THE CHEMILUMINESCENT REACTION OF ACTIVE NITROGEN WITH THALLOUS HALIDES

1963 ◽  
Vol 41 (3) ◽  
pp. 732-738 ◽  
Author(s):  
L. F. Phillips
Keyword(s):  
Energy Transfer ◽  
Light Emission ◽  
Bimolecular Reaction ◽  
Emission Lines ◽  
Kcal Mole ◽  
Third Order ◽  
Active Nitrogen ◽  
Simultaneous Production ◽  
Chemiluminescent Reaction ◽  
Overall Efficiency

Energy transfer from active nitrogen to gaseous thallous halides leads to dissociation of the halide molecules with simultaneous production of excited thallium atoms. Thallium emission lines have been observed to correspond to the transfer of up to 221 kcal/mole to the TlX molecule. The process is kinetically third order but the high overall efficiency of light emission and thallous halide destruction requires a mechanism which involves a bimolecular reaction of TlX with an excited N2 formed during N-atom recombination.

INTENSITIES OF EMISSION LINES IN FLAMES OF METAL HALIDES WITH ACTIVE NITROGEN

1963 ◽  
Vol 41 (8) ◽  
pp. 2060-2066 ◽  
Author(s):  
L. F. Phillips
Keyword(s):  
Energy Transfer ◽  
Energy Transfer Process ◽  
Nitrogen Molecule ◽  
Spectral Lines ◽  
Emission Lines ◽  
Metal Halides ◽  
Kcal Mole ◽  
Active Nitrogen ◽  
Atom Concentration ◽  
Excitation Mechanisms

The intensities of spectral lines emitted by flames of a number of metal halides with active nitrogen have been found to vary as the square of the nitrogen atom concentration. When the total energy required for simultaneous dissociation of the halide and excitation of the metal atom is less than about 200 kcal/mole the energy transfer process is too efficient to be attributed to the termolecular reaction of a halide molecule with a pair of nitrogen atoms. The observations are consistent with the hypothesis that in this case energy is transferred to the halide molecule during collision with a nitrogen molecule in the 5Σg+ state. Possible excitation mechanisms are discussed for less intense lines which would require up to 276 kcal/mole for simultaneous dissociation and excitation.

Spectroscopic study of the reaction of active nitrogen with some organometallic compounds

1967 ◽  
Vol 45 (16) ◽  
pp. 1891-1896 ◽  
Author(s):  
R. E. March ◽  
H. I. Schiff
Keyword(s):  
Energy Transfer ◽  
Spectroscopic Study ◽  
Organometallic Compounds ◽  
Initial Energy ◽  
Emission Lines ◽  
Kcal Mole ◽  
Vibrationally Excited ◽  
Active Nitrogen ◽  
Metal Atoms

Transfer of energy from constituents in active nitrogen to gaseous organometallic compounds leads to dissociation of the organometallic and excitation of CN and (or) metal atom. Organometallic compounds of aluminium, zinc, and boron were used in this investigation. The observed emission lines from metal atoms and highly vibrationally excited CN correspond to an initial energy transfer in excess of 200 kcal/mole. The possible role of N2(5Σg+) molecules as excitors is discussed in the light of the results obtained.

Vacuum ultraviolet chemiluminescence from the reactions of active nitrogen with I2, IBr, ICI, and ICN

1968 ◽  
Vol 46 (8) ◽  
pp. 1429-1434 ◽  
Author(s):  
L. F. Phillips
Keyword(s):  
Energy Transfer ◽  
Emission Intensity ◽  
Vacuum Ultraviolet ◽  
Nitrogen Molecule ◽  
Emission Lines ◽  
Kcal Mole ◽  
Active Nitrogen ◽  
Excitation Mechanisms ◽  
Excited Nitrogen ◽  
Cl Atoms

Numerous emission lines from excited I, Br, and Cl atoms have been observed between 1261 and 2062 Å. For the flames with I2, IBr, and ICl it is possible to assign excitation mechanisms on the basis of the dependence of emission intensity on either [N] or [N]2. In the case of dependence on [N] the emission is the result of energy transfer from an excited nitrogen molecule, which is produced by reaction of N with NI, has an energy of 185 ± 3.5 kcal/mole, and is identified with the predicted 3Δu species. The dissociation energy of NI is found to lie between 35.6 and 40 + 3.5 kcal/mole. It is proposed that excited nitrogen molecules can be produced as well as removed very rapidly by processes of the type[Formula: see text]

The afterglow and energy transfer mechanisms of active nitrogen

1970 ◽  
Vol 33 (1) ◽  
pp. 269-306 ◽  
Author(s):  
J Anketell ◽  
R W Nicholls
Keyword(s):  
Energy Transfer ◽  
Active Nitrogen ◽  
Transfer Mechanisms

Tunable White-Light Emission of Co2+ and Mn2+ Co-Doped ZnS Nanoparticles by Energy Transfer between Dopant Ions

2020 ◽  
Vol 124 (6) ◽  
pp. 3857-3866 ◽  
Author(s):  
G. Saavedra-Rodriguez ◽  
U. Pal ◽  
R. Sánchez-Zeferino ◽  
M. E. Álvarez-Ramos
Keyword(s):  
Energy Transfer ◽  
White Light ◽  
Light Emission ◽  
White Light Emission ◽  
Zns Nanoparticles ◽  
Co Doped

White light emission from a two-component hybrid gel via an energy transfer process

2015 ◽  
Vol 17 (48) ◽  
pp. 32297-32303 ◽  
Author(s):  
Xinhua Cao ◽  
Haichuang Lan ◽  
Zhenhua Li ◽  
Yueyuan Mao ◽  
Liming Chen ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Transfer Process ◽  
White Light ◽  
Light Emission ◽  
Light Harvesting ◽  
Energy Transfer Process ◽  
White Light Emission ◽  
Light Emitting ◽  
Hybrid Gel ◽  
Two Component

A two-component light-harvesting organogel containing a naphthalimide-based gelator as a donor and a phosphorescent Ir(iii) complex as an acceptor was used to produce white-light-emitting organogels.

Optical properties and energy transfer probing for white light emission in Ce3+/Tb3+/Sm3+ tri-doped barium gallium borosilicate glasses

2021 ◽  
Vol 120 ◽  
pp. 111412
Author(s):  
T. Sambasiva Rao ◽  
K.S. Rudramamba ◽  
T. Srikanth ◽  
D. Vijayasri ◽  
M. Rami Reddy
Keyword(s):  
Optical Properties ◽  
Energy Transfer ◽  
White Light ◽  
Light Emission ◽  
White Light Emission ◽  
Borosilicate Glasses

Third-order nonlinear optical response of energy transfer systems

1999 ◽  
Vol 111 (1) ◽  
pp. 27-39 ◽  
Author(s):  
Mino Yang ◽  
Graham R. Fleming
Keyword(s):  
Energy Transfer ◽  
Nonlinear Optical ◽  
Optical Response ◽  
Nonlinear Optical Response ◽  
Third Order

LIGHT EMISSION FROM ACTIVE NITROGEN SYSTEMS

1968 ◽  
pp. 13-64 ◽  
Author(s):  
A. Nelson Wright ◽  
Carl A. Winkler
Keyword(s):  
Light Emission ◽  
Active Nitrogen
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