Diameter-Selective Solubilization of Carbon Nanotubes by Lipid Micelles

2008 ◽  
Vol 8 (1) ◽  
pp. 420-423 ◽  
Author(s):  
Dimitrios Tasis ◽  
Konstantinos Papagelis ◽  
Dionysios Douroumis ◽  
James R. Smith ◽  
Nikolaos Bouropoulos ◽  
...  

The one-step dispersion of HiPco single-walled carbon nanotubes in aqueous media with the use of a synthetic lyso-phosphatidylcholine was studied. Solubilization occurs through wrapping of lipid molecules around the circumference of the tubes, yielding lipid monolayers on the graphitic sidewalls as evidenced by atomic force microscopy imaging and dynamic light scattering measurements. Raman spectroscopy showed that the dispersion and centrifugation process leads to an effective enrichment of the stable aqueous suspension in carbon nanostructures with smaller diameters.

Nano Research ◽  
2012 ◽  
Vol 5 (4) ◽  
pp. 235-247 ◽  
Author(s):  
Rouholla Alizadegan ◽  
Albert D. Liao ◽  
Feng Xiong ◽  
Eric Pop ◽  
K. Jimmy Hsia

Nano Letters ◽  
2008 ◽  
Vol 8 (11) ◽  
pp. 3568-3571 ◽  
Author(s):  
Tristan DeBorde ◽  
J. Caleb Joiner ◽  
Matthew R. Leyden ◽  
Ethan D. Minot

2012 ◽  
Vol 16 (07n08) ◽  
pp. 713-740 ◽  
Author(s):  
José H. Zagal ◽  
Sophie Griveau ◽  
Mireya Santander-Nelli ◽  
Silvia Gutierrez Granados ◽  
Fethi Bedioui

We discuss here the state of the art on hybrid materials made from single (SWCNT) or multi (MWCNT) walled carbon nanotubes and MN4complexes such as metalloporphyrins and metallophthalocyanines. The hybrid materials have been characterized by several methods such as cyclic voltammetry (CV), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and scanning electrochemical microscropy (SECM). The materials are employed for electrocatalysis of reactions such as oxygen and hydrogen peroxide reduction, nitric oxide oxidation, oxidation of thiols and other pollutants.


2019 ◽  
Vol 9 (4) ◽  
pp. 676 ◽  
Author(s):  
Lorena Cucci ◽  
Irina Naletova ◽  
Giuseppe Consiglio ◽  
Cristina Satriano

In this study, nanocomposites of spherical gold nanoparticles (AuNPs) and graphene oxide (GO) nanosheets were fabricated by a simple one-step reduction method. The characterisation by UV-visible spectroscopy of the plasmonic sensing properties pointed out to a strong interaction between graphene and metal nanoparticles in the hybrid GO-AuNP, as confirmed by nuclear magnetic resonance. Moreover, atomic force microscopy analyses demonstrated that the gold nanoparticles were mostly confined to the basal planes of the GO sheets. The response of the nanoassemblies at the biointerface with human neuroblastoma SH-SY5Y cell line was investigated in terms of nanotoxicity as well as of total and mitochondrial reactive oxygen species production. Confocal microscopy imaging of cellular internalization highlighted the promising potentialities of GO-AuNP nanoplatforms for theranostic (i.e., sensing/imaging + therapy) applications.


2010 ◽  
Vol 71 ◽  
pp. 34-39
Author(s):  
L. Minati ◽  
G. Speranza ◽  
I. Bernagozzi ◽  
S. Torrengo ◽  
L. Toniutti ◽  
...  

Multi-walled carbon nanotubes were chemically cut by acid treatments and then deposited on 2-aminoethanethiol-modified gold substrate by the application of an external electric field. 2-aminoethanethiol-capped gold nanoparticles were then covalently bonded to the nanotubes to exploit their plasmon resonances. Reaction intermediates as well as the final products were analyzed by X-Ray Photoelectron Spectroscopy, Atomic Force Microscopy and Scanning Electron Microscopy. The synergetic interaction between carbon nanotubes and gold nanoparticles leads to an efficient signal enhancement in Raman spectra. This is of particular interest for the detection of toxic molecules dangerous for the environment.


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