Total assignment of the 1H and 13C spectra of mikanokryptin and comparison of its solution and solid state conformations
Keyword(s):
The 1H and 13C spectra of mikanokryptin are unambiguously assigned using a variety of one-dimensional nmr experiments (selective homonuclear decoupling, use of inversion–recovery pulse sequences to reveal hidden peaks, and DEPT spectral editing) in conjunction with normal and "long range" two-dimensional heteronuclear correlated experiments. Detailed comparison of vicinal, allylic, and homoallylic 1H—1H coupling constants with dihedral angles determined from an earlier crystal structure determination indicates that solution and solid state configurations are similar.
2016 ◽
Vol 72
(7)
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pp. 972-975
2015 ◽
Vol 71
(7)
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pp. 852-856
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2015 ◽
Vol 71
(5)
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pp. 463-465
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2014 ◽
Vol 70
(7)
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pp. o806-o806
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2015 ◽
Vol 71
(2)
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pp. o108-o108
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2012 ◽
Vol 68
(6)
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pp. m826-m826
1996 ◽
Vol 278
(1)
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pp. 189-197
2006 ◽
Vol 62
(4)
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pp. o1529-o1531
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