Valence Electronic Structure of Aqueous Solutions: Insights from Photoelectron Spectroscopy

2016 ◽  
Vol 67 (1) ◽  
pp. 283-305 ◽  
Author(s):  
Robert Seidel ◽  
Bernd Winter ◽  
Stephen E. Bradforth
Keyword(s):  
Electronic Structure ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Structure Of Aqueous Solutions ◽  
Valence Electronic Structure

scholarly journals The Fermi Level as an Energy Reference in Liquid Jet X-ray Photoelectron Spectroscopy Studies of Aqueous Solutions  

2021 ◽  
Author(s):  
Lucia Pérez Ramírez ◽  
Anthony Boucly ◽  
Florent Saudrais ◽  
F. Bournel ◽  
Jean-Jacques Gallet ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Photoemission Spectroscopy ◽  
Liquid Jet ◽  
X Ray ◽  
Invaluable Tool ◽  
Structure Of Aqueous Solutions ◽  
Spectroscopy Studies ◽  
Photocatalytic Processes

To advance an understanding of key electrochemical and photocatalytic processes that depend on the electronic structure of aqueous solutions, X-ray photoemission spectroscopy has become an invaluable tool, especially when practiced...

scholarly journals UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes

2014 ◽  
Vol 87 (4) ◽  
pp. 495-499
Author(s):  
Igor Novak ◽  
Leo Klasinc ◽  
Boris Šket ◽  
Delano P. Chong ◽  
Sean P. McGlynn
Keyword(s):  
Electronic Structure ◽  
Photoelectron Spectroscopy ◽  
Uv Photoelectron Spectroscopy ◽  
Outer Valence ◽  
Valence Electronic Structure

scholarly journals Electronic Structure, Localization and 5f Occupancy in Pu Materials

2012 ◽  
Vol 1444 ◽  
Author(s):  
Miles F. Beaux ◽  
John J. Joyce ◽  
Tomasz Durakiewicz ◽  
Kevin S. Graham ◽  
Eric D. Bauer ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Fermi Energy ◽  
Photoelectron Spectroscopy ◽  
Electronic Configuration ◽  
Multiplet Structure ◽  
Temperature Dependent ◽  
Small Component ◽  
Narrow Peak ◽  
Valence Electronic Structure

ABSTRACTThe electronic structure of delta plutonium (δ-Pu) and plutonium compounds is investigated using photoelectron spectroscopy (PES). Results for δ-Pu show a small component of the valence electronic structure which might reasonably be associated with a 5f6 configuration. PES results for PuTe are used as an indication for the 5f6 configuration due to the presence of atomic multiplet structure. Temperature dependent PES data on δ-Pu indicate a narrow peak centered 20 meV below the Fermi energy and 100 meV wide. The first PES data for PuCoIn5 indicate a 5f electronic structure more localized than the 5fs in the closely related PuCoGa5. There is support from the PES data for a description of Pu materials with an electronic configuration of 5f5 with some admixture of 5f6 as well as a localized/delocalized 5f5 description.

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