The close relation between cyclic delocalization, energy effects of cycles and aromaticity

2009 ◽  
Vol 74 (1) ◽  
pp. 147-166 ◽  
Author(s):  
Robert Ponec ◽  
Stijn Fias ◽  
Sofie Van Damme ◽  
Patrick Bultinck ◽  
Ivan Gutman ◽  
...  
Keyword(s):  
Resonance Energy ◽  
Close Relation ◽  
Close Correlation ◽  
Delocalization Energy ◽  
Conjugated Circuits ◽  
Polycyclic Aromatic ◽  
New Evidence ◽  
Topological Resonance Energy ◽  
Local Nature

New evidence questioning the multidimensionality of the aromaticity phenomenon exemplified in what is called orthogonality between the classical (structural and energetic) and magnetic aromaticity indices and measures is reported. For this purpose, the recently proposed methodologies for the quantitative characterization of the energy benefits associated with the cyclic arrangement of mobile π-electrons in polycyclic aromatic hydrocarbons are compared with the indices characterizing the extent of cyclic delocalization in the corresponding conjugated circuits. The reported close correlation between both types of indices implies that no discrepancies between classical and magnetic aromaticity measures exist provided the comparison is based on the indices of inherently local nature and/or the interfering contributions of contaminating conjugated circuits is properly taken into account in the description of aromaticity measures like topological resonance energy (TRE) or nucleus independent chemical shift (NICS).

A Characterization of Some Geometries of Chains

1974 ◽  
Vol 26 (02) ◽  
pp. 257-272 ◽  
Author(s):  
Yi Chen
Keyword(s):  
Projective Plane ◽  
Minkowski Plane ◽  
Close Relation ◽  
Laguerre Plane ◽  
Geometric Structures ◽  
Möbius Plane

The geometries considered here are the Möbius plane M() (W. Benz [1]), the Laguerre plane L() (W. Benz and H. Mäurer [7]) and the Minkowski plane A() (W. Benz [5], G. Kaerlein [18]) over a field . All of them are geometries of an algebra with identity over a field. The characterization of the projective plane over a field by the proposition of Pappus first gave a close relation between algebraic and geometric structures. B. L. v. d. Waedern and L. J. Smid [28] presented a further example by characterizing the Möbius and Laguerre plane with incidence axioms and the "complete" proposition of Miquel.

scholarly journals POLIMORPHIC CHARACTERIZATION OF ESR1 AND FOXL2 GENES AND THE ASSOCIATION OF THEIR INTERACTION WITH PRODUCTIVE TRAITS OF BROWN LOCAL IRAQI CHICKENS

2021 ◽  
Vol 52 (6) ◽  
pp. 1391-1400
Author(s):  
R. I. A. Abu-Rekaiba ◽  
E. H. AL-Anbari ◽  
W. M. Razuki
Keyword(s):  
Production Performance ◽  
Production Traits ◽  
Chi Square ◽  
Beneficial Effects ◽  
Egg Formation ◽  
Hardy Weinberg Equilibrium ◽  
Productive Traits ◽  
Chi Square Analysis ◽  
New Evidence

The estrogen receptor 1(ESR1) and fork-head box L2 (FOX L2) genes play a pivotal role in regulation of egg formation in poultry. this study aimed to investigate interaction between ESR1 and FOXL2 in the productive performance of brown local Iraqi chickens (BLIC). A total of 104 BLIC represented from the F4th generation of local chicken selected for high egg productions were used. Two novel single nucleotide polymorphism (SNPs), one of them in ESR1 (T57198C) intron 3, and another of FOX L2 (C919T) gene within encoding region were identified through PCR-DNA sequencing. Six haplotypes (H1=TTCC, H2=TTCT, H3=TCCC, H4=TCCT, H5=CCCC, H6=CCCT) were obtained due to interaction between these two SNPs. Chi-square analysis showed no significant  in genotypic and allelic frequencies for each SNP which revealed that both genes were agreement with Hardy-Weinberg equilibrium. Association analysis of haplotypes with production traits revealed that individuals have H4 genotype achieved higher body weight at sexual maturity, at 60 weeks of age and egg weight at 45 and 60 weeks of age, whereas, the higher number of eggs were exhibited in individual with H6 from onset egg till 60 weeks of age. The two haplotypes; H4(TCCT) and H6(CCCT) showed better combination than others with respect to production performance. In conclusion, our findings provided new evidence that the two genes (ESR1 and FOXLl2) with special interaction may have potential effects on productive traits of chickens and beneficial effects in laying breeding programs.

scholarly journals Characterization of Polycyclic Aromatic Hydrocarbons and Bioaugmentation Potential of Locally Isolated Beneficial Microorganisms Consortium for Treatment of Tar-Balls

2021 ◽  
Vol 19 (3) ◽  
pp. 246-254
Author(s):  
Nur Zaida Zahari ◽  
◽  
Erma Hani Baharudzaman ◽  
Piakong Mohd Tuah ◽  
Fera Nony Cleophas ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Microbial Population ◽  
Oil Spills ◽  
Beneficial Microorganisms ◽  
Tar Balls ◽  
Polycyclic Aromatic ◽  
Biodegradation Study ◽  
Bioreactor System

Oil spills are one of the environmental pollutions that commonly occur along coastal areas. Tar-balls are one of the products that come from the oil spill pollution. In this study, tar-ball pollution was monitored at 10 points along the coastline of Marintaman Beach in Sipitang, Sabah, Malaysia. This research determined the physical characteristics, composition, and concentration of Polycyclic Aromatic Hydrocarbons (PAHs) in tar-balls. The total number of tar-balls collected was 227 (n=227). The tar-balls were observed in various shapes and the sizes were recorded in the range of 0.1 cm to 6.9 cm. The composition and concentration of Polycyclic Aromatic Hydrocarbons (PAHs) in the outer and inner layer of tar-balls were determined. The results showed that the main Polycyclic Aromatic Hydrocarbons (PAHs) compounds were found in inner layers of the tar-balls with benzo (g,h,i) perylene (72.26 mg/kg), flourene (59.87 mg/kg), dibenzo (a,h) anthracene (44.48 mg/kg), indeno (1,2,3-c,d) pyrene (78.18 mg/kg), and benzo (e) fluoranthene (45.70 mg/kg), respectively. Further research was done with the bioaugmentation study of locally isolated beneficial microorganisms (LIBeM) consortium for treatment of tar-balls in an Aerated Static Pile (ASP) bioreactor system. The results showed that, after 84 days of treatment, this consortium, consisting of C. tropicalis-RETL-Cr1, C. violaceum-MAB-Cr1, and P. aeruginosa-BAS-Cr1, was able to degrade total petroleum hydrocarbon (TPH) by 84% as compared to natural attenuation (19%). The microbial population of this consortium during the biodegradation study is also discussed in this paper.

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