Nonporous Nitrogen and Ruthenium Co-Doped Titania Films for Photocatalysis

2019 ◽  
Vol 18 (03n04) ◽  
pp. 1940043 ◽  
Author(s):  
O. Linnik ◽  
L. Khoroshko
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Structural Properties ◽  
Sol Gel ◽  
High Photocatalytic Activity ◽  
Gel Technique ◽  
Titania Films ◽  
Doped Titania ◽  
Co Doped

Nitrogen and ruthenium co-doped titania films synthesized by sol–gel technique exhibit high photocatalytic activity under both UV and visible light. Incorporation of nitrogen and ruthenium ions in titania lattice is proven by XPS. Both doping agents affected the structural properties of the films.

scholarly journals Synthesis of Fe- and Co-Doped TiO2 with Improved Photocatalytic Activity Under Visible Irradiation Toward Carbamazepine Degradation

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3874 ◽  
Author(s):  
Abderrahim El Mragui ◽  
Yuliya Logvina ◽  
Luís Pinto da Silva ◽  
Omar Zegaoui ◽  
Joaquim C.G. Esteves da Silva
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Diffuse Reflectance Spectroscopy ◽  
Anatase Phase ◽  
Aqueous Suspension ◽  
Sol Gel ◽  
Pure Tio2 ◽  
Doped Tio2 ◽  
Doped Titania ◽  
Co Doped

Pure TiO2 and Fe- and Co-doped TiO2 nanoparticles (NPs) as photocatalysts were synthesized using wet chemical methods (sol-gel + precipitation). Their crystalline structure and optical properties were analyzed using X-ray diffraction (XRD), Raman spectroscopy and Fourier-transform infrared (FTIR) spectroscopy, ultraviolet-visible light (UV-Vis) diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The photocatalytic activity of the synthesized nanoparticles was evaluated through degradation of carbamazepine (CBZ) under UV-A and visible-light irradiations. The XRD and Raman analyses revealed that all synthesized nanomaterials showed only the anatase phase. The DRS results showed that the absorption edge was blue-shifted for Fe-doped TiO2 NPs. The decrease in charge recombination was evidenced from the PL investigation for both Co-doped and Fe-doped TiO2 nanomaterials. An enhancement in photocatalytic degradation of carbamazepine in aqueous suspension under both UV-A light and visible-light irradiations was observed for Fe-doped Titania NPs by comparison with pure TiO2. These results suggest that the doping cations could suppress the electron/hole recombination. Therefore, the photocatalytic activity of TiO2-based nanomaterials was enhanced.

scholarly journals Modified Sol-Gel Synthesis of Carbon Nanotubes Supported Titania Composites with Enhanced Visible Light Induced Photocatalytic Activity

2016 ◽  
Vol 2016 ◽  
pp. 1-6
Author(s):  
Quanjie Wang ◽  
Yanqing Wang ◽  
Baorong Duan ◽  
Mengmeng Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Photocatalytic Activity ◽  
Carbon Nanotube ◽  
Visible Light ◽  
Sol Gel ◽  
High Photocatalytic Activity ◽  
Raw Material ◽  
Tetrabutyl Titanate ◽  
Multiwalled Carbon ◽  
Photodegradation Efficiency

Multiwalled carbon nanotube (MWCNT) enhanced MWCNT/TiO2nanocomposites were synthesized by surface coating of carbon nanotube with mixed phase of anatase and rutile TiO2through a modified sol-gel approach using tetrabutyl titanate as raw material. The morphological structures and physicochemical properties of the nanocomposites were characterized by FT-IR, XRD, DTA-TG, TEM, and UV-Vis spectra. The results show that TiO2nanoparticles with size of around 15 nm are closely attached on the sidewall of MWCNT. The nanocomposites possess good absorption properties not only in the ultraviolet but also in the visible light region. Under irradiation of ultraviolet lamp, the prepared composites have the highest photodegradation efficiency of 83% within 4 hours towards the degradation of Methyl Orange (MO) aqueous solution. The results indicate that the carbon nanotubes supported TiO2nanocomposites exhibit high photocatalytic activity and stability, showing great potentials in the treatment of wastewater.

