The Effect of Additives on the Performance and Failure Mechanisms of the Rechargeable, Low-Cost, Alkaline Zinc Electrode

2020 ◽  
Vol MA2020-02 (6) ◽  
pp. 1042-1042
Author(s):  
Michael Joseph D'Ambrose ◽  
Damon Turney ◽  
Gautam Ganapati Yadav ◽  
Michael Nyce ◽  
Robert J. Messinger ◽  
...  
2018 ◽  
Vol 8 (12) ◽  
pp. 2622 ◽  
Author(s):  
Armin Buchroithner ◽  
Peter Haidl ◽  
Christof Birgel ◽  
Thomas Zarl ◽  
Hannes Wegleiter

Data related to the performance of burst containments for high-speed rotating machines, such as flywheel energy storage systems (FESS), turbines or electric motors is scarce. However, development of optimized burst containment structures requires statistically significant data, which calls out for low-cost test methods as a strategic development tool. Consequently, a low-cost test rig (so called spin pit) for the investigation of burst containments was designed, with the goal to systematically investigate the performance of different containment structures and materials, in conjunction with the failure mechanisms of different rotors. The gathered data (e.g., burst speed, acceleration, temperature, ambient pressure, etc.) in combination with a post-mortem analysis was used to draw an energy balance and enabled the assessment of the effectiveness of various burst containments.


2021 ◽  
Author(s):  
Debasish Sen ◽  
Hamood Alwashali ◽  
Md Shafiul Islam ◽  
Matsutaro Seki ◽  
Masaki Maeda

Abstract In developing countries, lateral strengthening of seismically vulnerable masonry infilled RC buildings is one of the major concern. In this context, ferrocement can be used as a low cost and less labor-intensive strengthening scheme for those buildings. This study aims to experimentally identify major failure mechanisms, and to develop a lateral strength evaluation procedure of ferrocement strengthened masonry infilled RC frame. Subsequently, ductility of all of the identified major failure mechanisms is compared. Mainly four major failure mechanisms (i.e. overall flexural, column punching-joint sliding, diagonal compression, and diagonal cracking-sliding) are identified from the current experimental work and past experimental studies. The strength evaluation procedure, based on the identified failure mechanisms, is proposed and verified with an average calculated to experimental lateral strength ratio of 0.8. Among the identified failure mechanisms, overall flexural, and diagonal cracking-sliding mechanisms showed relatively ductile behavior when compared to the ductility of column punching-joint sliding, and diagonal compression failure mechanism.


2012 ◽  
Vol 134 (1) ◽  
Author(s):  
Sushma Madduri ◽  
Bahgat G. Sammakia ◽  
William Infantolino ◽  
Satish C. Chaparala ◽  
Lawrence C. Hughes ◽  
...  

This paper presents a performance study done on a semiconductor laser diode in a moisture condensing environment. Devices with laser diodes are used in a wide variety of electronic applications and in the various climatic conditions. The motivation behind this study is a common environmental exposure, where a device using a laser diode is brought into a relatively humid building from a dry, cold, outside environments. Under such conditions, condensation occurs on various components of the device, including the diode, which could affect the laser output power. Device performance could be affected since the laser diode and the lens are susceptible to degradation due to such repetitive condensation conditions. The test vehicle chosen for this study was an optoelectronic package using a 980 nm laser diode. These are used in products for a broad range of markets, including data communications, aerospace, material processing, scientific, and defense industries [Pliska et al., "Wavelength Stabilized 980nm Uncooled Pump Laser Modules for Erbium-Doped Fiber Amplifiers," Opt. Lasers Eng., 43, pp. 271–289; Righetti, 1996, “Amplifiers Pumped at 980 nm in Submarine Applications,” European Conference on Optical Communication, Vol. 3, pp. 75–80; Pfeiffer et al., 2002, "Reliability of 980 nm Pump Lasers for Submarine, Long-haul Terrestrial, and Low Cost Metro Applications," Optical Fiber Communication Conference and Exhibit, pp. 483–484]. These products may be used in environmental conditions that could result in condensation within the product. A hermetic package could address this concern, but it is an expensive option. Nonhermetic packaging for the laser component could help to lower the cost of these devices; however, these packages have important failure mechanisms that are a potential concern. Prior research reported performance studies conducted on similar packages at elevated temperature, humidity, and power conditions using accelerated tests [Pfeiffer et al., 2002, "Reliability of 980 nm Pump Lasers for Submarine, Long-haul Terrestrial, and Low Cost Metro Applications," Optical Fiber Communication Conference and Exhibit, pp. 483–484; Park and Shin, 2004, “Package Induced Catastrophic Mirror Damage of 980nm GaAs High Power Laser,” Mater. Chem. Phys., 88(2-3), pp. 410–416; Fukuda et al., 1992, “Reliability and Degradation of 980nm InGaAs/GaAs Strained Quantum Well Lasers,” Qual. Reliab. Eng., 8, pp. 283–286]. However, studies conducted that specifically addressed condensation measurements have not been previously reported. Hence, an attempt was made to study package performance with condensation, to address the identified concern for the current package. A test method based on a military standard specification was used for this purpose. Elevated temperature and humidity (without condensation) were found to affect the laser power. These were characterized to isolate the effect of condensation alone. The package was subjected to repetitive condensing cycles and laser output power was recorded as a function of time, temperature and humidity. The variation in laser output power due to condensation was observed and quantified. Results showed a temporary power degradation of approximately 5% with condensation. This was a repeatable effect throughout the test time. Visible water droplets were found in various areas of the package after the test cycle. This could lead to potential failure mechanisms during the device life time.


