Major-, trace-, and rare-earth-element geochemistry of the Archaean Maggo gneisses, southern Nain Province, Labrador

1991 ◽  
Vol 28 (1) ◽  
pp. 44-57 ◽  
Author(s):  
Gregory C. Finn

The early middle Archaean Maggo gneisses of the southern Nain Province, Labrador, form the southwest portion of the once contiguous North Atlantic (Nutak) Craton (NAC). The gneisses and their late middle Archaean metamorphosed and migmatized equivalents are typical of grey gneiss terranes exposed worldwide. Geochemically the gneisses exhibit a continuous range of composition from 53.7 to 78.4 wt.% SiO2 and straddle the boundary between low- and high-Al trondhjemites. Major-element distributions are comparable to those of other Archaean-aged NAC gneisses (Amîtsoq, Uivak, and Nûk gneisses), however, the Na2O and K2O contents are scattered. The gneisses are depleted in K, Rb, and Ba, are enriched in Sr, and have high-field-strength-element distributions similar to those for NAC gneisses.Rare-earth-element (REE) patterns of Maggo gneisses can be subdivided, on the basis of the nature of the Eu anomaly, into two groups of samples: (i) with negative Eu anomalies and higher Σ REE contents and (ii) with positive to normal Eu anomalies and lower Σ REE contents. The subdivision reflects differentiation processes in the parent magma of the Maggo gneisses. REE patterns are similar to those reported for NAC grey gneiss complexes. On the basis of the (La/Yb)N and (Yb)N values, the Maggo gneisses parent magma is interpreted as being derived by partial-melting processes from preexisting, high-grade (granulite to amphibolite facies) sialic continental crust equivalent to the early Archaean lithologies preserved elsewhere in the NAC.

Clay Minerals ◽  
2005 ◽  
Vol 40 (1) ◽  
pp. 131-151 ◽  
Author(s):  
E. Abdioğlu ◽  
M. Arslan

AbstractA number of bentonitic clay deposits from the Ordu area (NE Turkey) have been investigated by optical and electron microscopy, X-ray diffraction and chemical analysis. The clays are the alteration products of Late Cretaceous trachytic and trachyandesitic pyroclastic rocks. They contain volcanogenic sanidine, plagioclase, biotite and pumice, along with the diagenetic minerals opal-CT, cristobalite and rare calcite and zeolite (clinoptilolite). Ca-smectite (montmorillonite) is the dominant clay mineral. The rare earth element patterns of all the bentonitic clays are generally similar, although there are variations in the Eu anomaly indicating formation from different types of pyroclastic rocks. Oxygen and hydrogen stable isotope values suggest that the smectite was formed at 20–40°C in pore water of mixed meteoric and marine origin during argillization. These features, together with mass-balance calculations, indicate the enhanced MgO and Sr content of the smectite resulted from formation at shallow burial depths within a dominantly marine environment.


Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 335
Author(s):  
Iuliu Bobos ◽  
Celso Gomes

Acid-sulfate alteration is comprised by clays, sulfate, sinter and native sulphur minerals crystallized as neoformation products from dissolution of primary minerals during water-rock interaction. Smectite, kaolinite, halloysite-7 Å and opal-A occur in assemblages with alunite. Smectite represents a mechanical mixture between two (propylitic and acid-sulfate) alteration types. High amounts of high-field strength elements (HFSE) and rare earth elements (REE) were measured in acid-sulfate rocks. The Nb vs. Ta and Zr vs. Hf show a positive trend and a widely scattered relationships, suggesting a large fractionation during acid-sulfate alteration. Higher ∑REE amounts (up to 934.5 ppm) were found in clay-sulfate assemblages and lower ∑REE amounts in sinter (opal-A ± sulfate, 169.05 ppm) than to fresh rocks (up to 751.2 ppm). The acid-sulfate rocks reveal a distinctive gull-wing chondrite-normalized pattern with a negative Eu anomaly and light- and heavy-REE “wings” similar to the gull-wing pattern of fresh rocks. The Eu/Eu* shows a large fractionation of acid sulfate rocks from 0.16 to 0.78 with respect to fresh trachyte products (0.10 to 0.38). Variation of (La/Sm)N and (La/Yb)N ratio show a large fractionation of light-REE and heavy-REE. The Y vs. Dy and Y vs. Ho show a very good positive correlation coefficient and a large Y fractionation in acid-sulfate rocks with respect to fresh rocks.


1983 ◽  
Vol 112 ◽  
pp. 23-33
Author(s):  
J.L Boak ◽  
R.F Dymek ◽  
L.P Gromet

An investigation of the petrology and rare-earth element (REE) geochemistry of clastic metasedimentary rocks from the ~ 3800 Ma Isua Supracrustal Belt has been carried out to provide constraints on the nature of early Archaean metamorphie regimes and on the sources of their sedimentary protolith. The assemblages garnet + staurolite + biotite and biotite + kyanite (both with qtz + muse + plag + Hm) characterize the Isua metasediments and represent types common in younger metamorphic belts. Secondary chlorite and sericite occur in most samples. Garnet-biotite geothermometry indicates T = 541 ± 43°C for prograde metamorphism and T = 464 ± 39°C for retrograde metamorphism. Suggested metamorphic conditions of T - 550°C and P - 5 Kb imply burial to at least 15 Km with metamorphic thermal gradients < 40°C/Km. These data argue against excessively steep early Archaean crustal thermal gradients. REE patterns for three museovite-biotite gneisses are strongly fractionated (CeN = 40-100; YbN = 2-8) with variable Eu-anomalies (Eu/Eu* = 0.48-0.95), not unlike patterns for Arehaean felsic voicanic rocks in other areas. Garnet-biotite sehists have less-fractionated light REE, and exhibit a slope reversal for the heavy REE (i.e., GdN< YbN. These most plausibly represent a mixed felsic-mafic (- ultramafic?) protolith. Both sediment types could be the erosion produets of a rapidly emergent voicanic structure shedding debris into a shallow basin.


