The formation of structure regularities in the recrystallized near-surface layer after restoration by heat treatment process of nickel-based high-temperature strength alloys

In modern nickel nickel-based high-temperature strength alloys of the ZhS32 type with a directional and single-crystal structure on surfaces that were previously subjected to mechanical treatment, with the subsequent isothermal exposure in the vicinity of the homogenization temperature lasting more than 15 minutes a subsurface recrystallized layer up to 40-65 μm deep is formed such us a chain of grains. The formation of this layer is a side effect that restrained the industrial application of vacuum heat treatment to restore local operational degradation ("raft"-structure) on the overheated inlet edges of non-bandage shelved gas-cooled high-pressure turbine blades of some modern aircraft turbine engines. Given the technical complexity of reliable removal of this recrystallized layer from the tract surface of thin-walled gas-cooled blades, it is important to develop technological measures to translate grain boundaries in unremoved residues of recrystallized near-surface layer into a safer structural state. The regularities of recrystallized layer formation in the process of 3-stage reductive vacuum treatment has been investigated by the methods of raster electron microscopy and X-ray structural (EDX) microanalysis at magnification up to × 2000 on fragments of TVT blades with ZhS26-VI alloy (directional structure) and ZhS32-VI alloy (monocrystalline structure). It has been established that the recrystallized layer formed in the process of aging 1.25-1.5 hours at the temperature of alloy homogenization, is a chain of grain with a tightly packed γ׳-phase with layers at their boundaries, which consist of the non-reinforcing γ׳-phase up to 1-3 μm wide with the carbide phases presence. It has been shown that the rational choice of the temperature of high-temperature aging is an effective technological control of the grain boundaries structural state in a near-surface recrystallized layer of the considered high-temperature strength alloys. Assigning a temperature of 1050°C for isothermal exposure after homogenization heat treatment for ZhS26 and ZhS32 alloys allows to reduce the grain boundaries width in the recrystallized layer to 1-2 μm, keep them intermittent and avoid systematic release of carbide particles at the grain boundaries. On the basis of established in the Paton welding institute of regularities of formation and control of the structure of the near-surface recrystallized layer developed technological recommendations for optimizing the vacuum heat treatment modes to restore the structure of non-bandage shelved gas-cooled high-pressure turbine blades with type ZhS32 high-temperature strength alloys. This technology has passed experimental and practical testing during the next maintenance cycle of flight operation on one of the modern turbojet double-circuit gas turbine engines with afterburner combustion chamber. Keywords: nickel nickel-based high-temperature strength alloys, vacuum heat treatment, restoration of alloys structure, subsurface recrystallized layer, raster electron microscopy.

Effect of Vacuum Heat Treatment on Microstructures and Mechanical Properties of 7A52 Aluminum Alloy-Al2O3 Ceramic Brazed Joints

This study investigated the interface morphology, microstructure composition and connection strength of 7A52 aluminum alloy-Al2O3 ceramic brazed joints under heat treatment conditions. Alumina ceramics were first treated with electroless nickel plating, followed by vacuum heat treatment at different temperatures. Then an Al-Si-Mg intermediate layer was placed between the treated alumina ceramic and 7A52 aluminum alloy for brazing under the conditions of welding temperature 590, holding time 1h, pressure 2 MPa. Results showed that when heat treatment was performed at 350°C and below, the nickel-plated metal had an amorphous structure, and when performed at 400°C, the nickel-plated layer had a crystalline structure and the brittle phase Ni3P was precipitated. When the heat treatment temperature was 350°C, the joint shear strength reached the maximum, which was 68.7 MPa.