1,7-Dioxaspiro[5.5]undecanes. An excellent system for the study of stereoelectronic effects (anomeric and exo-anomeric effects) in acetals
1981 ◽
Vol 59
(7)
◽
pp. 1105-1121
◽
Keyword(s):
Several isomeric compounds derived from the spiro systems 5 to 9 (Scheme 4) were obtained from the acid cyclization of the appropriate dihydroxy ketone precursor.The configuration and the conformation of the products obtained was determined by 13C nmr analysis and equilibration studies. The experimental results can be rationalized by taking into account the anomeric and the exo-anomeric effects and the usual steric interactions.
Keyword(s):
Keyword(s):
1982 ◽
Vol 37
(5-6)
◽
pp. 363-368
◽
2009 ◽
Vol 21
(5)
◽
pp. 624-632
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Keyword(s):
Keyword(s):
1986 ◽
Vol 41
(1-2)
◽
pp. 215-221
◽
Keyword(s):