Triplet Charge Transfer Complex between Excited Electron Acceptor and Ground State Electron Donor

1972 ◽  
Vol 50 (24) ◽  
pp. 4052-4056 ◽  
Author(s):  
Rafik O. Loutfy ◽  
Raouf O. Loutfy
Keyword(s):  
Free Energy ◽  
Charge Transfer ◽  
Linear Free Energy Relationship ◽  
Quenching Rate ◽  
Linear Free Energy ◽  
Oxidation Potentials ◽  
Half Wave ◽  
Ct Complex ◽  
Quenching Rate Constant ◽  
Ground State Electron

The half-wave reduction and oxidation potentials, E1/2's, of carbonyl compounds and amines, respectively, are used to estimate the location of triplet charge transfer states (CT). A linear free-energy relationship between the calculated CT triplet energies and the corresponding carbonyl molecules triplet energies was obtained. It has also been found that the free energy change (ΔF) for CT complex formation correlate with the triplet carbonyl quenching rate constant kq.

Half-wave potentials of quinone methides in dimethylformamide: Substituent effects

1981 ◽  
Vol 46 (4) ◽  
pp. 861-872 ◽  
Author(s):  
Josef Krupička ◽  
Bohumír Koutek ◽  
Lubomír Musil ◽  
Libuše Pavlíčková ◽  
Milan Souček
Keyword(s):  
Free Energy ◽  
Substituent Effects ◽  
Linear Free Energy Relationship ◽  
Quinone Methides ◽  
Linear Free Energy ◽  
Diffusion Controlled ◽  
Half Wave ◽  
Substituent Constants ◽  
Series Type ◽  
Spin Densities

Half-wave potentials of two series of quinone methides A have been determined in 0.1M tetrabutylammonium perchlorate in dimethylformamide. the first series (type I; 14 compounds) contained fuchsones substituted in positions 2 and 2,6 of the quinonoid ring, the second series (type II and III; 17 compounds) consisted of 2,6-ditert-butylquinone methides, with substituents at the exocyclic C(7) carbon atom. Properties of the first polarographic wave proved that in both series the reaction is one-electron, reversible, diffusion-controlled process. Linear free energy relationship was found between E1/2 and dual substituent constants σI and σR. Statistical analysis of linear free energy relationship for 2- and 2,6-substituted derivatives proved absence of steric factor in transmission of electronic substituent effect. The experimental results were interpreted on the basis of LUMO energies and spin densities, calculated by the HMO method.

Correlation of π,π* Triplet Energy of some Cyclic α,β-Unsaturated Ketones with Electroreduction Potentials

1972 ◽  
Vol 50 (24) ◽  
pp. 4050-4052 ◽  
Author(s):  
Rafik O. Loutfy ◽  
Raouf O. Loutfy
Keyword(s):  
Free Energy ◽  
Triplet State ◽  
Linear Free Energy Relationship ◽  
Triplet Energy ◽  
Unsaturated Ketones ◽  
Reduction Potentials ◽  
Linear Free Energy ◽  
Half Wave ◽  
Cyclic Enones ◽  
Wave Reduction

The half-wave reduction potentials, E1/2's, of some cyclic enones have been determined in acetonitrile. A linear free-energy relationship was obtained between E1/2 and the lowest π,π* triplet state of the enones studied. This correlation enabled an estimate to be made of the triplet energy of the cyclohexenone, which was found to be ~70 kcal/mol.

Synthesis and characterization of a series of 1-methyl-4-[2-aryl-1-diazenyl]piperazines and a series of ethyl 4-[2-aryl-1-diazenyl]-1-piperazinecarboxylates

2004 ◽  
Vol 82 (8) ◽  
pp. 1294-1303 ◽  
Author(s):  
Vanessa Renée Little ◽  
Keith Vaughan
Keyword(s):  
Free Energy ◽  
Chemical Shifts ◽  
Linear Free Energy Relationship ◽  
Piperazine Ring ◽  
Linear Free Energy ◽  
In Series ◽  
Methylene Groups ◽  
Diazonium Coupling ◽  
The Difference

