scholarly journals Synthesis and Characterization of Metal Tribromoacetates and Their Alkali Metal Derivatives

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Jugal Kishore Puri ◽  
Rajni Chhoker
Keyword(s):  
Alkali Metal ◽  
Elemental Analysis ◽  
Molar Conductance ◽  
Synthesis And Characterization ◽  
Infrared Reflectance ◽  
Metal Derivatives ◽  
Thermogravimetric Studies

Complexes of composition Fe2Cl2(O2CCBr3)4, Fe2Cl(O2CCBr3)5, Fe (O2CCBr3)3, [(Me4N)2][Fe (O2CCBr3)4], K[Fe (O2CCBr3)4], Rb[Fe (O2CCBr3)4], Cs[Fe (O2CCBr3)4], [(Me4N)2][Co(O2CCBr3)4], [(Me4N)2][Mn(O2CCBr3)4], [(Me4N)2][Cu(O2CCBr3)4], and [(Me4N)2][Ni(O2CCBr3)4] have been prepared by metathetical reactions using nitromethane as solvent. All these compounds have been characterized by elemental analysis, molar conductance, infrared, reflectance and thermogravimetric studies.

SYNTHESIS AND CHARACTERIZATION OF TI (III), V (III),VO (IV), MOO (V),FE (II) AND FE (III) COMPLEXES OF BENZIL- 2,4-DINITROPHENYL HYDRAZONE P-BROMO ANILINE

2016 ◽  
Vol 2 (4) ◽  
pp. 177
Author(s):  
Raj Kamal Rastogi ◽  
Sonu Sharma ◽  
Gulshan Rastogi ◽  
Alok K. Singh
Keyword(s):  
Elemental Analysis ◽  
Magnetic Measurement ◽  
Measurement Data ◽  
Molar Conductance ◽  
Octahedral Geometry ◽  
Synthesis And Characterization ◽  
Distorted Octahedral Geometry ◽  
Distorted Octahedral ◽  
Uv Visible

The complexes of Benzil-2, 4-dinitrophenyl hydrazone-p- bromo aniline with Ti(III),V(III), VO(IV),MoO (V), Fe(II), Fe(III) have synthesized and characterized by elemental analysis, magnetic measurement data, molar conductance, TGA,UV-visible and IR spectra data. The complexes of Ti (III), V (III), Fe (II) and Fe (III) have octahedral geometry while VO (IV) and MoO(V) have distorted octahedral geometry due to the presence of M=O moiety.

scholarly journals The synthesis and characterization of some new diazoamino derivatives

2010 ◽  
Vol 16 (1) ◽  
pp. 89-95
Author(s):  
Mihaela Mocanu
Keyword(s):  
1H Nmr ◽  
Bioactive Compounds ◽  
Elemental Analysis ◽  
Analysis Data ◽  
Biological Properties ◽  
Synthesis And Characterization ◽  
Elemental Analysis Data ◽  
Spectral Measurements ◽  
Inflammatory Processes

The sulfonamidic moiety is much encountered in structures of bioactive compounds. In the present paper the studies on the sulfonamidated aryloxyalkylcarboxylic acids are extended by their attaching on certain substrata able to confer some special biological properties to the final products, such as anti-tumor and antioxidant actions useful in treating inflammatory processes, ulcer, convulsions and diabetes, as well as a herbicidal action. The stepwise syntheses of the sulfonamidated aryloxyalkylcarboxylic acid derivatives and their characterization by elemental analysis data and IR, 1H-NMR and UV-Vis spectral measurements are described. The newly obtained compounds could show potential pharmaceutical and herbicide properties.

scholarly journals Synthesis and characterization of new Oxazine , Thiazine and Pyrazol derived from chalcones

2014 ◽  
Vol 11 (2) ◽  
pp. 477-485 ◽  
Author(s):  
Baghdad Science Journal
Keyword(s):  
Nmr Spectroscopy ◽  
Hydrazine Hydrate ◽  
Elemental Analysis ◽  
Potassium Hydroxide ◽  
1H Nmr Spectroscopy ◽  
Room Temperature ◽  
Potassium Hydroxide Solution ◽  
Synthesis And Characterization ◽  
Heterocyclic Derivatives

