The gauche effect on conformation. α-Substituted sulfones and N-substituted sulfonamides
1979 ◽
Vol 44
(11)
◽
pp. 3378-3384
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Keyword(s):
The dipole moments of α-halogenosulfones IIa-f in benzene solution revealed the conformation C, those of N-methyl-N-nitrosulfonamides IIIa-c the conformation F. In either case the conformational preference is governed by the gauche rule which may be worded in a modified version that symmetrical positions of polar bonds and/or of lone electron pairs are disfavoured. A lone electron pair appears to be more significant than a polar bond.
1996 ◽
Vol 52
(1)
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pp. 7-15
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Spatial dispersion of lone electron pairs? – Experimental charge density of cubic arsenic(iii) oxide
2015 ◽
Vol 17
(16)
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pp. 11020-11027
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Keyword(s):
Keyword(s):
1980 ◽
Vol 35
(4)
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pp. 415-417
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Keyword(s):
Keyword(s):
1973 ◽
Vol 51
(15)
◽
pp. 2423-2432
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Keyword(s):