STUDIES ON RDX AND RELATED COMPOUNDS: II. THE NITROLYSIS OF HEXAMINE IN ACETIC ACID
1950 ◽
Vol 28b
(11)
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pp. 715-719
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Acetic acid has a harmful effect on the reaction rate and on the yield of RDX at 1 °C. and at 30 °C. for a given nitric acid – hexamine ratio below a certain optimum value. At the optimum, however, the maximum yield of 80% is obtained at both temperatures. The deleterious effect of acetic acid may be explained by assuming that the concentration of the active nitrolyzing agent (nitracidium ion) is decreased by reaction between acetic acid and nitric acid.
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1973 ◽
Vol 31
◽
pp. 468-469
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1980 ◽
Vol 45
(7)
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pp. 2120-2124
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1970 ◽
Vol 19
(5)
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pp. 573-615
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1955 ◽
Vol 77
(3)
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pp. 533-535
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