A novel high color purity yellow luminescent material NaBaBO3:Sm3+

2015 ◽  
Vol 08 (04) ◽  
pp. 1550042 ◽  
Author(s):  
Jianghui Zheng ◽  
Jia Feng ◽  
Qijin Cheng ◽  
Ziquan Guo ◽  
Lihan Cai ◽  
...  

Yellow emitting Sm 3+-doped NaBa 1-x BO 3(0.01 ≤ x ≤ 0.13) phosphors were synthesized by conventional solid state reaction method. The phase structure and luminescence properties of the as-prepared phosphors were investigated. These phosphors can be effectively excited by 403 nm near-ultraviolet light and feature a satisfactory yellow performance. The emission peaks are observed at 560 nm, 603 nm and 650 nm, originating from the transitions of 4G5∕2→6H5∕2, 4G5∕2→6H7∕2 and 4G5∕2→6H9∕2 respectively. Investigation of Sm 3+ concentration-dependent emission spectra indicates that the NaBa 0.95 BO 3:0.05 Sm 3+ phosphor shows the strongest yellow emission intensity and exhibits the CIE value of x = 0.4760 and y = 0.5090. Through the theoretical calculation, a high color purity of 96.0% was determined for the NaBaBO 3: Sm 3+ phosphor, and the color purity of NaBaBO 3: Sm 3+ is much higher than that of the commercial yellow phosphor YAG : Ce 3+. This work is highly relevant to the development of a new type of potential down-conversion (DC) yellow phosphor for near ultraviolet white or yellow light-emitting diodes (LEDs).

2017 ◽  
Vol 31 (16-19) ◽  
pp. 1744058
Author(s):  
Rong Yang ◽  
Huidong Tang

A novel phosphor, K2MgSiO4:Eu[Formula: see text], was synthesized by a solid-state reaction method. The phase formation was checked by X-ray powder diffraction. The photoluminescence excitation, emission spectra, decay curve and CIE coordinates of samples with different Eu[Formula: see text] ion concentrations were investigated in detail. The excitation spectra show a broad wavelength range of 225–470 nm. The K2MgSiO4:Eu[Formula: see text] phosphors exhibit highly red emission peaking at about 616 nm which is assigned to the 5D[Formula: see text]F2 transition of Eu[Formula: see text]ions under the excitation of near-ultraviolet (NUV) (394 nm) light. The critical quenching concentration of Eu[Formula: see text] doped in the K2MgSiO4: Eu[Formula: see text] phosphors was about 10 mol.% and the concentration quenching mechanism was dipole–dipole interactions between Eu[Formula: see text] ions. The results indicate that K2MgSiO4:Eu[Formula: see text] is a potential red phosphor candidate for NUV-pumped white light emitting diodes.


2011 ◽  
Vol 295-297 ◽  
pp. 547-550
Author(s):  
Jia Yue Sun ◽  
Jin Li Lai ◽  
Hai Yan Du

A series of new Na3CaB5O10:Eu3+ phosphor was synthesized by a solid-state reaction method, and its luminescent properties were investigated. The phase formation of phosphors was confirmed by X-ray powder diffraction (XRD). The excitation spectra exhibited that the phosphors could be effectively excited by near ultraviolet (392 nm) and blue (464 nm) light, which perfectly match the emission wavelength of near-UV light-emitting diodes (LEDs). The emission spectra showed that two characteristic red emission lines peaking at 592 and 613 nm can be obtained upon 394 and 463 excitation with the chromaticity coordinates of (0.6347, 0.3649), which are due to 5D0- 7F1 and 5D0-7F2transitions of Eu3+ ions. The effect of Eu3+ concentration on the emission spectrum of Na3CaB5O10:Eu3+ phosphor was studied. The results showed that the emission intensity increased with increasing Eu3+ concentration, and then decreased because of concentration quenching. The obtained results indicated that this phosphor could be a promising candidate for near-UV white LEDs.


2019 ◽  
Vol 3 (11) ◽  
pp. 2448-2454 ◽  
Author(s):  
Huili Ma ◽  
Kang Shen ◽  
Yipei Wu ◽  
Fang Xia ◽  
Feiling Yu ◽  
...  

A series of Pt(ii) complexes with narrow emission spectra were systematically investigated and Pt(ppzOczpy-4m), rationally designed with predominantly 3LC(3ππ*) character in T1, was fabricated into efficient blue OLEDs via a solution process.


2021 ◽  
Author(s):  
Yanyu Qi ◽  
Weimin Ning ◽  
Yang Zou ◽  
Xiaosong Cao ◽  
Shaolong Gong ◽  
...  

<p>High device efficiency and color-purity are the two essentials for high-quality organic light emitting diodes (OLEDs). Multi-resonance (MR) molecules show great potentials for high color-purity OLEDs due to their sharp emission bands. However, most MR molecules exhibit emission limited from deep-blue to green spectral region. Herein, through peripherally decorating MR emitter with electron donors, we demonstrated a new approach enabling the emission spectra of MR emitters red-shift while retaining narrowband emission. By manipulating the numbers and electron-donating abilities of the peripheries, the first narrowband yellow emitter with emission maxima of 562 nm and a full-width at half-maximum (FWHM) of 30 nm is realized. Highly efficient OLEDs with external quantum efficiency of over 24% and excellent color purity are fabricated by employing these newly developed MR molecules as emitters.</p>


2021 ◽  
Author(s):  
Yanyu Qi ◽  
Weimin Ning ◽  
Yang Zou ◽  
Xiaosong Cao ◽  
Shaolong Gong ◽  
...  

<p>High device efficiency and color-purity are the two essentials for high-quality organic light emitting diodes (OLEDs). Multi-resonance (MR) molecules show great potentials for high color-purity OLEDs due to their sharp emission bands. However, most MR molecules exhibit emission limited from deep-blue to green spectral region. Herein, through peripherally decorating MR emitter with electron donors, we demonstrated a new approach enabling the emission spectra of MR emitters red-shift while retaining narrowband emission. By manipulating the numbers and electron-donating abilities of the peripheries, the first narrowband yellow emitter with emission maxima of 562 nm and a full-width at half-maximum (FWHM) of 30 nm is realized. Highly efficient OLEDs with external quantum efficiency of over 24% and excellent color purity are fabricated by employing these newly developed MR molecules as emitters.</p>


2017 ◽  
Vol 5 (8) ◽  
pp. 2066-2073 ◽  
Author(s):  
Rongzhen Cui ◽  
Weiqiang Liu ◽  
Liang Zhou ◽  
Xuesen Zhao ◽  
Yunlong Jiang ◽  
...  

High performance sensitized organic light-emitting diodes with high color purity were obtained by utilizing terbium or gadolinium complexes as sensitizers.


2021 ◽  
Vol 52 (1) ◽  
pp. 953-956
Author(s):  
Tatsuya Ryowa ◽  
Yusuke Sakakibara ◽  
Tadashi Kobashi ◽  
Keisuke Kitano ◽  
Masaya Ueda ◽  
...  

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