TERBIUM MOLYBDATE: GROUP THEORY AND FLUCTUATIONS
Keyword(s):
A new mechanism to explain the first order ferroelastic—ferroelectric transition in Terbium Molybdate (TMO) is presented. From group theory analysis it is shown that in the two-dimensional parameter space ordering along either an axis or a diagonal is forbidden. These symmetry-imposed singularities are found to make the unique stable fixed point not accessible for TMO. A continuous transition even if allowed within Landau theory is thus impossible once fluctuations are included. The TMO transition is therefore always first order. This explanation is supported by experimental results.
2016 ◽
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pp. 1650170
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2007 ◽
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pp. 3071-3083
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2018 ◽
Vol 28
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pp. 1830011
2014 ◽
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pp. 1450114
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pp. 1350195
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2021 ◽
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pp. 2150047
2012 ◽
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pp. 785-791
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2003 ◽
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pp. 3325-3340
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Vol 31
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pp. 1650154