Preparation and Characterization of Ophthalmic Lens Materials Containing Titanium Silicon Oxide and Silver Nanoparticles

2015 ◽  
Vol 15 (10) ◽  
pp. 8016-8022 ◽  
Author(s):  
Jung-Won No ◽  
Dong-Hyun Kim ◽  
Min-Jae Lee ◽  
Duck-Hyun Kim ◽  
Tae-Hun Kim ◽  
...  

Hydrogel ophthalmic lenses containing fluorine-substituted aniline group, titanium silicon oxide nanoparticles, and silver nanoparticles were copolymerized, and the physical and optical properties of the hydrogel lenses were measured. To produce the hydrophilic ophthalmic lenses, the additives were added to the mixture containing HEMA, NVP, MA, EGDMA, and AIBN. The cast mold method was used for the manufacture of the hydrogel ophthalmic lenses, and the produced lenses were completely soaked in a 0.9% NaCl normal saline solution for 24 hours for hydration. The physical properties of the produced macromolecule showed that the water content was 32.5–37.6%, the refractive index was 1.450–1.464, the UV-B transmittance was 0.5–35.2%, and the contact angle was between 56 and 69°. Also, the addition of aniline, titanium silicon oxide, and silver nanoparticles allowed the ophthalmic lenses to block UV. These results show that the produced macromolecule can be used as hydrophilic lenses for ophthalmologic purposes that can block UV.

2008 ◽  
Vol 3 ◽  
pp. 103-114 ◽  
Author(s):  
Guadalupe Valverde-Aguilar ◽  
Jorge A. García-Macedo ◽  
Víctor Rentería-Tapia

Metallic silver particles in the nanometer size range were obtained in SiO2 matrix by the reduction of AgNO3 with the non-ionic diblock copolymer (Brij 58). Hexagonal mesostructured sol-gel films were synthesized by dip-coating method using the surfactant Brij58 to produce channels into the film, which house the silver nanoparticles. Optical properties of the metallic nanoparticles were studied by UV-Vis spectroscopy, TEM and HRTEM images. The experimental absorption spectrum of the metallic silver nanoparticles exhibits an absorption band located at 438 nm and a shoulder at longer wavelength. The TEM images show randomly distributed silver nanoparticles (Type I) along with some oriented as long line (Type II). Both distributions exhibit a silver oxide shell around of them. The second shell covering the silver core - silver oxide shell system is related to the surfactant. The optical absorption spectrum was modelled using the Gans theory. The fit shows two main contributions related to metallic silver nanoparticles with different axial ratios, and surrounding of a dielectric medium with high refractive index. Presence of the high refractive index silver oxide shell was confirmed by X-ray diffraction technique. The contributions of silver core and silver oxide shell play important roles in the optical properties of the films.


Author(s):  
Е.И. Михиенкова ◽  
А.В. Минаков ◽  
С.В. Лысаков ◽  
А.Л. Неверов ◽  
М.И. Пряжников

The results of experimental studies of the effect of the addition of silicon oxide nanoparticles on the stability of inverse emulsions based on mineral oils are presented. The concentration of nanoparticles in the emulsion was varied from 0.25 to 2 wt%. The following ratios of the volume fractions of the hydrocarbon phase and water were investigated: 70/30, 80/20, 90/10. Several types of emulsifiers have been considered. It has been shown that, even at low concentrations, hydrophobic SiO2 nanoparticles significantly improve the stability of inverse emulsions. Destabilization rate of the emulsion upon addition of 2 wt%. of nanoparticles decreases 1.7 times.


2019 ◽  
Vol 60 (5) ◽  
pp. 688-692 ◽  
Author(s):  
Hitoshi Sasaki ◽  
Genki Saito ◽  
Norihito Sakaguchi ◽  
Ryo Ota ◽  
Heishichiro Takahashi

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