scholarly journals Ni-Composite Microencapsulated Graphite as the Negative Electrode in Lithium-Ion Batteries II: Electrochemical Impedance and Self-Discharge Studies

2000 ◽  
Vol 147 (6) ◽  
pp. 2081 ◽  
Author(s):  
P. Yu ◽  
J. A. Ritter ◽  
R. E. White ◽  
B. N. Popov
Keyword(s):  
Lithium Ion Batteries ◽  
Electrochemical Impedance ◽  
Negative Electrode ◽  
Lithium Ion

Electrochemical Properties of Carbon-Coated NbO2 as a Negative Electrode for Lithium-Ion Batteries

2016 ◽  
Vol 724 ◽  
pp. 87-91 ◽  
Author(s):  
Chang Su Kim ◽  
Yong Hoon Cho ◽  
Kyoung Soo Park ◽  
Soon Ki Jeong ◽  
Yang Soo Kim
Keyword(s):  
Electrochemical Properties ◽  
Lithium Ion Batteries ◽  
Ball Milling ◽  
Carbon Coating ◽  
Electrochemical Impedance ◽  
Active Material ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Transfer Resistance ◽  
Carbon Coated

We investigated the electrochemical properties of carbon-coated niobium dioxide (NbO2) as a negative electrode material for lithium-ion batteries. Carbon-coated NbO2 powders were synthesized by ball-milling using carbon nanotubes as the carbon source. The carbon-coated NbO2 samples were of smaller particle size compared to the pristine NbO2 samples. The carbon layers were coated non-uniformly on the NbO2 surface. The X-ray diffraction patterns confirmed that the inter-layer distances increased after carbon coating by ball-milling. This lead to decreased charge-transfer resistance, confirmed by electrochemical impedance spectroscopy, allowing electrons and lithium-ions to quickly transfer between the active material and electrolyte. Electrochemical performance, including capacity and initial coulombic efficiency, was therefore improved by carbon coating by ball-milling.

Electrochemical Decomposition of Poly(Vinylidene Fluoride) Binder for a Graphite Negative Electrode in Lithium-Ion Batteries

2017 ◽  
Vol 893 ◽  
pp. 127-131 ◽  
Author(s):  
Min Ji Kim ◽  
Chang Hee Lee ◽  
Mun Hui Jo ◽  
Soon Ki Jeong
Keyword(s):  
Lithium Ion Batteries ◽  
Vinylidene Fluoride ◽  
Electrochemical Impedance ◽  
Negative Electrode ◽  
Reduction Process ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Electrode Resistance ◽  
Poly Vinylidene Fluoride

To clarify the electrochemical decomposition of poly (vinylidene fluoride) (PVdF) used as a binder for lithium-ion batteries while simultaneously verifying the correlation between electrode resistance and the PVdF content in graphite negative electrodes, in this study, we applied lithium bis (trifluoromethanesulfonyl) imide, which suppresses graphite exfoliation, as a salt. As a result, the electrochemical decomposition of PVdF was observed at a higher potential than that at which the electrolyte was decomposed during the reduction process. Additionally, this study demonstrated (through electrochemical impedance spectroscopy analysis) that electrode resistances such as solid electrolyte interface and charge transfer resistance proportionally increased with the PVdF content.

scholarly journals Electrochemical study on nickel aluminum layered double hydroxides as high-performance electrode material for lithium-ion batteries based on sodium alginate binder

2021 ◽  
Author(s):  
Xinyue Li ◽  
Marco Fortunato ◽  
Anna Maria Cardinale ◽  
Angelina Sarapulova ◽  
Christian Njel ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Material ◽  
Photoelectron Spectroscopy ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Electrochemical Study ◽  
Ex Situ ◽  
Potential Range ◽  
X Ray ◽  
Storage Mechanism

AbstractNickel aluminum layered double hydroxide (NiAl LDH) with nitrate in its interlayer is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the performance of the material is investigated in 1 M LiPF6 in EC/DMC vs. Li. The NiAl LDH electrode based on sodium alginate (SA) binder shows a high initial discharge specific capacity of 2586 mAh g−1 at 0.05 A g−1 and good stability in the potential range of 0.01–3.0 V vs. Li+/Li, which is better than what obtained with a polyvinylidene difluoride (PVDF)-based electrode. The NiAl LDH electrode with SA binder shows, after 400 cycles at 0.5 A g−1, a cycling retention of 42.2% with a capacity of 697 mAh g−1 and at a high current density of 1.0 A g−1 shows a retention of 27.6% with a capacity of 388 mAh g−1 over 1400 cycles. In the same conditions, the PVDF-based electrode retains only 15.6% with a capacity of 182 mAh g−1 and 8.5% with a capacity of 121 mAh g−1, respectively. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. Graphical abstract The as-prepared NiAl-NO3−-LDH with the rhombohedral R-3 m space group is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the material’s performance is investigated in 1 M LiPF6 in EC/DMC vs. Li. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. This work highlights the possibility of the direct application of NiAl LDH materials as negative electrodes for LIBs.

