Disorientation of K(42P1/2) Atoms, Induced in Collisions with Noble Gases

1975 ◽  
Vol 53 (15) ◽  
pp. 1499-1503 ◽  
Author(s):  
B. Niewitecka ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Noble Gas ◽  
Zero Magnetic Field ◽  
Degree Of Polarization ◽  
Low Density ◽  
Resonance Fluorescence ◽  
Circularly Polarized ◽  
Potassium Vapor ◽  
The Cross ◽  
Gas Pressures

The cross sections for disorientation of 42P1/2 potassium atoms, induced in collisions with noble gas atoms, have been determined in zero magnetic field by studying the depolarization of K(7699 Å) resonance fluorescence in relation to noble gas pressures. Potassium vapor at low density, mixed with a noble gas in a fluorescence vessel, was irradiated with circularly polarized 7699 Å potassium resonance radiation and the resulting resonance fluorescence, observed in an approximately backward direction, was analyzed with respect to circular polarization. The variation of the degree of polarization with gas pressure was interpreted on the basis of a 'J randomization' model for the collisions and yielded the following disorientation cross sections which are appropriately corrected for the effect of nuclear spin: K–He, 24 ± 4 Å2; K–Ne, 21 ± 3 Å2; K–Ar, 37 ± 5 Å2; K–Kr, 51 ± 7 Å2; K–Xe, 69 ± 9 Å2. The cross sections are significantly smaller than values obtained previously in kilogauss fields.

Disorientation of Cs(62P1/2) atoms, induced in collisions with noble gases

1976 ◽  
Vol 54 (7) ◽  
pp. 748-752 ◽  
Author(s):  
B. Niewitecka ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Noble Gas ◽  
Zero Magnetic Field ◽  
Zero Field ◽  
Buffer Gas ◽  
Resonance Fluorescence ◽  
Circularly Polarized ◽  
Low Field ◽  
Good Agreement ◽  
Gas Pressures

The disorientation of 62P1/2 cesium atoms, induced in collisions with noble gas atoms in their ground states, was systematically investigated by monitoring the depolarization of cesium resonance fluorescence in relation to noble gas pressures. The Cs atoms, contained together with a buffer gas in a fluorescence cell and located in zero magnetic field, were excited and oriented by irradiation with circularly polarized 8943 Å resonance radiation, and the resonance fluorescence, emitted in an approximately backward direction, was analyzed with respect to circular polarization. The experiments yielded the following disorientation cross sections which have been corrected for the effects of nuclear spin: Cs–He: 4.9 ± 0.7 Å2; Cs–Ne: 2.1 ± 0.3 Å2; Cs–Ar: 5.6 ± 0.8 Å2; Cs–Kr: 5.8 ± 0.9 Å2; Cs–Xe: 6.3 ± 0.9 Å2. The results are in good agreement with most of the available zero-field and low-field data.

Disorientation of Na(32P1/2) Atoms, Induced in Collisions with Noble Gases

1974 ◽  
Vol 52 (20) ◽  
pp. 1956-1960 ◽  
Author(s):  
B. Niewitecka ◽  
T. Skaliński ◽  
L. Krause
Keyword(s):  
Circular Polarization ◽  
Cross Sections ◽  
Nuclear Spin ◽  
Noble Gas ◽  
Gas Pressure ◽  
Degree Of Polarization ◽  
Low Density ◽  
Resonance Fluorescence ◽  
Sodium Vapor ◽  
Circularly Polarized

The cross sections for disorientation of 32P1/2 sodium atoms, induced in collisions with noble gas atoms, have been determined by following the depolarization of Na–D1 resonance fluorescence in relation to noble gas pressure. Sodium vapor at low density, mixed with a noble gas in a fluorescence cell, was irradiated with circularly polarized D1 resonance radiation and the resulting D1 resonance fluorescence, observed in an approximately backward direction, was analyzed with respect to circular polarization. The variation of the degree of polarization with gas pressure was interpreted on the basis of a 'J randomization' model for the collisions, and yielded the following disorientation cross sections which are appropriately corrected for effects due to nuclear spin. Na–He: 28.1 ± 4.0 Å2; Na–Ne: 27.8 ± 4.0 Å2; Na–Ar: 57.0 ± 8.0 Å2; Na–Kr: 78.0 ± 10 Å2; Na–Xe: 87.0 ± 13 Å2.

Coherence Transfer between the 2P1/2 and 2P3/2 States in Potassium, Induced in Collisions with Noble Gas Atoms and with Molecules

1973 ◽  
Vol 51 (4) ◽  
pp. 425-430 ◽  
Author(s):  
B. Niewitecka ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Noble Gas ◽  
Coherence Transfer ◽  
Circularly Polarized ◽  
Sensitized Fluorescence ◽  
Potassium Vapor ◽  
Simple Molecules

The transfer of coherence accompanying 42P1/2 → 42P3/2 transfer of excitation induced in collisions between 42P1/2 potassium atoms and noble gas atoms as well as some simple molecules, was studied in a series of sensitized fluorescence experiments. Mixtures of potassium vapor at 6 × 10−7 Torr with the various buffer gases were irradiated with circularly polarized D1(σ+) light and the relative intensities of the σ+ and σ− fractions of both the D1 and D2 fluorescent components were determined in relation to the pressures of the buffer gases. The experiments yielded the following cross sections for coherence transfer: K–He:1.7 Å2; K–Ne :0.8 Å2; K–Ar < 0.5 Å2; K–H2 :3.5 Å2; K–CH4 :7.0 Å2; K–CD4:7.7 Å2.

