Is a Gas-Phase Cannizzaro-Type Reaction Perspective?
1997 ◽
Vol 62
(2)
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pp. 147-153
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Keyword(s):
Quantum chemical calculations for model processes CH2=O + CH2=O-• ⇌ CH3O- + CH=O• and C6H5CH=O + C6H5CH=O-• ⇌ C6H5CH2O- + C6H5C=O• indicate convincingly their endoergicity. Therefore, spontaneous gas-phase Cannizzaro-type reaction between formaldehyde and benzaldehyde and their radical anions is unlikely to occur. This suggests a significant difference between the gas phase reaction under investigation and the classical Cannizzaro reaction.
2009 ◽
Vol 11
(26)
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pp. 5331
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2019 ◽
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2004 ◽
Vol 126
(21)
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pp. 6816-6824
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2019 ◽
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2012 ◽
Vol 217-219
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pp. 2497-2500
1987 ◽
Vol 81
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pp. 147-164
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