The effect of systematic errors of the equilibrium distribution concentrations on the number of stages of countercurrent extraction with various consumption of extractant

1989 ◽  
Vol 54 (4) ◽  
pp. 981-989
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Distribution ◽  
Systematic Errors ◽  
Mutual Solubility ◽  
Operating Conditions ◽  
Liquid Equilibrium ◽  
Countercurrent Extraction ◽  
Absolute Deviation ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number

On using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve, the effect is evaluated of systematic errors in the form of absolute deviation in the liquid-liquid equilibrium distribution concentrations on the accuracy of calculated number of theoretical stages of isothermal countercurrent extraction under various operating conditions.

The effect of random and systematic errors of the equilibrium distribution concentrations on the number of stages of countercurrent extraction with various consumption of solvent

1990 ◽  
Vol 55 (5) ◽  
pp. 1162-1174
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Distribution ◽  
Systematic Errors ◽  
Mutual Solubility ◽  
Operating Conditions ◽  
Binodal Curve ◽  
Liquid Equilibrium ◽  
Countercurrent Extraction ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number

On using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve, the effect is evaluated of random and systematic errors in the liquid-liquid equilibrium distribution concentrations on the accuracy of calculated number of theoretical stages of isothermal countercurrent extraction under different operating conditions.

Systematic errors in equilibrium composition of ternary liquid-liquid systems and their effect on the calculated number of theoretical stages of countercurrent extraction

1988 ◽  
Vol 53 (6) ◽  
pp. 1172-1180
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Composition ◽  
Systematic Errors ◽  
Liquid Equilibrium ◽  
Countercurrent Extraction ◽  
Liquid Systems ◽  
Equilibrium Concentrations ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number

The influence of magnitude of systematic errors in the determination of ternary liquid-liquid equilibrium concentrations on the accuracy of the calculated number of theoretical stages of countercurrent extraction is evaluated on using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve.

Random errors in equilibrium composition of ternary liquid-liquid systems and their effect on the calculated number of theoretical stages of countercurrent extraction

1988 ◽  
Vol 53 (1) ◽  
pp. 34-44
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Composition ◽  
Random Errors ◽  
Liquid Equilibrium ◽  
Liquid Systems ◽  
Equilibrium Concentrations ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number ◽  
Countercurrent Extractor

The influence of size of random errors in the determination of ternary liquid-liquid equilibrium concentrations on the accuracy of the calculated number of theoretical stages of a countercurrent extractor is evaluated by using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve.

Effect of Errors in Temperature Measurement on the Accuracy of Composition of the Liquid-Vapour Phases and Their Impact on the Calculated Number of Theoretical Stages of Rectification Columns

1992 ◽  
Vol 57 (9) ◽  
pp. 1867-1878
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Phase Composition ◽  
Binary Systems ◽  
Equilibrium Temperature ◽  
Systematic Errors ◽  
Operating Conditions ◽  
Rectification Column ◽  
Relative Volatility ◽  
The Impact ◽  
Calculated Number

The effect of random and systematic errors in the determination of the equilibrium temperature on the phase composition in isobaric L-G equilibria was simulated on five binary systems with different size and relative volatility. The impact of the inaccuracies on the calculated number of theoretical stages of a continuously operating rectification column is discussed with respect to the different operating conditions of the separatory process.

A New Heat Transfer Correlation for Supercritical RP-3 Flowing in Vertical Tubes

2017 ◽  
Author(s):  
Longyun Wang ◽  
Zhi Tao ◽  
Jianqin Zhu ◽  
Haiwang Li ◽  
Zeyuan Cheng
Keyword(s):  
Heat Transfer ◽  
Influence Factors ◽  
Hydrocarbon Fuel ◽  
Operating Conditions ◽  
Major Influence ◽  
Absolute Deviation ◽  
New Correlation ◽  
Vertical Tubes ◽  
Correction Terms ◽  
Good Agreement

