Size Dependence of the Integral Melting Enthalpy and Entropy of Nanoparticles

2020 ◽  
Vol 20 (2) ◽  
pp. 934-940 ◽  
Author(s):  
Yan Wang ◽  
Yong-Qiang Xue ◽  
Qing-Shan Fu
2020 ◽  
Vol 138 ◽  
pp. 109269 ◽  
Author(s):  
Qingshan Fu ◽  
Hongxu Gao ◽  
Wengang Qu ◽  
Fengqi Zhao ◽  
Yongqiang Xue ◽  
...  

2017 ◽  
Vol 121 (44) ◽  
pp. 24831-24836 ◽  
Author(s):  
Zixiang Cui ◽  
Huijuan Duan ◽  
Qingshan Fu ◽  
Yongqiang Xue ◽  
Shuting Wang

2016 ◽  
Vol 52 (4) ◽  
pp. 1911-1918 ◽  
Author(s):  
Qingshan Fu ◽  
Jinhua Zhu ◽  
Yongqiang Xue ◽  
Zixiang Cui

2000 ◽  
Vol 634 ◽  
Author(s):  
H. Ehrhardt ◽  
J. Weissmüller ◽  
G. Wilde

ABSTRACTWe report calorimetric data for the size-dependence of the melting temperature as well as the enthalpy and entropy of melting for nanoscale Pb particles in an Al matrix, prepared by high energy ball-milling. The results are discussed with respect to various models for the melting of small confined systems. We can rule out models based on a temperature-independent Gibbs excess free energy of the particle-matrix interface, and a model based on an increased meansquare displacement of the interfacial layer. The best agreement to the data is provided by modeling the interface as an inert layer of finite thickness, which does not participate in the phase transition.


Author(s):  
Karl Schulmeister ◽  
Bernhard Seiser ◽  
Florian Edthofer ◽  
David J. Lund

Author(s):  
A. S. Sharipov ◽  
◽  
B. I. Loukhovitski ◽  

The size-dependence of different physical properties of atomic clusters (by the example of binding energy, collision diameter, and static isotropic polarizability) is discussed.


2014 ◽  
Vol 56 (12) ◽  
pp. 2369-2373 ◽  
Author(s):  
V. M. Samsonov ◽  
S. A. Vasilyev ◽  
A. G. Bembel ◽  
T. E. Samsonov ◽  
V. L. Skopich

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