Author(s):  
Junnan Hao ◽  
Libei Yuan ◽  
Chao Ye ◽  
Dongliang Chao ◽  
Kenneth Davey ◽  
...  

2021 ◽  
Author(s):  
Junnan Hao ◽  
Libei Yuan ◽  
Chao Ye ◽  
Dongliang Chao ◽  
Kenneth Davey ◽  
...  

2021 ◽  
Author(s):  
GEHAN JAYATILAKA, ◽  
MOHAMMAD MOEIN MOHAMMADI ◽  
MEHRAN TEHRANI

Graphene oxide (GO) films have great potential for aerospace, electronics, and renewable energy applications. GO sheets are low-cost and water-soluble and retain some of Graphene’s exceptional properties once reduced. GO or reduced GO (rGO) sheets within a film interact with each other via secondary bonds and cross-linkers. These interfacial interactions include non-covalent bonds such as hydrogen bonding, ionic bonding, and π-π stacking. Stress transfer and failure mechanisms in GO and rGO films, specifically how linkers affect them, are not well understood. The present study investigates the influence of inter-particle interactions and film structures, focusing on hydrogen bonds introduced via cellulose nanocrystals (CNC), on failure and stress-transfer of the GO and rGO films. To this end, GO films with CNC crosslinkers were made, followed by a chemical reduction. The few-micron thick films were characterized using tensile testing. All tested films exhibited a brittle failure and achieved tensile strengths and modulus in the ~40-85 MPa and ~3.5-9 GPa ranges, respectively. To reveal stress transfer mechanisms in each sample, tensile in-situ Raman spectroscopy testing was carried out. By monitoring the changes in bandwidth and position of Raman bands while stretching the film, useful information such as sheet slippage and cross-linker interactions were gathered. The addition of CNC enhanced modulus but degraded strength for both GO and rGO films. Interestingly, the Raman G-peak shift at failure, indicative of stress transfer to individual GO/rGO particles, is commensurate with the films’ strengths. Correlating these results with the structure and composition of different films reveals new understanding of stress transfer between GO/rGO particles, paving the way for the scalable manufacturing of strong and stiff GO-based films.


Author(s):  
Da-Ming Feng ◽  
Ying Sun ◽  
Zhong-Yong Yuan ◽  
Yang Fu ◽  
Baohua Jia ◽  
...  

AbstractThe electrochemical production of green and low-cost ammonia requests the development of high-performance electrocatalysts. In this work, the ampoule method was applied to modulate the surface of the zinc electrode by implanting defects and low-valent active sites. The N-doped ZnS electrocatalyst was thus generated by sulfurization with thiourea and applied for electrocatalytic nitrogen reduction reaction (ENRR). Given the rich sulfur vacancies and abundant Zn-N active sites on the surface, excellent catalytic activity and selectivity were obtained, with an NH3 yield rate of 2.42 × 10–10 mol s−1 cm−2 and a Faradaic efficiency of 7.92% at − 0.6 V vs. RHE in 0.1 M KOH solution. Moreover, the as-synthesized zinc electrode exhibits high stability after five recycling tests and a 24 h potentiostatic test. The comparison with Zn foil, non-doping ZnS/Zn and recent metal sulfide electrocatalysts further demonstrated advanced catalytic performance of N@ZnS/Zn for ENRR. By simple synthesis, S vacancies, and N-doping defects, this promising electrocatalyst would represent a good addition to the arena of transition-metal-based catalysts with superior performance in ENRR. Graphic abstract


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