A new empirical correlation for upward flowing supercritical aviation kerosene RP-3 in the vertical tubes is proposed. In order to obtain the database, numerical simulation with a four-component surrogate model on RP-3 and LS low Reynolds turbulence model in vertical circular tube has been performed. Tubes of diameter 2mm to 10mm are studied and operating conditions cover pressure from 3MPa to 6MPa. Heat flux is 500KW/m2, mass flow rate is 700kg/(m2·s). The numerical results on wall temperature distribution under various conditions are compared with experimental data and a good agreement is achieved. The existing correlations are summarized and classified into three categories. Three representative correlations of each category are selected out to evaluate the applicability in heat transfer of supercritical RP-3. The result shows that correlations concluded from water and carbon-dioxide do not perform well in predicting heat transfer of hydrocarbon fuel. The mean absolute deviation of them is up to 20% and predict about 80% of the entire database within 30% error bands. So a new correlation which is applicable to different working conditions for supercritical RP-3 is put forward. Gnielinski type has been adapted as the basis of the new correlation for its higher accuracy. In consideration of major influence factors of supercritical heat transfer, correction terms of density and buoyancy effect are added in. The new correlation has a MAD of 9.26%, predicting 90.6% of the entire database within ±15% error bands. The comparisons validate the applicability of the new correlation.

scholarly journals Experimental and an electrolyte non-random two-liquid model to predict the vapor–liquid equilibrium of CO2 in aqueous solutions of diethylenetriamine

2020 ◽  
pp. 174751982096417
Author(s):  
Ruilei Zhang ◽  
Yandong Tang ◽  
Weifeng Shan ◽  
Haijun Liu ◽  
Haijun Li ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Saturated Vapor ◽  
Physical Parameters ◽  
Liquid Equilibrium ◽  
Absolute Deviation ◽  
Vapor Liquid Equilibrium ◽  
Liquid Theory ◽  
Equilibrium Data ◽  
Experimental Values ◽  
Vapor Liquid

The absorption and desorption data of CO2 in aqueous solutions with a mass fraction of 10% and 20% of diethylenetriamine are measured at 313.15, 343.15, 373.15, and 393.15 K. The electrolyte non-random two-liquid theory is developed using Aspen V9.0 to correlate and predict the vapor–liquid equilibrium of CO2 in aqueous diethylenetriamine solutions. The model predicted the heat capacity and saturated vapor pressure data of diethylenetriamine, the mixed heat of a diethylenetriamine–H2O binary system, and the vapor–liquid equilibrium data of a diethylenetriamine–H2O–CO2 ternary system. The physical parameters and the interaction parameters of the model system are calculated. The model predicted CO2 solubility showing a 10% average absolute deviation from experimental data. The calculated values of the model are basically consistent with the experimental values.

scholarly journals Application of COSMO-RS Method for the Prediction of Liquid-Liquid Equilibrium of Water/n-Dodecane/1-Butanol

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
S. Balasubramonian ◽  
Shekhar Kumar ◽  
D. Sivakumar ◽  
U. Kamachi Mudali
Keyword(s):  
Activity Coefficient ◽  
Mutual Solubility ◽  
Solubility Data ◽  
Interaction Parameters ◽  
Binary Interaction ◽  
Liquid Equilibrium ◽  
Model Interaction ◽  
Uniquac Model ◽  
Unifac Model ◽  
Lle Data

The liquid-liquid equilibrium (LLE) for the system water-dodecane-butanol was estimated using the UNIQUAC model. In the UNIQUAC model interaction parameters were estimated from the vapor-liquid equilibrium (VLE) and LLE data of their constituent binary pairs. The water-dodecane-butanol LLE was experimentally measured at 298.15 K. Phase stability constraints were taken into account while calculating the binary interaction parameters from the mutual solubility data. The COSMO-RS method was used to estimate the activity coefficient in the miscible binary pair. The ternary LLE composition was predicted using the experimental VLE data as well as using the COSMO-RS calculated activity coefficient data along with the experimental mutual solubility data. In the latter case the root mean square deviation (RMSD) for the distribution of butanol between aqueous and organic phase is 0.24%. The corresponding UNIFAC model prediction is 7.63%.

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