Intercollisional Interference in the S Lines of H2–He Mixtures

1975 ◽  
Vol 53 (10) ◽  
pp. 954-961 ◽  
Author(s):  
J. D. Poll ◽  
J. L. Hunt ◽  
J. W. Mactaggart
Keyword(s):  
Dipole Moment ◽  
Line Shape ◽  
Short Range ◽  
Experimental Results ◽  
Strength Parameter ◽  
Free Molecule ◽  
Fundamental Band ◽  
A Value ◽  
Induced Dipole ◽  
Interference Minimum

Further experimental results on the pressure induced spectrum of normal H2–He in the region of the S(1) branch of the fundamental band are presented. These results show a well-defined minimum at the transition frequency of the free molecule. The S line is found to be the sum of two components. One of these is of essentially the same nature as the Q branch and should therefore show a pronounced intercollisional interference minimum. The second component shows the usual quadrupolar line shape without a minimum. Finally, a value for the strength parameter characterizing the short range component of the induced dipole moment is determined.

Intercollisional interference at low temperatures

1985 ◽  
Vol 63 (1) ◽  
pp. 99-103
Author(s):  
John Courtenay Lewis
Keyword(s):  
Dipole Moment ◽  
Impact Parameter ◽  
Low Temperatures ◽  
Quantum Effect ◽  
Intermolecular Force ◽  
Fundamental Band ◽  
Induced Dipole ◽  
Binary Collisions

The intercollisional interference dip in the Q-branch of the fundamental band of collision-induced spectra of H2–He mixtures partially fills in at low temperatures. In contradiction to claims that this ia a quantum effect, we show 1. that if the induced dipole moment is exactly proportional to the intermolecular force then the interference dip goes to zero at all temperatures; 2. that the filling-in of the dip is essentially a classical phenomenon and is due mainly to the discontinuity in the distance of closest approach during binary collisions as a function of impact parameter.

Theory of Intercollisional Interference Effects. IV. Does a Zero Minimum in Induced Absorption Imply the Proportionality of the Induced Dipole Moment to the Force?

1973 ◽  
Vol 51 (23) ◽  
pp. 2455-2458 ◽  
Author(s):  
J. Courtenay Lewis
Keyword(s):  
Dipole Moment ◽  
Lorentz Gas ◽  
Intermolecular Force ◽  
Interference Effects ◽  
Induced Absorption ◽  
Induced Dipole ◽  
Interference Minimum

We show that, within the limits of the theory of intercollisional interference effects developed for collision-induced absorption by a Lorentz gas in paper I of this series, an intercollisional interference minimum which goes precisely to zero implies that the induced dipole moment is exactly proportional to the intermolecular force.

Theory of collision-induced translational absorption

1968 ◽  
Vol 46 (10) ◽  
pp. 1163-1172 ◽  
Author(s):  
V. F. Sears
Keyword(s):  
Dipole Moment ◽  
Line Shape ◽  
Shape Function ◽  
Interatomic Potential ◽  
Exponential Model ◽  
Rare Gas ◽  
Repulsive Core ◽  
Frequency Range ◽  
Induced Dipole ◽  
Binary Collisions

A theory of the line shape for collision-induced translational absorption in rare-gas mixtures is developed. The reduced line-shape function is expanded in terms of the quantity ρ/σ, typically of the order of 0.1, where ρ is the range of the induced dipole moment and σ is the size of the repulsive core of the interatomic potential. The calculation is based on the special properties of the exponential model for the induced electric dipole moment. The temperature is assumed to be sufficiently high that the motion of the atoms can be treated classically, while the density is assumed to be sufficiently low that only binary collisions are important and intercollisional correlation effects are negligible over the frequency range of interest. A least-squares comparison of theory with experiment yields values for ρ and the magnitude of the induced moment for Ne–Ar and He–Ar pairs.

Interference effects in the spectrum of HD: III. The pure rotational band at 77 K for HD and HD–Ne mixtures

1984 ◽  
Vol 62 (12) ◽  
pp. 1673-1679 ◽  
Author(s):  
A. R. W. McKellar ◽  
J. W. C. Johns ◽  
W. Majewski ◽  
N. H. Rich
Keyword(s):  
Dipole Moment ◽  
Rotational Band ◽  
Reasonable Agreement ◽  
Permanent Dipole Moment ◽  
Destructive Interference ◽  
Interference Effects ◽  
Constructive Interference ◽  
Fundamental Band ◽  
A Value

The pure rotational R(0) transition of HD has been studied in pure HD and in HD–Ne mixtures at a temperature of 77 K and at densities between 3 and 123 amagat. Limited measurements of R(1) in pure HD were also made. A value of 8.18 ± 0.26 D was obtained for the R(0) permanent dipole moment of HD, in reasonable agreement with the theoretical value of 8.3 D. However, no evidence for destructive collisional interference effects at high densities was found, and in fact a slight constructive interference was noted. Thus, these results stand in contrast with those for the fundamental band, and with other recent experiments on the pure rotational band, in which destructive interference was invariably measured.

Intensity of the Pressure-Induced Fundamental Infrared Band of Gaseous Chlorine

1973 ◽  
Vol 51 (6) ◽  
pp. 696-697 ◽  
Author(s):  
P. T. T. Wong ◽  
E. Whalley
Keyword(s):  
Dipole Moments ◽  
Good Evidence ◽  
Transition Moment ◽  
Infrared Band ◽  
Fundamental Band ◽  
Induced Dipole ◽  
Integrated Intensity ◽  
Type Interaction

The integrated intensity of the pressure-induced fundamental band of gaseous chlorine measured by Winkel, Hunt, and Clouter is about 5 times that calculated assuming that the transition moment arises from the oscillation of quadrupole-induced dipole moments. This provides good evidence that valence-type interaction between gaseous chlorine molecules occurs.