scholarly journals Surface-Plasmon-Induced Visible Light Photocatalytic Activity of Fe3O4/TiO2 Nanocomposite

2020 ◽  
Author(s):  
Narjes Esmaeili ◽  
Azadeh Ebrahimian Pirbazari ◽  
Ziba Khodaee
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Surface Plasmon ◽  
Resonance Effect ◽  
Sol Gel ◽  
Analytical Techniques ◽  
Visible Light Photocatalytic Activity ◽  
Structure Morphology ◽  
Gel Technique ◽  
Visible Light Photocatalytic

In this research, first a binary nanocomposite of magnetic recyclable photocatalyst Fe3O4/TiO2, was synthesized by sol gel technique. Then, in order to enhance the photocatalytic activity of the synthesized nanocomposite, it was deposited by silver nanoparticles for using in degradation of organic pollutants 2, 4-dichlorophenol (2, 4-DCP) under visible light. A range of analytical techniques including XRD, FESEM/EDX, DRS, VSM and N2 physisorption were employed to reveal the crystal structure, morphology and property of the nanocomposites. We obtained 32% and 55% degradation of 2, 4-DCP under visible light after 180 min irradiation in the presence of Fe3O4/TiO2 and Fe3O4/TiO2/Ag respectively. Thus, the excellent visible light photocatalytic activity of Fe3O4/TiO2/Ag sample can be attributed to the surface plasmon resonance effect of Ag nanoparticles deposited on Fe3O4/TiO2 nanocomposite.

Visible-Light Driven LaNiO3 Nanosized Photocatalysts Prepared by a Sol-Gel Process

2011 ◽  
Vol 279 ◽  
pp. 83-87 ◽  
Author(s):  
Pei Song Tang ◽  
He Sun ◽  
Feng Cao ◽  
Jin Tian Yang ◽  
Sheng Liang Ni ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Visible Light ◽  
Light Absorption ◽  
Diffuse Reflectance Spectroscopy ◽  
Sol Gel ◽  
High Photocatalytic Activity ◽  
Visible Light Absorption ◽  
Average Grain Size ◽  
Sol Gel Process

The LaNiO3 nanoparticles were prepared by a sol-gel process. The LaNiO3 nanoparticles were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-Vis diffuse reflectance spectroscopy (DRS). XRD and SEM demonstrate the successful synthesis of single phase perovskite LaNiO3 and an average grain size of 80 nm in diameter. It was found that the as-prepared LaNiO3 shows strong visible-light absorption with absorption onset of 545 nm, indicating a narrow optical band gap of 2.28 eV. Consequently, LaNiO3 nanoparticles show high visible-light photocatalytic activity for decomposition of methyl orange in comparison with the commercial Degussa P25. The photocatalytic experiment shows the high photocatalytic activity for the decomposition of methyl orange under visible-light irradiation, which is attributed to the strong visible-light absorption.

Mesoporous template-free gyroid-like nanostructures based on La and Mn co-doped bismuth ferrites with improved photocatalytic activity

RSC Advances ◽  
2016 ◽  
Vol 6 (115) ◽  
pp. 114183-114189 ◽  
Author(s):  
Syed Irfan ◽  
Syed Rizwan ◽  
Yang Shen ◽  
Radmila Tomovska ◽  
Sonia Zulfiqar ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Low Cost ◽  
Sol Gel ◽  
Template Free ◽  
Gel Technique ◽  
Co Doped ◽  
Mesoporous Nanostructures

Template-free and gyroid-like mesoporous nanostructures of La and Mn co-doped bismuth ferrites were fabricated using a simple and low-cost double solvent sol–gel technique.

Structure of Nitrogen and Zirconium Co-Doped Titania with Enhanced Visible-Light Photocatalytic Activity

2014 ◽  
Vol 6 (7) ◽  
pp. 4622-4629 ◽  
Author(s):  
Peng Zhang ◽  
Yanlong Yu ◽  
Enjun Wang ◽  
Jingsheng Wang ◽  
Jianghong Yao ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Photocatalytic Activity ◽  
Doped Titania ◽  
Co Doped ◽  
Visible Light Photocatalytic
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