1-Methylpiperazine was coupled with a series of diazonium salts to afford the 1-methyl-4-[2-aryl-1-diazenyl]piperazines (2), a new series of triazenes, which have been characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, and elemental analysis. Assignment of the chemical shifts to specific protons and carbons in the piperazine ring was facilitated by comparison with the chemical shifts in the model compounds piperazine and 1-methylpiperazine and by a HETCOR experiment with the p-tolyl derivative (2i). A DEPT experiment with 1-methylpiperazine (6) was necessary to distinguish the methyl and methylene groups in 6, and a HETCOR spectrum of 6 enabled the correlation of proton and carbon chemical shifts. Line broadening of the signals from the ring methylene protons is attributed to restricted rotation around the N2-N3 bond of the triazene moiety in 2. The second series of triazenes, the ethyl 4-[2-phenyl-1-diazenyl]-1-piperazinecarboxylates (3), have been prepared by similar diazonium coupling to ethyl 1-piperazinecarboxylate and were similarly characterized. The chemical shifts of the piperazine ring protons are much closer together in series 3 than in series 2, resulting in distortion of the multiplets for these methylenes. It was noticed that the difference between these chemical shifts in 3 exhibited a linear free energy relationship with the Hammett substituent constants for the substituents in the aryl ring. Key words: triazene, piperazine, diazonium coupling, NMR, HETCOR, linear free energy relationship.

Absorption Spectra of Substituted 2-Phenylindan-1,3-Dion-2-YL Radicals in Solution

1983 ◽  
Vol 38 (12) ◽  
pp. 1337-1341
Author(s):  
J. Zechner ◽  
N. Getoff ◽  
I. Timtcheva ◽  
F. Fratev ◽  
St. Minchef
Keyword(s):  
Free Energy ◽  
Absorption Spectra ◽  
Flash Photolysis ◽  
Bathochromic Shift ◽  
Substitution Effects ◽  
Linear Free Energy Relationship ◽  
Linear Free Energy

Abstract Flash photolysis of a series of 2-phenylindandione-1,3 derivatives substituted in the 4′ position results in both the formation of stable benzylidenephthalides and of phenylindan-1,3-dion-2-yl radicals. The u. v. absorption maxima of these radicals are dependent on the solvent and show a bathochromic shift upon substitution. These substitution effects were correlated by means of a linear free energy relationship. Attempts were made to draw conclusions concerning the changes in the gap of the states involved and their curvature due to substitution.

Correlation of Human and Animal Air-to-Blood Partition Coefficients With a Single Linear Free Energy Relationship Model

2008 ◽  
Vol 27 (9) ◽  
pp. 1130-1139 ◽  
Author(s):  
Laura M. Sprunger ◽  
Jennifer Gibbs ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Free Energy ◽  
Partition Coefficients ◽  
Linear Free Energy Relationship ◽  
Linear Free Energy ◽  
Relationship Model

Lifetime of Singlet Oxygen and Quenching by NaN3 in Mixed Solvents

1982 ◽  
Vol 37 (5) ◽  
pp. 649-652 ◽  
Author(s):  
N. Miyoshi ◽  
M. Ueda ◽  
K. Fuke ◽  
Y. Tanimoto ◽  
M. Itoh ◽  
...  
Keyword(s):  
Activation Energy ◽  
Charge Transfer ◽  
Singlet Oxygen ◽  
Mixed Solvents ◽  
Solvent Polarity ◽  
Thermal Lensing ◽  
Partial Charge ◽  
Partial Charge Transfer ◽  
Quenching Rate ◽  
Quenching Rate Constant

Singlet oxygen was generated by the photosensitization of erythrosine. The lifetime of singlet oxygen and the quenching rate constant for singlet oxygen by NaN3 were measured by a thermal lensing method in MeOH-H2O mixed solvents. The reciprocal of the lifetime increased linearly with the increase of the H2O mole fraction. Semi-log plot of the quenching constant against the reciprocal of the solvent polarity exhibited a linear relation. The quenching of the singlet oxygen by NaN3 may proceed through a partial charge-transfer intermediate. The activation energy for the quenching reaction of N3- + 1O2 →[N3·1O2-] increased with the increase of the solvent polarity. The lifetime was also measured in MeOH-ethyleneglycol mixed solvents, and its relation with viscosity was obtained

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