MAGNETIC BEHAVIOUR OF A Cr+1.6 at.% Si SINGLE CRYSTAL

1993 ◽  
Vol 07 (01n03) ◽  
pp. 630-633 ◽  
Author(s):  
J.A.J. LOURENS ◽  
H.L. ALBERTS

Measurements of thermal expansion and velocity of sound around the Néel temperature (TN) of a Cr+1.6 at.% Si single crystal are presented. A weak continuous transition superimposed on a sharp first-order discontinuity was observed in the thermal expansion near TN. The continuous component is accurately described by a critical exponent power law. The sound velocity diverges sharply near TN in contrast with theoretical predictions for Cr-like itinerant electron antiferromagnets.

2002 ◽  
Vol 38 (5) ◽  
pp. 3252-3254 ◽  
Author(s):  
M. Han ◽  
J.A. Paulsen ◽  
J.E. Snyder ◽  
D.C. Jiles ◽  
T.A. Lograsso ◽  
...  

2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>


2015 ◽  
Vol 652 ◽  
pp. 287-291 ◽  
Author(s):  
Xiaojuan Li ◽  
Zengzhe Xi ◽  
Peng Liu ◽  
Wei Long ◽  
Pinyang Fang

1982 ◽  
Vol 53 (11) ◽  
pp. 7966-7968 ◽  
Author(s):  
F. J. Rachford ◽  
G. A. Prinz ◽  
J. J. Krebs ◽  
K. B. Hathaway

ChemInform ◽  
2015 ◽  
Vol 46 (10) ◽  
pp. no-no
Author(s):  
Hai-Feng Li ◽  
Andrew Wildes ◽  
Binyang Hou ◽  
Cong Zhang ◽  
Berthold Schmitz ◽  
...  

1975 ◽  
Vol 10 (8) ◽  
pp. 1462-1463 ◽  
Author(s):  
J. S. Abell ◽  
I. R. Harris ◽  
B. Cockayne

1987 ◽  
Vol 01 (05n06) ◽  
pp. 239-244
Author(s):  
SERGE GALAM

A new mechanism to explain the first order ferroelastic—ferroelectric transition in Terbium Molybdate (TMO) is presented. From group theory analysis it is shown that in the two-dimensional parameter space ordering along either an axis or a diagonal is forbidden. These symmetry-imposed singularities are found to make the unique stable fixed point not accessible for TMO. A continuous transition even if allowed within Landau theory is thus impossible once fluctuations are included. The TMO transition is therefore always first order. This explanation is supported by experimental results.


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