Simultaneous Determination of Adenine and Guanine Using Cadmium Selenide Quantum Dots-Graphene Oxide Nanocomposite Modified Electrode

2015 ◽  
Vol 15 (6) ◽  
pp. 4697-4705 ◽  
Author(s):  
Arumugam Kalaivani ◽  
Sangilimuthu Sriman Narayanan
2014 ◽  
Vol 938 ◽  
pp. 176-181 ◽  
Author(s):  
Arumugam Kalaivani ◽  
Sangilimuthu Sriman Narayanan

A novel Cadmium selenide Quantum dots MWCNTs nanocomposite modified electrode was achieved by simple drop casting method and its application towards the quantitative determination of epinephrine. The Cadmium selenide Quantum Dots was characterized by transmission electron microscopy and MWCNT was characterized by scanning electron microscopy. The electrochemical characteristics of the modified electrode were studied using cyclic voltammetry. The voltammetric response of the modified electrode was higher than that of the MWCNT and bare electrodes. The modified electrode exhibits excellent electrocatalytic activity towards the oxidation of epinephrine by enhancing its oxidation current in 0.1M phosphate buffer solution. The determination range of epinephrine is from 0.16 μM to 14 μM and the detection limit was 0.05 μM (S/N = 3). The proposed modified electrode exhibited good stability and reproducibility.


2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Gen Liu ◽  
Wei Ma ◽  
Yan Luo ◽  
Deng-ming Sun ◽  
Shuang Shao

Poly(methylene blue) and electrochemically reduced graphene oxide composite film modified electrode (PMB-ERGO/GCE) was successfully fabricated by electropolymerization and was used for simultaneous determination of uric acid (UA) and xanthine (Xa). Based on the excellent electrocatalytic activity of PMB-ERGO/GCE, the electrochemical behaviors of UA and Xa were studied by cyclic voltammetry (CV) and square wave voltammetry (SWV). Two anodic sensitive peaks at 0.630 V (versus Ag/AgCl) for UA and 1.006 V (versus Ag/AgCl) for Xa were given by CV in pH 3.0 phosphate buffer. The calibration curves for UA and Xa were obtained in the range of 8.00 × 10−8~4.00 × 10−4 M and 1.00 × 10−7~4.00 × 10−4 M, respectively, by SWV. The detection limits for UA and Xa were3.00×10-8 M and5.00×10-8 M, respectively. Finally, the proposed method was applied to simultaneously determine UA and Xa in human urine with good selectivity and high sensitivity.


2018 ◽  
Vol 30 (11) ◽  
pp. 2620-2627 ◽  
Author(s):  
Miloš Ognjanović ◽  
Dalibor M. Stanković ◽  
Martin Fabián ◽  
Aleksandar Vukadinović ◽  
Željko Prijović ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (89) ◽  
pp. 48522-48534 ◽  
Author(s):  
A. T. Ezhil Vilian ◽  
Muniyandi Rajkumar ◽  
Shen-Ming Chen ◽  
Chi-Chang Hu ◽  
Shakkthivel Piraman

This paper describes the two-step synthesis of a nitrogen-doped reduced graphene oxide–ZnO (N-doped RGO–ZnO) nanocomposite and its photo electrochemical application.


2020 ◽  
Vol 44 (12) ◽  
pp. 4916-4926 ◽  
Author(s):  
Chaoli Tan ◽  
Jie Zhao ◽  
Peng Sun ◽  
Wei Zheng ◽  
Guofeng Cui

AuNPs, GO and PPy are combined effectively to form a novel composite showing a huge enhancement in electrochemical performance compared to the single materials.


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