An Analysis of Conventional and Self-Aligned four Terminal Resistor Structures for The Determination of The Contact Resistivity from End Resistance Measurements

1986 ◽  
Vol 71 ◽  
Author(s):  
I. Suni ◽  
M. Finetti ◽  
K. Grahn
Keyword(s):  
Finite Element Method ◽  
Finite Element ◽  
Computer Model ◽  
Contact Resistivity ◽  
Experimental Results ◽  
The Finite Element Method ◽  
Model Based ◽  
A Value ◽  
And Diffusion

AbstractA computer model based on the finite element method has been applied to evaluate the effect of the parasitic area between contact and diffusion edges on end resistance measurements in four terminal Kelvin resistor structures. The model is then applied to Al/Ti/n+ Si contacts and a value of contact resistivity of Qc = 1.8×10−7.Ωcm2 is derived. For comparison, the use of a self-aligned structure to avoid parasitic effects is presented and the first experimental results obtained on Al/Ti/n+Si and Al/CoSi2/n+Si contacts are shown and discussed.

DIRECTIONAL DIFFUSION OF K ATOMS ON A GaAs(110) SURFACE

2006 ◽  
Vol 05 (06) ◽  
pp. 895-900 ◽  
Author(s):  
NOBUYUKI ISHIDA ◽  
AGUS SUBAGYO ◽  
KAZUHISA SUEOKA
Keyword(s):  
Dipole Moment ◽  
Electric Field ◽  
Radial Direction ◽  
Negative Sample ◽  
Directional Diffusion ◽  
Sample Bias ◽  
Induced Dipole ◽  
High K ◽  
Scanning Area ◽  
The Relationship

We performed STM measurements on the K/GaAs (110) surface with high K coverage. The K atoms gradually disappeared while scanning the tip over the surface at negative sample bias voltage. The phenomenon strongly occurred over the scanning area and can be explained by the field-induced surface diffusion from the scanning area to radial direction. Considering the interaction between the dipole moment of the adsorbed K atoms and the electric field, we discuss the relationship between the static and induced dipole moment of K atoms on a GaAs (110) surface.

An anomaly in the specific heat below 3 °K of copper containing hydrogen

1969 ◽  
Vol 47 (14) ◽  
pp. 1485-1491 ◽  
Author(s):  
Neil Waterhouse
Keyword(s):  
Specific Heat ◽  
Molecular Hydrogen ◽  
Pure Copper ◽  
Solid Hydrogen ◽  
Rotational State ◽  
Experimental Results ◽  
Ortho Hydrogen ◽  
Temperature Range ◽  
A Value ◽  
Heat Curve

The specific heat of copper heated in hydrogen at 1040 °C has been measured over the temperature range 0.4 to 3.0 °K and found to be anomalous. The anomaly occurs in the same temperature range as the solid hydrogen λ anomaly which, in conjunction with evidence of ortho to para conversion of hydrogen in the sample, suggests the presence of molecular hydrogen in the copper. The anomaly reported by Martin for "as-received" American Smelting and Refining Company (ASARCO) 99.999+ % pure copper has been briefly compared with the present results. The form of the anomaly produced by the copper-hydrogen specimen has been compared with Schottky curves using the simplest possible model, that for two level splitting of the degenerate J = 1 rotational state of the ortho-hydrogen molecule.Maintenance of the copper-hydrogen sample at ~20 °K for approximately 1 week removed the "hump" in the specific heat curve. An equation of the form Cp = γT + (464.34/(θ0c)3)T3 was found to fit these experimental results and produced a value for γ which had increased over that for vacuumannealed pure copper by ~2%.

scholarly journals Finite Element Analysis of Artificially Frozen C-Phi soil

2019 ◽  
Vol 8 (4) ◽  
pp. 12722-12728
Keyword(s):  
Finite Element ◽  
Numerical Analysis ◽  
Frozen Soil ◽  
Experimental Results ◽  
Soil Freezing ◽  
Strength Parameter ◽  
Frozen Ground ◽  
Element Analysis ◽  
Test Setup ◽  
Geological Conditions

Artificial Ground Freezing techniques eliminate the need for structural supports during the course of an excavation, as frozen ground is solid and waterproof. At present, it is adopted as an effective way to deal with various construction ground control challenges such as the mitigation of seepage infiltration into tunnels and shaft excavations; or ground strengthening for excavation. In-depth knowledge of the frozen soil characteristics through experiments and the development of suitable constitutive models that suit the geological conditions of our country are necessary to predict the strength and behavior of the frozen soils. Numerical analysis of frozen soil can be used for mass works like tunneling which cannot be experimentally verified. This paper presents a validation of experimental results obtained from laboratory setup and soil freezing system for C-Phi soil. The main aim is to compare numerical and experimental results and hence obtaining the shear strength parameter of the soil, similar to the conventional triaxial test setup. To perform numerical analysis Finite element tool ANSYS 19 is used. Soil model is made in ANSYS 19 and required loads are inputted to performed the analysis similar to the experimental method. The result obtained from experimental test setup and numerical analysis was verified and compared and it was found that values of numerical results lies closer to experimental results

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