Rehbinder effect and enables this effect to be more closely defined than was hitherto possible. Evidence is also presented which indicates that the backface effect does not contribute to the reduction in cutting forces during rakeface lubrication and is therefore unimportant in practice where flood lubrication of the cutting region invariably occurs.


2018 ◽  
Vol 256 ◽  
pp. 131-144 ◽  
Author(s):  
Alexey A. Fedorov ◽  
Alexander I. Blesman ◽  
Denis V. Postnikov ◽  
Denis A. Polonyankin ◽  
Gregory S. Russkikh ◽  
...  

Nature ◽  
1949 ◽  
Vol 164 (4183) ◽  
pp. 1127-1127 ◽  
Author(s):  
E. N. DA C. ANDRADE ◽  
R. F. Y. RANDALL
Keyword(s):  

1969 ◽  
Vol 9 (04) ◽  
pp. 425-433 ◽  
Author(s):  
A.A. Selim ◽  
C.W. Schultz ◽  
K.C. Strebig

Abstract The effect of some organic additives in diamond drilling of quartzite was investigated in the laboratory. The drill was designed to measure the rate of penetration, the trust, and the torque and to record penetration, the trust, and the torque and to record each as a function of the distance drilled. A statistical plan was followed throughout the investigation and an equation representing the bit performance was derived from the mathematical performance was derived from the mathematical theory to reliability. The drilling torque was found to increase with the use of additives while the sliding coefficient of friction and the wear coefficient decreased. The energy per unit volume consumed was found to increase with the use of additives. A hypothesis explaining the effects achieved with the additives is given. Introduction For some time researchers have attempted to increase drilling efficiency by adding certain agents to the flushing medium. Much of this interest is the result of the observations of Rehbinder, Shreiner and Zhigach. The postulate that "...in processes for the mechanical destruction of solids, a region of increased crack formation is created in the deformed layers adjoining the surface of destruction, forming the predestruction zone. The surrounding medium (for example, a liquid which wets a given solid will penetrate the embryo micro cracks of the predestruction penetrate the embryo micro cracks of the predestruction zone. Increasing the molecular affinity of this liquid for the surface of the solid considerably facilitates the deformation and destruction by softening the solid in the zone of increased crack formation. In this manner, the hardness or strength of the deformed body is decreased by the influence of the penetration of the liquid into the predestruction zone." This is known as the "Rehbinder effect". Rehbinder's work has prompted many investigators to examine the effect of additives on the mechanical destruction of rocks. Engelmann, Terichow and Selim reported that the maximum penetration of the rock by a diamond point in a solution environment was at the isoelectric point of the solution. Robinson reported that his point of the solution. Robinson reported that his results did not appear to support the theory of Rehbinder. Joris and McLaren suggested that additives with surface tension lower than water will be more efficient in cooling the diamonds. Their effectiveness in removing the fine cuttings from the face of the bit will also improve the efficiency of the system. They reported an improvement in impregnated bit life and penetration rates with the use of soluble oil additives. In contrast, Long and Agnew, drilling with surface set bits, reported that lubricating agents increase bit temperature and wear. A significant change was reported in the mechanical properties of rock with polar additives. It properties of rock with polar additives. It was concluded that this change in the mechanical properties of the rock in the presence of the additive properties of the rock in the presence of the additive is due to the rock hydrophilic properties. Ethylene glycol, glycerine and anionic detergent were selected for this investigation because their surface tension is lower than that of water. The surface tension of these additives for the concentrations studied was 42 to 75 percent of the surface tension of water. A low surface tension additive would wet the surface of the diamonds more easily and hence would be more effective in cooling the diamonds. Another characteristic of these low surface tension additives is their effectiveness in removing the cuttings and preventing the flocculation of the formed particles in the drilling process. This article summarizes the results of an investigation performed at the laboratories of USBM, Twin performed at the laboratories of USBM, Twin Cities Mining Research Center. The objective of the investigation was to study the over-all effects of some organic additives on the performance of diamond impregnated bits in atmospheric drilling conditions only and not in downhole pressured conditions. SPEJ p. 425


Nature ◽  
1966 ◽  
Vol 211 (5053) ◽  
pp. 1076-1077 ◽  
Author(s):  
P. L. BARLOW

2006 ◽  
Vol 42 (10) ◽  
pp. 1073-1078 ◽  
Author(s):  
M. I. Volkova-Gugeshashvili ◽  
A. G. Volkov ◽  
V. S. Markin

1983 ◽  
Vol 48 (4) ◽  
pp. 964-975 ◽  
Author(s):  
Ladislav Novotný ◽  
Ivan Smoler ◽  
Jaroslav Kůta

Using drop-time technique with long drop-times achieved by means of a spindle-type capillary with the combination of a interrupted convection the surface tension data of tetrabutylammonium perchlorate in 0.1 mol l-1 NaClO4 in the concentration range 3 . 10-3 mol l-1 down to 10-7 mol l-1 could be measured. The corresponding adsorption parameters have been evaluated both from Langmuir (for Θ ⪬ 0.8) and Frumkin isotherm. The maximum energy of adsorption amounts to -48.1 kJ . mol-1. The dependence of E vs log c (Yesin-Markov plot) carried out in the concentration range 10-7 to 10-3 mol l-1 showed a S-shaped curve.


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