scholarly journals Net Water Drag Coefficient during High Temperature Operation of Polymer Electrolyte Fuel Cells

Author(s):  
Hiroshi Ito ◽  
Taiki Mimoto ◽  
Satoshi Someya ◽  
Tetsuo Munakata

Abstract For polymer electrolyte fuel cell (PEFC) systems in vehicle applications, net water drag coefficient ( ) is an essential index and must be negative for system operation. The feasibility of PEFC operation at temperatures over 100C was examined here by measuring and comparing the current density (j) - characteristics using PEFCs with either an Aquivion or Nafion membrane. The effect of cell temperature ( ) on was evaluated at range from 80 to 120C. Results clearly demonstrated that, for both membrane types, significantly increased increasing . Results also confirmed that, at a constant flow rate of H2 at the anode, decreased with decreasing stoichiometric ratio of air ( ), although the effect of on was relatively small. Finally, the effect of relative humidity (RH) balance of supplied gases in both sides (anode/cathode) on water transport at temperature up to 120C was examined for the Aquivion cell. Results revealed that could be significantly decreased by decreasing the RH of hydrogen supplied to the anode (RHA) and that the control of RHA is an effective method for lowering at elevated temperature operation.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Shofu Matsuda ◽  
Yuuki Niitsuma ◽  
Yuta Yoshida ◽  
Minoru Umeda

AbstractGenerating electric power using CO2 as a reactant is challenging because the electroreduction of CO2 usually requires a large overpotential. Herein, we report the design and development of a polymer electrolyte fuel cell driven by feeding H2 and CO2 to the anode (Pt/C) and cathode (Pt0.8Ru0.2/C), respectively, based on their theoretical electrode potentials. Pt–Ru/C is a promising electrocatalysts for CO2 reduction at a low overpotential; consequently, CH4 is continuously produced through CO2 reduction with an enhanced faradaic efficiency (18.2%) and without an overpotential (at 0.20 V vs. RHE) was achieved when dilute CO2 is fed at a cell temperature of 40 °C. Significantly, the cell generated electric power (0.14 mW cm−2) while simultaneously yielding CH4 at 86.3 μmol g−1 h−1. These results show that a H2-CO2 fuel cell is a promising technology for promoting the carbon capture and utilization (CCU) strategy.


2019 ◽  
Vol 21 (24) ◽  
pp. 13126-13134 ◽  
Author(s):  
J. Halter ◽  
T. Gloor ◽  
B. Amoroso ◽  
T. J. Schmidt ◽  
F. N. Büchi

The influence of phosphoric acid temperature and concentration on the wetting behavior of porous high temperature polymer electrolyte fuel cell materials is investigated.


2019 ◽  
Vol 25 (1) ◽  
pp. 1999-2007 ◽  
Author(s):  
Antonino Salvatore Aricò ◽  
Alessandra Di Blasi ◽  
Giovanni Brunaccini ◽  
Francesco Sergi ◽  
Vincenzo Antonucci ◽  
...  

2013 ◽  
Vol 10 (6) ◽  
Author(s):  
Agus P. Sasmito ◽  
Tariq Shamim ◽  
Erik Birgersson ◽  
Arun S. Mujumdar

Portable and motive applications of open-cathode polymer electrolyte fuel cells (PEFCs) require not only good stack performance but also a light and compact design. In this context, we explore how edge cooling with three different fin designs—one standard rectangular fin and two triangular fins that essentially halve the size of the fins—can improve the thermal and water envelopes inside the stack as well as stack performance while reducing the overall volume. The results suggest that all three edge-cooling designs give rise to lower and more uniform local temperature distributions as well as higher and more uniform hydration levels at the membrane in the stack compared to the conventional open-cathode PEFC without fins and design with additional air coolant plates. In addition, edge cooling design with one of the triangular fins yields the best performance (around 5% higher in term of power per unit catalyst area and power per unit weight as well as ∼10% higher in term of power per unit volume as compared to other designs). Overall, the triangular fin design shows potential to be used in, for example, automotive applications due to its high performance as well as lightweight and compact design.


2020 ◽  
Author(s):  
Shofu Matsuda ◽  
Yuuki Niitsuma ◽  
Yuta Yoshida ◽  
Minoru Umeda

Abstract Generating electric power using CO2 as a reactant is challenging because the electroreduction of CO2 usually requires a large overpotential. Herein, we report the design and development of a polymer electrolyte fuel cell driven by feeding H2 and CO2 to the anode (Pt/C) and cathode (Pt0.8Ru0.2/C), respectively, based on their theoretical electrode potentials. Pt-Ru/C is a promising electrocatalysts for CO2 reduction at a low overpotential; consequently, CH4 is continuously produced through CO2 reduction with an enhanced faradaic efficiency (18.2%) and without an overpotential (at 0.20 V vs. RHE) was achieved when dilute CO2 is fed at a cell temperature of 40 °C. Significantly, the cell generated electric power (0.14 mW·cm− 2) while simultaneously yielding CH4 at 86.3 µmol·g− 1·min− 1. These results show that a H2-CO2 fuel cell is a promising technology for promoting the carbon capture and utilization (CCU) strategy.


2010 ◽  
Vol 22 (2) ◽  
pp. 150-157 ◽  
Author(s):  
Yogo Takada ◽  
◽  
Ryosuke Araki ◽  
Yukinobu Nakanishi ◽  
Motohiro Nonogaki ◽  
...  

Small fish robots, the size of a killifish – 5 cm long – are potentially in finding disaster victims in flooded areas, because of their ability to navigate narrow confines. Powering such robots, however, becomes a question, since the easiest answer – rechargeable batteries – has low energy density. The “Power Tube” we developed is a small and ultra-light passive-type polymer electrolyte fuel cell. Based on this fuel cell technology, we fabricated a 110 mm fish robot combining a drive, consisting of a DC motor and link, with a Power Tube having a hydrogen generator. We also fabricated an energy-efficient submersible fish robot with neodymium magnets and coil actuators, that methanol-fueled Power Tubes powered with a voltage booster.


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