A High Energy Rechargeable Battery Based on a One-Step Successive Two-Electron Transfer Process

2005 ◽  
Vol 8 (8) ◽  
pp. A382 ◽  
Author(s):  
Kentarou Nishi ◽  
Toyohiko Nishiumi ◽  
Masayoshi Higuchi ◽  
Kimihisa Yamamoto
Keyword(s):  
Electron Transfer ◽  
Transfer Process ◽  
High Energy ◽  
Rechargeable Battery ◽  
Electron Transfer Process ◽  
One Step

scholarly journals Electrochemical reduction mechanism of several oxides of refractory metals in FClNaKmelts

2020 ◽  
Vol 39 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Hui Li ◽  
Lei Jia ◽  
Jing Wang ◽  
Jing-long Liang ◽  
Hong-yan Yan ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Chemical Reaction ◽  
Transfer Process ◽  
Reduction Process ◽  
Refractory Metals ◽  
Reduction Mechanism ◽  
Reversible Process ◽  
Electron Transfer Process ◽  
One Step

AbstractThe dissolution characteristics and electrochemical reduction mechanism of oxides of refractory metals ZrO2, HfO2 and MoO3 in NaCl-KCl-NaF melts are studied. The results shows that there are no chemical reaction of ZrO2 and HfO2 in NaCl-KCl-NaF melts, the dissolution of MoO3 is chemically dissolved, and MoO3 reactwith melts to form Na2Mo2O7. The reduction process of zirconium in the NaCl-KCl-NaF-ZrO2 melts is a reversible process of one-step electron transfer controlled by diffusion. The electrochemical reduction process of ruthenium is a one-step reversible process and the product is insoluble; Electrochemical reduction of metallic molybdenum in melts is controlled by the diffusion and electron transfer process of active ion Mo2O27− . The electrochemical reduction process of the metal molybdenum in the melts is carried out in two steps.

First Redox Polymer Bearing One-Step Successive Two-Electron-Transfer Process Based on Redox Potential Inversion

2004 ◽  
Vol 37 (7) ◽  
pp. 2661-2664 ◽  
Author(s):  
Toyohiko Nishiumi ◽  
Yuya Chimoto ◽  
Yuki Hagiwara ◽  
Masayoshi Higuchi ◽  
Kimihisa Yamamoto
Keyword(s):  
Electron Transfer ◽  
Redox Potential ◽  
Transfer Process ◽  
Redox Polymer ◽  
Electron Transfer Process ◽  
One Step ◽  
Polymer Bearing

Thionine–graphene oxide covalent hybrid and its interaction with light

2017 ◽  
Vol 19 (22) ◽  
pp. 14412-14423 ◽  
Author(s):  
Ewelina Krzyszkowska ◽  
Justyna Walkowiak-Kulikowska ◽  
Sven Stienen ◽  
Aleksandra Wojcik
Keyword(s):  
Electron Transfer ◽  
Graphene Oxide ◽  
Excited State ◽  
Transfer Process ◽  
Singlet Excited State ◽  
Functionalized Graphene ◽  
Electron Transfer Process ◽  
Functionalized Graphene Oxide ◽  
Back Electron Transfer

Quenching of the thionine singlet excited state in covalently functionalized graphene oxide with an efficient back electron transfer process.

scholarly journals Electrokinetic and Impedimetric Dynamics of FeCo-Nanoparticles on Glassy Carbon Electrode

Nano Hybrids ◽  
2013 ◽  
Vol 3 ◽  
pp. 1-23 ◽  
Author(s):  
Chinwe O. Ikpo ◽  
Njagi Njomo ◽  
Kenneth I. Ozoemena ◽  
Tesfaye Waryo ◽  
Rasaq A. Olowu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Transfer Process ◽  
Dimethyl Carbonate ◽  
Electrochemical Impedance ◽  
Ethylene Carbonate ◽  
Carbon Electrode ◽  
Electron Transfer Process ◽  
Feco Nanoparticles

The electrochemical dynamics of a film of FeCo nanoparticles were studied on a glassy carbon electrode (GCE). The film was found to be electroactive in 1 M LiClO4 containing 1:1 v/v ethylene carbonate dimethyl carbonate electrolyte system. Cyclic voltammetric experiments revealed a diffusion-controlled electron transfer process on the GCE/FeCo electrode surface. Further interrogation on the electrochemical properties of the FeCo nanoelectrode in an oxygen saturated 1 M LiClO4 containing 1:1 v/v ethylene-carbonate-dimethyl carbonate revealed that the nanoelectrode showed good response towards the electro-catalytic reduction of molecular oxygen with a Tafel slope of about 120 mV which is close to the theoretical 118 mV for a single electron transfer process in the rate limiting step; and a transfer coefficient (α) of 0.49. The heterogeneous rate constant of electron transfer (ket), exchange current density (io) and time constant (τ) were calculated from data obtained from electrochemical impedance spectroscopy and found to have values of 2.3 x 10-5 cm s-1, 1.6 x 10-4 A cm-2 and 2.4 x 10-4 s rad-1, respectively.

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