In this study, chalcones were synthesis by condensing 2-acetylpyridine with aromatic aldehyde derivatives in dilute ethanolic potassium hydroxide solution at room temperature according to Claisen-Schmidt condensation. After that, new heterocyclic derivatives such as Oxazine, Thiazine and Pyrazol were synthesis by reaction between chalcones with urea, thiourea and hydrazine hydrate respectively scheme 1. All these compounds wrer characterization by FTIR, 1H-NMR spectroscopy and elemental analysis.

scholarly journals Synthesis and Characterization of Super Bulky β-Diketiminato Group 1 Metal Complexes

Inorganics ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 72
Author(s):  
Dafydd D. L. Jones ◽  
Samuel Watts ◽  
Cameron Jones
Keyword(s):  
Nmr Spectroscopy ◽  
Alkali Metal ◽  
Metal Complexes ◽  
Oxidation State ◽  
Synthesis And Characterization ◽  
X Ray Crystallography ◽  
Low Oxidation State ◽  
Bulky Ligand ◽  
Group 1

Sterically bulky β-diketiminate (or Nacnac) ligand systems have recently shown the ability to kinetically stabilize highly reactive low-oxidation state main group complexes. Metal halide precursors to such systems can be formed via salt metathesis reactions involving alkali metal complexes of these large ligand frameworks. Herein, we report the synthesis and characterization of lithium and potassium complexes of the super bulky anionic β-diketiminate ligands, known [TCHPNacnac]− and new [TCHP/DipNacnac]− (ArNacnac = [(ArNCMe)2CH]−) (Ar = 2,4,6-tricyclohexylphenyl (TCHP) or 2,6-diisopropylphenyl (Dip)). The reaction of the proteo-ligands, ArNacnacH, with nBuLi give the lithium etherate compounds, [(TCHPNacnac)Li(OEt2)] and [(TCHP/DipNacnac)Li(OEt2)], which were isolated and characterized by multinuclear NMR spectroscopy and X-ray crystallography. The unsolvated potassium salts, [{K(TCHPNacnac)}2] and [{K(TCHP/DipNacnac)}∞], were also synthesized and characterized in solution by NMR spectroscopy. In the solid state, these highly reactive potassium complexes exhibit differing alkali metal coordination modes, depending on the ligand involved. These group 1 complexes have potential as reagents for the transfer of the bulky ligand fragments to metal halides, and for the subsequent stabilization of low-oxidation state metal complexes.

Synthesis and Characterization of Alkali Metal and Thallium Polyfluoroantimonates, ASbnF5n+1 (n = 2, 3).

ChemInform ◽  
2006 ◽  
Vol 37 (21) ◽  
Author(s):  
Primoz Benkic ◽  
H. Donald Brooke Jenkins ◽  
Maja Ponikvar ◽  
Zoran Mazej
Keyword(s):  
Alkali Metal ◽  
Synthesis And Characterization

Synthesis and Characterization of Substituted μ-oxo-bis[tetra-phenylporphyrinatoiron] Compounds

2015 ◽  
Vol 748 ◽  
pp. 183-186
Author(s):  
Zhi Cheng Sun ◽  
Shu Ying Chen ◽  
Zhi Peng Guo ◽  
Mei Juan Cao ◽  
Lu Hai Li
Keyword(s):  
Infrared Spectra ◽  
Elemental Analysis ◽  
Aromatic Aldehydes ◽  
Synthesis And Characterization ◽  
Visible Spectroscopy ◽  
Reaction Conditions ◽  
One Pot ◽  
Optimum Reaction ◽  
Novel Method

A novel one-pot method for the synthesis of substituted μ-oxo-bis [tetraphenyl porphyrinatoiron] compounds ([TRPPFe]2O) from pyrrole and aromatic aldehydes was proposed and investigated in this paper. Four kinds of [TRPPFe]2O were designed and synthesized by one-pot reaction and characterized by elemental analysis, infrared spectra and ultraviolet-visible spectroscopy. Moreover, the [TRPPFe]2O yields of 18.7~22.4% could be obtained with this novel method under the optimum reaction conditions.

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