A Mixed Interface Reaction/Diffusion Control Model for Oxidation of Si3 N 4

1991 ◽  
Vol 138 (10) ◽  
pp. 3001-3007 ◽  
Author(s):  
Krishan L. Luthra
2018 ◽  
Vol 37 (7) ◽  
pp. 683-691
Author(s):  
Bartek Wierzba ◽  
Wojciech J. Nowak ◽  
Daria Serafin

AbstractThe reaction zones between pure titanium and iron-nickel and pure nickel at 1173 K have been characterized. Two alloys with different initial composition were analyzed. When Ni80Fe20 is used the layer sequence at the reaction interface is: Ni80Fe20 → Ni3Ti → NiTi → NiTi2 →Ti, while for Ni48Fe52 the sequence is: Ni48Fe52 → Ni3Ti → TiFe2 → TiFe → NiTi2 → Ti. The difference is in formation of NiTi, TiFe2 and TiFe phases. The reaction zone remains very thin independently of time due to the fast dissolution rate of Ti in the alloy. The two different elementary chemical interaction processes have been identified in this article, namely the growth of the reaction layers by solid state diffusion and chemical conversion of the compounds by reaction-diffusion in the solid state. The mathematical description combining these processes is presented for description of the diffusion path generated during diffusion process.


2001 ◽  
Vol 41 (supplement) ◽  
pp. S186
Author(s):  
J. Ozaki ◽  
M. Hirata ◽  
S. Kondo

2021 ◽  
Author(s):  
Karthik Pushpavanam ◽  
Brittney Hellner ◽  
François Baneyx

To emulate the control that biomineralizing organisms exert over reactant transport, we construct a countercurrent reaction-diffusion chamber in which an agarose hydrogel regulates the fluxes of inorganic precursor and precipitating...


Metals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 259
Author(s):  
Guopu Shi ◽  
Liu Zhang ◽  
Zhi Wang

Element reaction–diffusion of Ti/Al2O3 composite which was fabricated at various sintering temperatures, holding times, and a sintering pressure of 30 MPa has been discussed in the present research. Results show that the thickness of the reaction layer of the Ti-Al2O3 interface was increased in exponential form in correspondence with the increase of the sintering temperature. Furthermore, according to analysis, the relationship between the thickness of the interface reaction layer, sintering temperature, and heat preservation time acquiring the kinetic equation of interfacial reaction of Ti/Al2O3 composite was d = 182.5exp(−6.6 × 104/RT)t0.48 by linear fitting.


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