Recent progress in the computational study of transition metal doped Si clusters

2005 ◽  
Vol 1 (4) ◽  
pp. 230-239 ◽  
Author(s):  
Ju-Guang Han ◽  
Frank Hagelberg
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Computational Study ◽  
Magnetic Characteristic ◽  
Building Blocks ◽  
Atomic Transition ◽  
Equilibrium Geometry ◽  
Silicon Clusters ◽  
Computational Research ◽  
Metal Doped

Computational investigations on silicon clusters (Sin) in combination with atomic transition metal (TM) impurities are reviewed in this contribution. Emphasis is placed on studies that focus on the size exohedral to endohedral evolution features of TMSin, such as the critical ligand number for the transition from equilibrium geometry. Geometric, energetic, electronic and magnetic characteristic of TMSin are discussed in the size region n ≤ 20. It is pointed out that selected TMSin systems with n = 12 and n = 16 emerge from present computational research as the most promising candidates for building blocks of novel nanomaterials.

scholarly journals Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation

Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 391 ◽  
Author(s):  
Ke Cao ◽  
Cai-Yan Zhang ◽  
Tao-Tao Xu ◽  
Ji Wu ◽  
Xin-Yu Wen ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Building Blocks ◽  
Bioactive Natural Products ◽  
Fused Heterocycles ◽  
Selective Functionalization ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Photoluminescent Materials ◽  
Borane Cluster

Aromatic heterocycles are ubiquitous building blocks in bioactive natural products, pharmaceutical and agrochemical industries. Accordingly, the carborane-fused heterocycles would be potential candidates in drug discovery, nanomaterials, metallacarboranes, as well as photoluminescent materials. In recent years, the transition metal catalyzed B-H activation has been proved to be an effective protocol for selective functionalization of B-H bond of o-carboranes, which has been further extended for the synthesis of polyhedral borane cluster-fused heterocycles via cascade B-H functionalization/annulation process. This article summarizes the recent progress in construction of polyhedral borane cluster-fused heterocycles via B-H activation.

Recent progress in transition-metal-catalyzed hydrocyanation of nonpolar alkenes and alkynes

2020 ◽  
Vol 18 (3) ◽  
pp. 391-399 ◽  
Author(s):  
Hongru Zhang ◽  
Xin Su ◽  
Kaiwu Dong
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Building Blocks ◽  
Powerful Method ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Hydrocyanation is a powerful method for the preparation of nitriles which are versatile building blocks for the synthesis of amines, acids and amides.

scholarly journals The structures of neutral transition metal doped silicon clusters, SinX (n = 6−9; X = V, Mn)

2013 ◽  
Vol 138 (19) ◽  
pp. 194301 ◽  
Author(s):  
Pieterjan Claes ◽  
Vu Thi Ngan ◽  
Marko Haertelt ◽  
Jonathan T. Lyon ◽  
André Fielicke ◽  
...  
Keyword(s):  
Transition Metal ◽  
Silicon Clusters ◽  
Doped Silicon ◽  
Metal Doped

Recent Progress in Transition-Metal-Doped II–VI Mid-IR Lasers

2007 ◽  
Vol 13 (3) ◽  
pp. 810-822 ◽  
Author(s):  
Sergey B. Mirov ◽  
Vladimir V. Fedorov ◽  
Igor S. Moskalev ◽  
Dmitri V. Martyshkin
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Metal Doped

Recent progress in transition metal doped II-VI mid-IR lasers

2007 ◽  
Author(s):  
Sergey B. Mirov ◽  
Vladimir V. Fedorov ◽  
Igor S. Moskalev ◽  
Dmitri Martyshkin ◽  
Andrew Gallian ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Metal Doped

Recent progress in theoretical and experimental studies of metal-doped silicon clusters: Trend among elements of periodic table

2020 ◽  
Vol 403 ◽  
pp. 213095 ◽  
Author(s):  
Umar Farooq ◽  
Sadia Naz ◽  
Hong-Guang Xu ◽  
Bin Yang ◽  
Xi-Ling Xu ◽  
...  
Keyword(s):  
Periodic Table ◽  
Recent Progress ◽  
Experimental Studies ◽  
Silicon Clusters ◽  
Doped Silicon ◽  
Metal Doped

Recent Advances in Transition-Metal-Catalyzed C–H Addition to Nitriles

Synthesis ◽  
2021 ◽  
Author(s):  
Wei-Wei Liao ◽  
Shu-Qiang Cui
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Recent Progress ◽  
Building Blocks ◽  
Short Review ◽  
Synthetic Approach ◽  
Bond Forming ◽  
Palladium Catalyzed ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

AbstractTransition-metal-catalyzed C–H bond addition to nitriles has emerged as a powerful synthetic approach for the construction of C–C bonds in organic synthesis. Due to the merits of atom- and step-economy, as well the easy availability of the starting materials, these transformations not only deliver acyclic aryl ketone products with nitriles­ as C-building blocks, but can also be utilized for the highly efficient­ assembly of azaheterocyclic skeletons using nitriles as C–N building blocks. This short review summarizes recent progress on transition-metal-catalyzed C–C bond-forming reactions based on C(sp2)–H and C(sp3)–H additions to nitriles.1 Introduction2 Palladium-Catalyzed C–H Addition to Nitriles2.1 Palladium-Catalyzed C–H Addition to Nitriles for the Preparation of Ketone (Imine) Products2.2 Palladium-Catalyzed C–H Addition to Nitriles for the Preparation of Azaheterocycles2.3 Palladium-Catalyzed C–H Addition to Nitriles/1,2-Rearangement3 Other Transition-Metal-Catalyzed C–H Additions to Nitriles4 Summary and Outlook

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