scholarly journals Characterization of the Compressive Load on a Lithium-Ion Battery for Electric Vehicle Application

Machines ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 71
Author(s):  
Seyed Saeed Madani ◽  
Erik Schaltz ◽  
Søren Knudsen Kær
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Electric Vehicles ◽  
Large Scale ◽  
Electrochemical Impedance ◽  
Applied Pressure ◽  
Lithium Ion ◽  
Battery Cells

Lithium-ion batteries are being implemented in different large-scale applications, including aerospace and electric vehicles. For these utilizations, it is essential to improve battery cells with a great life cycle because a battery substitute is costly. For their implementation in real applications, lithium-ion battery cells undergo extension during the course of discharging and charging. To avoid disconnection among battery pack ingredients and deformity during cycling, compacting force is exerted to battery packs in electric vehicles. This research used a mechanical design feature that can address these issues. This investigation exhibits a comprehensive description of the experimental setup that can be used for battery testing under pressure to consider lithium-ion batteries’ safety, which could be employed in electrified transportation. Besides, this investigation strives to demonstrate how exterior force affects a lithium-ion battery cell’s performance and behavior corresponding to static exterior force by monitoring the applied pressure at the dissimilar state of charge. Electrochemical impedance spectroscopy was used as the primary technique for this research. It was concluded that the profiles of the achieved spectrums from the experiments seem entirely dissimilar in comparison with the cases without external pressure. By employing electrochemical impedance spectroscopy, it was noticed that the pure ohmic resistance, which is related to ion transport resistance of the separator, could substantially result in the corresponding resistance increase.

scholarly journals Determination of the Distribution of Relaxation Times by Means of Pulse Evaluation for Offline and Online Diagnosis of Lithium-Ion Batteries

Batteries ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 36
Author(s):  
Erik Goldammer ◽  
Julia Kowal
Keyword(s):  
Lithium Ion Batteries ◽  
Electrochemical Impedance ◽  
Sampling Rate ◽  
Relaxation Times ◽  
Low Frequency ◽  
Lithium Ion ◽  
Battery Management ◽  
Time Constants ◽  
Time Domain Data ◽  
Aging Study

The distribution of relaxation times (DRT) analysis of impedance spectra is a proven method to determine the number of occurring polarization processes in lithium-ion batteries (LIBs), their polarization contributions and characteristic time constants. Direct measurement of a spectrum by means of electrochemical impedance spectroscopy (EIS), however, suffers from a high expenditure of time for low-frequency impedances and a lack of general availability in most online applications. In this study, a method is presented to derive the DRT by evaluating the relaxation voltage after a current pulse. The method was experimentally validated using both EIS and the proposed pulse evaluation to determine the DRT of automotive pouch-cells and an aging study was carried out. The DRT derived from time domain data provided improved resolution of processes with large time constants and therefore enabled changes in low-frequency impedance and the correlated degradation mechanisms to be identified. One of the polarization contributions identified could be determined as an indicator for the potential risk of plating. The novel, general approach for batteries was tested with a sampling rate of 10 Hz and only requires relaxation periods. Therefore, the method is applicable in battery management systems and contributes to improving the reliability and safety of LIBs.

Negative Electrode Comprised of Nanostructured CuO for Advanced Lithium Ion Batteries

2017 ◽  
Vol 28 (3) ◽  
pp. 1595-1604 ◽  
Author(s):  
Manab Kundu ◽  
Gopalu Karunakaran ◽  
Evgeny Kolesnikov ◽  
Mikhail V. Gorshenkov ◽  
Denis Kuznetsov
Keyword(s):  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion

Recent progress in rechargeable lithium batteries with organic materials as promising electrodes

2016 ◽  
Vol 4 (19) ◽  
pp. 7091-7106 ◽  
Author(s):  
Jian Xie ◽  
Qichun Zhang
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Recent Progress ◽  
Electrode Materials ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Positive Electrode ◽  
Rechargeable Lithium Batteries ◽  
Organic Electrode ◽  
Negative Electrode Materials

Different organic electrode materials in lithium-ion batteries are divided into three types: positive electrode materials, negative electrode materials, and bi-functional electrode materials, and are further discussed.

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