Disorientation and disalignment of 42P3/2 potassium atoms, induced in resonant collisions

1980 ◽  
Vol 58 (10) ◽  
pp. 1500-1506 ◽  
Author(s):  
P. Skalinski ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Selective Excitation ◽  
Variable Magnetic Field ◽  
Constant Field ◽  
Resonance Fluorescence ◽  
Vapor Density ◽  
Scanning Method ◽  
Total Cross Sections ◽  
Circularly Polarized ◽  
Potassium Vapor

The total cross sections for disorientation (σ1) and disalignment (σ2) of 42P3/2 potassium atoms, induced in collisions with the ground-state atoms, have been determined using a modified Zeeman scanning method. Potassium vapor at densities of the order of 1011 cm−3, contained in a fluorescence cell located in a kilogauss variable magnetic field, was irradiated with circularly polarized 7665 Å resonance radiation emitted from a discharge lamp located in a constant field of 5.4 kG. Scans of the variable field permitted selective excitation of single Zeeman components in the absorbing vapor. The σ+ and σ− components of the resulting resonance fluorescence emitted parallel to the scanning field were monitored in relation to the vapor density, as were the π and σ components emitted in the perpendicular direction. As the vapor density increased so did the frequency of the collisions which caused transfers among the Zeeman states in the vapor and thus disorientation and disalignment. The observed dependence of circular and linear depolarization of the fluorescence on the potassium density yielded the cross sections σ1 = 17 × 10−12 cm2 and σ2 = 21 × 10−2 cm2, corrected for imprisonment of radiation.

SENSITIZED FLUORESCENCE IN VAPORS OF ALKALI METALS: VIII. ENERGY TRANSFER BETWEEN THE 4 2P LEVELS IN POTASSIUM INDUCED BY INELASTIC COLLISIONS

1966 ◽  
Vol 44 (4) ◽  
pp. 753-768 ◽  
Author(s):  
G. D. Chapman ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Alkali Metals ◽  
Inelastic Collisions ◽  
Inert Gases ◽  
Inert Gas ◽  
Vapor Pressures ◽  
Sensitized Fluorescence ◽  
Potassium Vapor ◽  
The Cross ◽  
Scattering Cross Sections

Sensitized fluorescence in potassium vapor and its mixtures with inert gases was investigated in order to determine cross sections for the inelastic collisions leading to excitation transfer between the 4 2P1/2 and 4 2P3/2 states in potassium. The study was carried out at potassium vapor pressures of about 10−6 mm Hg, which were not formerly accessible to such experiments, and in the absence of radiation trapping. The cross sections Q1(4 2P1/2 → 42P3/2) and Q2(4 2P1/2 → 4 2P3/2) are as follows: for K–K collisions: 370 and 250 Å2; for K–He: 60 and 41 Å2; for K–Ne: 14 and 9.5 Å2; for K–A: 37 and 22 Å2; for K–Kr: 61 and 41 Å2; for K–Xe: 104 and 72 Å2. These values supersede those published previously (Chapman, Krause, and Brockman 1964; Chapman and Krause 1965). The cross sections for collisions between potassium and inert gas atoms do not increase monotonically with the polarizabilities of the inert gases but behave similarly to the electron – inert gas elastic scattering cross sections. This behavior is interpreted on the basis of a semiclassical model for the interaction, which involves overlap forces.

scholarly journals Cross sections of electron collisions with noble gases atoms

2021 ◽  
pp. 11-16
Author(s):  
Rusudan Golyatina ◽  
Sergei Maiorov
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Noble Gas ◽  
Empirical Formulas ◽  
Electron Collisions ◽  
Wide Range ◽  
Analytical Formulas ◽  
The Cross ◽  
Approximation Coefficients ◽  
Ionization Cross Sections

Consideration is given to the analysis of data on the cross sections of elastic and inelastic col-lisions of electrons with noble gas atoms. The transport (diffusion) cross section, the excita-tion and ionization cross sections are studied. For the selected sets of experimental and theo-retical data, optimal analytical formulas are found and approximation coefficients are select-ed for them. The obtained semi-empirical formulas allow us to reproduce the cross section values in a wide range of collision energies from 0.001 to 10000 eV with an accuracy of sev-eral percent.