1988 ◽  
Vol 25 (4) ◽  
pp. 570-580 ◽  
Author(s):  
T. J. Barrett ◽  
P. W. Fralick ◽  
I. Jarvis

Rare-earth-element (REE) compositions of iron formation from two Archean terrains in western Ontario have been determined in order to assess the possible influence of hydrothermal activity on the REE patterns of chemical sediments. One terrain is characterized by sulfide-facies iron formation in association with volcanic flows and volcaniclastic sediments, whereas the other is dominated by oxide-facies iron formation intercalated within submarine-fan clastic sediments. Mineral separates of chert, magnetite, and pyrite from the iron formations have low ΣREE concentrations (< 20–30 ppm) and display moderate to strong positive Eu anomalies (relative to Archean shale). The positive anomalies (and lack of negative Ce anomalies) indicate that Archean sea water from which iron formation locally precipitated was reduced, although to varying degrees.The REE patterns of mineral separates from a given locality are almost identical, but the patterns for various localities differ in detail. A number of iron-formation samples interbedded within volcanics and at the volcanic–sediment interface show a distinct positive La anomaly and near-flat to slightly heavy-REE (HREE)-enriched patterns. The only modern environment where metalliferous sediments are accumulating with these combined characteristics is the Red Sea brine deeps. By contrast, limited data from iron formation interbedded within the clastic submarine fan suggest a fairly flat pattern with a moderate positive Eu anomaly and no La enrichment. We therefore suggest that the latter pattern typifies nonhydrothermal Archean seawater.Where seawater was influenced by a direct hydrothermal contribution, La enrichment and enhancement of the Eu anomaly could result. However, since periods of low-intensity discharge and (or) bottom-water mixing could eliminate the hydrothermal signal, not all samples from volcanic associations need show these features. By analogy with the Red Sea, preservation of a hydrothermal signal is most likely where circulation in the depositional basin is restricted and bottom waters are strongly reducing. Evidence for such conditions in the volcanic association is provided by the nature of the associated sediments (e.g., carbonaceous slates and unreworked distal turbidites).


2021 ◽  
pp. 1-20
Author(s):  
I.M. Bhat ◽  
T. Ahmad ◽  
D.V. Subba Rao ◽  
N.V. Chalapathi Rao

Abstract The Ladakh Himalayan ophiolites preserve remnants of the eastern part of the Neo-Tethyan Ocean, in the form of Dras, Suru Valley, Shergol, Spongtang and Nidar ophiolitic sequences. In Kohistan region of Pakistan, Muslim Bagh, Zhob and Bela ophiolites are considered to be equivalents of Ladakh ophiolites. In western Ladakh, the Suru–Thasgam ophiolitic slice is highly dismembered and consists of peridotites, pyroxenites and gabbros, emplaced as imbricate blocks thrust over the Mesozoic Dras arc complex along the Indus Suture Zone. The Thasgam peridotites are partially serpentinized with relict olivine, orthopyroxene and minor clinopyroxene, as well as serpentine and iron oxide as secondary mineral assemblage. The pyroxenites are dominated by clinopyroxene followed by orthopyroxene with subordinate olivine and spinel. Gabbros are composed of plagioclase and pyroxene (mostly replaced by amphiboles), describing an ophitic to sub-ophitic textural relationship. Geochemically, the studied rock types show sub-alkaline tholeiitic characteristics. The peridotites display nearly flat chondrite-normalized rare earth element (REE) patterns ((La/Yb)N = 0.6–1.5), while fractionated patterns were observed for pyroxenites and gabbros. Multi-element spidergrams for peridotites, pyroxenites and gabbros display subduction-related geochemical characteristics such as enriched large-ion lithophile element (LILE) and depleted high-field-strength element (HFSE) concentrations. In peridotites and pyroxenites, highly magnesian olivine (Fo88.5-89.3 and Fo87.8-89.9, respectively) and clinopyroxene (Mg no. of 93–98 and 90–97, respectively) indicate supra-subduction zone (SSZ) tectonic affinity. Our study suggests that the peridotites epitomize the refractory nature of their protoliths and were later evolved in a subduction environment. Pyroxenites and gabbros appear to be related to the base of the modern intra-oceanic island-arc tholeiitic sequence.


Geochemistry ◽  
2012 ◽  
Vol 72 (3) ◽  
pp. 245-252 ◽  
Author(s):  
Jian Cao ◽  
Ming Wu ◽  
Yan Chen ◽  
Kai Hu ◽  
Lizeng Bian ◽  
...  

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