Preparation and Characterization of Planar-Type ZnO Powder with High Aspect Ratio for Application in Ultraviolet- and Heat-Shield Cosmetics

2021 ◽  
Vol 21 (3) ◽  
pp. 1897-1903
Author(s):  
Jung-Hwan Lee ◽  
Gun-Sub Lee ◽  
Eung-Nam Park ◽  
Sung-Eun Hong ◽  
Sung-Bong Kye ◽  
...  

In this study, a [0001]-plane planar-type ZnO ceramic powder material with a high aspect ratio ranging from 20:1–50:1 is synthesized using the electrolyte collected from zinc air battery power generation. This high aspect ratio may be due to the Zn(OH)2-4 anion dissolved in the electrolyte. The obtained planar-type ZnO exhibits excellent formulation stability and applicability, even when formulated as a cosmetic with a single inorganic ingredient. Compared to commercial ZnO or TiO2 powders, relatively better protection against infrared and ultraviolet (UV) radiation is realized due to its asymmetric characteristics, with a width of approximately 1 μm and thickness of tens of nm. The synthesized planar-type ZnO is mixed with nanosized ZnO or TiO2 commercial powders and formulated into various combinations to achieve a high UV protection rate and heat-blocking effect. In particular, the addition of planar-type ZnO to nanosized TiO2 powders increases the heat-blocking effect, and improves the applicability and formulation stability of the cosmetic formulation, despite the decrease in turbidity. Among all the ceramic powder combinations examined in this study, the best UV protection rate and heat-blocking effect are obtained when the synthesized planar-type ZnO is mixed with microsized and nanosized TiO2.

2012 ◽  
Vol 22 (5) ◽  
pp. 055021 ◽  
Author(s):  
Pradeep Dixit ◽  
Tapani Vehmas ◽  
Sami Vähänen ◽  
Philippe Monnoyer ◽  
Kimmo Henttinen

2015 ◽  
Vol 54 (32) ◽  
pp. 9422 ◽  
Author(s):  
Nojan Motamedi ◽  
Salman Karbasi ◽  
Joseph E. Ford ◽  
Vitaliy Lomakin

2010 ◽  
Vol 2010 (1) ◽  
pp. 000703-000706
Author(s):  
Colin Stevens ◽  
Robert Dean ◽  
Samuel Lawrence ◽  
Lee Levine

The Bosch Deep Reactive Ion Etch Process is commonly used for the manufacture of MEMS and MOEMS devices that require deep high aspect ratio trenches. In many cases fully released, high aspect ratio features can be generated in one pass. However the process must be understood to avoid generating some of the defect structures that are characteristic of the process. Defects such as scalloping, silicon grass, and undercutting at the interface of a nonconductive layer can be controlled by process parameters and optimization. Measurement and characterization of the defective structures is a key element of controlling them. The use of SEM measurement techniques for characterizing the small features associated with scalloping and silicon grass is essential. No other technique is capable of providing the large depth of focus required to visualize these features. The use of metallographic techniques furthers understanding of the surface conditions on the side walls of these deep trenches.


Micromachines ◽  
2020 ◽  
Vol 11 (4) ◽  
pp. 378 ◽  
Author(s):  
Hailiang Li ◽  
Changqing Xie

We report a robust, sidewall transfer metal assistant chemical etching scheme for fabricating Al2O3 nanotube arrays with an ultra-high aspect ratio. Electron beam lithography followed by low-temperature Au metal assisted chemical etching (MacEtch) is used to pattern high resolution, high aspect ratio, and vertical silicon nanostructures, used as a template. This template is subsequently transferred by an atomic layer deposition of the Al2O3 layer, followed by an annealing process, anisotropic dry etching of the Al2O3 layer, and a sacrificial silicon template. The process and characterization of the Al2O3 nanotube arrays are discussed in detail. Vertical Al2O3 nanotube arrays with line widths as small as 50 nm, heights of up to 21 μm, and aspect ratios up to 420:1 are fabricated on top of a silicon substrate. More importantly, such a sidewall transfer MacEtch approach is compatible with well-established silicon planar processes, and has the benefits of having a fully controllable linewidth and height, high reproducibility, and flexible design, making it attractive for a broad range of practical applications.


2006 ◽  
Vol 179 (3) ◽  
pp. 708-715 ◽  
Author(s):  
Qi Tao ◽  
Yuanming Zhang ◽  
Xiang Zhang ◽  
Peng Yuan ◽  
Hongping He

2007 ◽  
Vol 26-28 ◽  
pp. 601-607 ◽  
Author(s):  
Z.J. Wang ◽  
S.C. Qu ◽  
Y. Xu ◽  
Y.H. Chen ◽  
X.B. Zeng ◽  
...  

Orthorhombic Bi2S3 (bismuthinite) nanorods and nanowires were synthesized by the solventless thermolysis of bismuth alkylthiolate precursors. Reactions producing high aspect ratio nanowires were carried out in air at 225°C with the presence of a capping ligand species, octanoate. Nanorods with a lower aspect ratio were produced by the same approach with the addition of elemental sulfur at a lower temperature (~160°C). Current density –Voltage characterization of the devices under illumination with 500 W Xenon lamp showed the photovoltaic performance. Both the nanorods and the nanowires hybrid with the polymer show the improved photovoltaic performance than polymer only. As far as we know, we are the first to apply Bi2S3 nanorods and nanowires to solar cells with the structure of ITO/PEDOT:PSS/MDMO-PPV:Bi2S3/Al.


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