Thermal Analysis and Modeling of Thermal Batteries with Lithium-Boron Alloy Anode and Cobalt Disulfide Cathode

2021 ◽  
Author(s):  
Ling Ran ◽  
Jun Tang ◽  
Hongliang Zhang ◽  
Licai Fu
Keyword(s):  
Thermal Analysis ◽  
Alloy Anode ◽  
Thermal Batteries ◽  
Cobalt Disulfide

scholarly journals Monitoring of CoS2 reactions using high-temperature XRD coupled with gas chromatography (GC)

2016 ◽  
Vol 31 (2) ◽  
pp. 90-96 ◽  
Author(s):  
Mark A. Rodriguez ◽  
Eric N. Coker ◽  
James J. M. Griego ◽  
Curtis D. Mowry ◽  
Adam S. Pimentel ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
High Temperature ◽  
Gas Analysis ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Thermal Batteries ◽  
Cobalt Disulfide ◽  
High Temperature Xrd ◽  
Salt Phase

High-temperature X-ray diffraction with concurrent gas chromatography (GC) was used to study cobalt disulfide cathode pellets disassembled from thermal batteries. When CoS2 cathode materials were analyzed in an air environment, oxidation of the K(Br, Cl) salt phase in the cathode led to the formation of K2SO4 that subsequently reacted with the pyrite-type CoS2 phase leading to cathode decomposition between ~260 and 450 °C. Independent thermal analysis experiments, i.e. simultaneous thermogravimetric analysis/differential scanning calorimetry/mass spectrometry (MS), augmented the diffraction results and support the overall picture of CoS2 decomposition. Both gas analysis measurements (i.e. GC and MS) from the independent experiments confirmed the formation of SO2 off-gas species during breakdown of the CoS2. In contrast, characterization of the same cathode material under inert conditions showed the presence of CoS2 throughout the entire temperature range of analysis.

Historical Note on Thermal Batteries

1890 ◽  
Vol 29 (752supp) ◽  
pp. 12017-12017
Author(s):  
Henri Becquerel
Keyword(s):  
Historical Note ◽  
Thermal Batteries

Microstructural Analysis of Si-Ti-Fe Alloy Anode Materials for Li-ion Secondary Batteries

2013 ◽  
Vol 51 (6) ◽  
pp. 429-436 ◽  
Author(s):  
Jeong Eun Chae ◽  
Jun-Mo Yang ◽  
Kyung Jin Park ◽  
Jung Ho Yoo ◽  
Yun Chang Park ◽  
...  
Keyword(s):  
Anode Materials ◽  
Microstructural Analysis ◽  
Alloy Anode ◽  
Li Ion
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