Essential Oil Variability of Azorean Cryptomeriajaponica Leaves under Different Distillation Methods, Part 1: Color, Yield and Chemical Composition Analysis

This study mainly deals with the effect of hydrodistillation (HD) and water-steam distillation (WSD) methods on the color, yield, and chemical profile of the essential oil (EO) from Cryptomeria japonica fresh leaves from São Miguel Island (Azores Archipelago, Portugal). The yields of EO–HD (pale-yellowish) and EO–WSD (colorless) samples were 1.21% and 0.45% (v/w), respectively. The GC–FID, GC–MS, and 13C-NMR analyses of EO–HD vs. EO–WSD revealed (i) a high-content of monoterpenes (72.8% vs. 86.7%), mainly α-pinene (34.5% vs. 46.4%) and sabinene (20.2% vs. 11.6%), and oxygenated mono- and sesquiterpenes (20.2% vs. 9.6%); (ii) similar sesquiterpene (1.6% vs. 1.6%), β-myrcene (5.9% vs. 5.8%), and camphene (3.5% vs. 3.8%) contents; and (iii) significant differences in other classes/components: EO–HD is richer in oxygenated sesquiterpenes (17.1%, mainly elemol (10.4%) and α-eudesmol (3.4%)) and diterpenes (3%; mostly phyllocladene), while EO–WSD is richer in oxygenated monoterpenes (7.2%, mainly terpinen-4-ol (5.4%)), p-cymene (4.4%), and limonene (3.2%). Overall, the color, yield, and quantitative composition of the EO samples studied are strongly influenced by the distillation method. Nonetheless, this C. japonica leaf EO displayed a consistent α-pinene- and sabinene-rich composition. The same chemotype was found in a commercial Azorean C. japonica leaf EO sample, obtained by industrial steam distillation (SD), as well as in Corsica C. japonica leaf EO–HD. Furthermore, the bioactive composition of our EO samples revealed the potential to be used in green plant protection and in the medical, food, cosmetic, and household industries.

Inland and Island Tourism, Contrasting Geographies Touching Each Other

Despite being opposite geographic regions, inland territories and small islands have very much in common in terms of economic and social constraints. Based on the case study of the Azores archipelago, the limitations and opportunities for tourism development in the small oceanic islands are analysed. This study is supported by empirical research involving the application of questionnaires to the main tourism stakeholders in the archipelago. The results lead to the conclusion that in the case of the group of small temperate islands, tourism has progressively asserted itself as strategic for the local economy, but the application of a sustainable development model must be considered as these territories are generally highly vulnerable, both environmentally and socially.

The Digital Brand Marketing in the Azores Archipelago

The ultra-peripheral Portuguese region of Azores is considered one of the EU outermost regions. This insular region is widely recognized as a sustainable nature-based destination. Its remoteness and breathtaking landscape attributed the region a label of adventure tourism by global references as Bloomberg, Departures, BBC, Forbes, GeekyExplorer, Lonely Planet, among others. In this regard, this type of tourism incorporated with the digital marketing generated around it is seen as a vital channel for inspiring sustainable regional development. Consequently, it is possible to verify that the digital marketing created around this new typology of tourism along with the Azores' singularity as a destination could significantly influence the local socio-economy base to the sustained development growth of the region. Furthermore, it was identified that the most reasonable opportunities for slow and nature-based tourism were located in rural tourism.

Positive Interactions Drive Bat Distribution in a Remote Oceanic Archipelago (Azores, Portugal)

One of the fundamental interests in ecology is understanding which factors drive species’ distribution. We aimed to understand the drivers of bat distribution and co-occurrence patterns in a remote, insular system. The two bat species known to occur in the Azores archipelago were used as a model. Echolocation calls were recorded at 414 point-locations haphazardly distributed across the archipelago. Calls were analysed and assigned to each species. Binominal generalised linear models were adjusted using different descriptors at two scales: archipelago and island. The presence of the co-occurring species was included at both scales. The results show that island isolation, habitat and climate play an essential role on the archipelago and island scales, respectively. However, the positive interaction between bat species was the most critical driver of species’ distribution at the island scale. This high co-occurrence pattern at the island scale may result from both species’ maximising foraging profit in a region where prey abundance may be highly variable. However, further research is necessary to clarify the mechanisms behind this positive interaction. Both species are threatened and lack specific management and protection measures. Maintaining this positive interaction between the two species may prove to be fundamental for their conservation.

Arrival and proliferation of the invasive seaweed Rugulopteryx okamurae in NE Atlantic islands

The present study reports the recent occurrence and expansion of Rugulopteryx okamurae in the Azores archipelago (NE Atlantic). Morphological and molecular characters confirmed the species identification. Quick surveys around the island of São Miguel showed that it has successfully colonized the island and is quickly expanding. In some locations, R. okamurae is currently the dominant organism smothering all other benthic biota and posing a serious threat to the benthic ecosystems across the region. The species first record dates from 2019 near the main harbour of the island, suggesting that its introduction was driven by human-assisted transport, via boat ballast waters or adhered to ship hulls and likely originating from the Mediterranean populations that have been proliferating in recent years across the Strait of Gibraltar.

Cement-Treated Volcanic Scoria for Low-Traffic Road Pavements in the Azores Archipelago

The Azoreans rely on an extensive network of rural roads for the most of the rural population’s activities (primary sector) and accessibility. To rehabilitate and maintain this network, asphalt concrete and crushed rock aggregate are usually used. However, in the region, the application of such paving technology can be extremely costly. It requires specialized contractors, dedicated equipment and raw materials that must be imported to most of the islands. Therefore, the use of locally available materials would result in more flexibility and fewer costs for planned interventions. In the Azores, known as bagacina, the volcanic scoria is a pyroclastic material, generally highly abundant in volcanic islands. This natural aggregate is inexpensive, easy to extract, and presents good geotechnical characteristics. However, due to its porous nature, it generally does not comply with the current specifications for pavement materials. Therefore, this study aims to evaluate cement-treated volcanic scoria to be used as low-traffic road pavement layers. The geotechnical properties and mechanical performance of the two types of scoriae were analyzed. As a result, both types of scoriae presented good behavior, according to the expected for a cement-treated material, and proved to be a suitable alternative for road pavements in the Azores Archipelago.

Climate change facilitated the early colonization of the Azores Archipelago during medieval times

Humans have made such dramatic and permanent changes to Earth's landscapes that much of it is now substantially and irreversibly altered from its preanthropogenic state. Remote islands, until recently isolated from humans, offer insights into how these landscapes evolved in response to human-induced perturbations. However, little is known about when and how remote systems were colonized because archaeological data and historical records are scarce and incomplete. Here, we use a multiproxy approach to reconstruct the initial colonization and subsequent environmental impacts on the Azores Archipelago. Our reconstructions provide unambiguous evidence for widespread human disturbance of this archipelago starting between 700-60+50 and 850-60+60 Common Era (CE), ca. 700 y earlier than historical records suggest the onset of Portuguese settlement of the islands. Settlement proceeded in three phases, during which human pressure on the terrestrial and aquatic ecosystems grew steadily (i.e., through livestock introductions, logging, and fire), resulting in irreversible changes. Our climate models suggest that the initial colonization at the end of the early Middle Ages (500 to 900 CE) occurred in conjunction with anomalous northeasterly winds and warmer Northern Hemisphere temperatures. These climate conditions likely inhibited exploration from southern Europe and facilitated human settlers from the northeast Atlantic. These results are consistent with recent archaeological and genetic data suggesting that the Norse were most likely the earliest settlers on the islands.