Radiative association for the formation of MgO

2020 ◽  
Vol 500 (2) ◽  
pp. 2496-2502
Author(s):  
Tianrui Bai ◽  
Zhi Qin ◽  
Linhua Liu
Keyword(s):  
Cross Sections ◽  
Rate Coefficients ◽  
Low Density ◽  
Mechanical Method ◽  
Hot Gas ◽  
Radiative Association ◽  
Quantum Mechanical Method ◽  
Formation And Evolution ◽  
The Cross ◽  
Increasing Temperature

ABSTRACT The radiative association process for the formation of magnesium oxide (MgO) may be of great importance due to its frequent occurrence in the low-density and dust-poor astrochemical environments. In this work, the cross-sections and rate coefficients for the A1Π → X1Σ+, ${\rm X}^1\Sigma ^+\, \rightarrow \, {\rm A}^1\Pi$, D1Δ → A1Π, a3Π → e3Σ−, ${\rm X}^1\Sigma ^+\, \rightarrow \, {\rm X}^1\Sigma ^+$, and A1Π → A1Π radiative association processes of forming MgO are theoretically estimated. The cross-sections for the transitions between the different states are obtained by using the semiclassical method for direct contributions and the Breit–Wigner theory as a complement for resonance contributions. For the transitions between the same states, the quantum mechanical method is used. The rate coefficients are then obtained from the cross-sections for the temperatures in the range of 10–10 000 K and the results are found to vary from 4.69 $\times \, 10^{-16}$ to 6.27 $\times \, 10^{-14}$ cm3 s−1. For temperatures lower than around 693 K, the rate coefficients for the A1Π → X1Σ+ process are dominant, which indicates this process is the most efficient way of producing MgO at low temperatures. However, the rate coefficients for the D1Δ → A1Π process go through a rapid increase with increasing temperature and become dominant at higher temperatures. For other processes, their rate coefficients are several orders of magnitude lower than those for the two processes mentioned above. The results can be used to further investigate the formation and evolution of MgO in low density and hot gas close to the photosphere of evolved oxygen-rich stars.

scholarly journals Mobility of thermal cations in low density alkane gases

1986 ◽  
Vol 64 (12) ◽  
pp. 2423-2426
Author(s):  
Norman Gee ◽  
M. Antonio Floriano ◽  
Gordon R. Freeman
Keyword(s):  
High Temperature ◽  
Momentum Transfer ◽  
Temperature Coefficient ◽  
Cross Sections ◽  
Hard Sphere ◽  
Low Density ◽  
Density Limit ◽  
Average Momentum ◽  
Low Density Limit ◽  
The Cross

Mobilities µ of thermal cations were measured in gases of six linear n-alkanes, ethane to n-decane, and in i-butane and neo-pentane, as functions of density n and temperature T. The low density limit was reached where nµ and the temperature coefficient at constant n, (dnµ,/dT)n, were constant. At all temperatures the average momentum transfer cross sections σave equalled (1.2 ± 0.4) times the cross sections expected from simple polarization. At high temperature σave might be approaching a hard sphere limit.

Disorientation of 42P1/2 potassium atoms, induced in resonant collisions

1979 ◽  
Vol 57 (12) ◽  
pp. 2222-2226 ◽  
Author(s):  
P. Skalinski ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Variable Magnetic Field ◽  
Fluorescent Light ◽  
Exciting Light ◽  
Constant Field ◽  
Resonance Fluorescence ◽  
Resonance Transition ◽  
Vapor Density ◽  
Scanning Method ◽  
Potassium Vapor

A (modified) Zeeman scanning method was used to determine the cross sections for disorientation of potassium atoms in the 42P1/2 resonance substate, induced in collisions with the ground-state atoms. Potassium vapor at densities of the order of 1011 cm−3 placed in a variable magnetic field was irradiated with σ+ polarized resonance radiation of wavelength 7699 Å emitted from a discharge lamp located in a constant field of 5.4 kG. The σ+ and σ− components of the resonance fluorescence emitted at right angles to the direction of excitation were monitored in relation to the vapor density as the variable field was scanned to make the σ+ resonance transition in the absorbing vapor coincide with the σ+ component present in the exciting light. As the vapor density increased, so did the admixture of the σ− component in the fluorescent light, which arises from collisional mixing between the mJ = 1/2 and mJ = −1/2 Zeeman substates. The resulting depolarization curve yielded the disorientation cross section σ1 = 4.0 × 10−11 cm2.

Sensitized Fluorescence in Vapors of Alkali Atoms XIV. Temperature Dependence of Cross Sections for 72P1/2–72P3/2 Mixing in Cesium, Induced in Collisions with Noble Gas Atoms

1974 ◽  
Vol 52 (11) ◽  
pp. 945-949 ◽  
Author(s):  
I. N. Siara ◽  
H. S. Kwong ◽  
L. Krause
Keyword(s):  
Temperature Dependence ◽  
Cross Sections ◽  
Noble Gas ◽  
Excitation Transfer ◽  
Sensitized Fluorescence ◽  
Alkali Atoms ◽  
Resonance Doublet ◽  
The Cross ◽  
Adiabatic Case

The cross sections for 72P1/2–72P3/2 excitation transfer in cesium, induced in collisions with noble gas atoms, have been determined in a series of sensitized fluorescence experiments at temperatures ranging from 405 to 630 K. The cross sections which lie in the range 0.06–20 Å2, exhibit a temperature dependence which, however, is less pronounced than in the more adiabatic case of the cesium resonance doublet.

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