Mineralogical and geochemical characterization of palygorskite from Gabasa (NE Spain). Evidence of a detrital precursor

Clay Minerals ◽  
1996 ◽  
Vol 31 (1) ◽  
pp. 33-44 ◽  
Author(s):  
A. Lopez-Galindo ◽  
A. Ben Aboud ◽  
P. Fenoll Hach-Ali ◽  
J. Casas Ruiz
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Statistical Analysis ◽  
Geochemical Data ◽  
Geochemical Characterization ◽  
Early Oligocene ◽  
Geochemical Study ◽  
Playa Lake ◽  
Ne Spain

AbstractA mineralogical and geochemical study of the Gabasa outcrop (Huesca, NE Spain) was undertaken. It consists of Early Oligocene marly and clayey fluvial and lacustrine (playa-lake) sediments. The phases detected were quartz, amorphous silica, calcite, dolomite, palygorskite, illite, interstratified illite-smectite, Al-smectite and Mg-smectite. The palygorskite expands with ethyleneglycol. Statistical analysis of the geochemical data shows that the rare earth elements and transition trace elements are basically associated with the detrital phyllosilicates, although a considerable amount of the latter is contained in the palygorskite (ΣREE = 60–70 ppm, Cr+Co+Ni+V+Zn+Cu = 120–150 ppm), in contrast to the normally low values for neoformed minerals. This fact, together with the significant presence of Al and Fe in the palygorskite, suggest genesis involving alteration by dissolution of the 2:1 structure of the illite and/or Al-smectite, followed by re-ordering in a fibrous structure.

scholarly journals The distribution of the trace element contents in lignite and ash from Drama lignite deposit, using multivariate statistical analysis

2001 ◽  
Vol 34 (3) ◽  
pp. 1255
Author(s):  
S. PANILAS ◽  
G. HATZIYANNIS
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Statistical Analysis ◽  
Rare Earth Elements ◽  
Multivariate Statistical Analysis ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Geochemical Data ◽  
Multivariate Statistical ◽  
Inorganic Matter

Multivariate statistical analysis was used on existing geochemical data of the Drama lignite deposit, eastern Macedonia, Greece. Factor analysis with varimax rotation technique was applied to study the distribution of major, trace and rare earth elements in the lignite and 850°C lignitic ash, to find a small set of factors that could explain most of the geochemical variability. The study showed that major elements AI, Na, Κ, contained in the lignite samples, presented high correlation with most of the trace and rare earth elements. In 850°C lignitic ashes major and trace elements present different redistribution. Only Al remained correlated with the trace elements Co, Cr, Rb, Ta, Th, Ti, Sc and rare earths related with inorganic matter in the lignite beds. Trace elements Fe, Mo, U, V, W, and Lu were associated with organic matter of lignite and had also been affected by the depositional environment.

Preliminary characteristics of rare earth elements and other trace elements in fine-grained deposits from the Triassic-Jurassic transition in the former Mid-Polish Trough

2018 ◽  
Vol 472 (472) ◽  
pp. 255-270
Author(s):  
Paweł BRAŃSKI
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Raw Material ◽  
Geochemical Data ◽  
Fine Grained ◽  
Geochemical Study ◽  
Icp Ms ◽  
The Subject ◽  
Siliciclastic Rocks

Fine-grained siliciclastic rocks from the Triassic-Jurassic transition (Rhaetian–Hettangian) in the former Mid-Polish Trough were the subject of the geochemical study at the Polish Geological Institute – National Research Institute in Warsaw. Ninety-four samples of claystones and mudstones from six archived drill cores were analysed by ICP-MS and XRF for rare earth elements (REE) and other trace elements. The results indicate that the sources of most of the claystones and mudstones were sedimentary rocks of the upper continental crust of old cratonic areas, where the protolith had a moderately felsic character. Weathering and recycling processes modified the original chemical composition to some extent. However, during Rhaetian and early Hettangian, some geochemical data in the south-eastern segment of the MPT suggest significant input from a mafic volcanic protolith. Moreover, a clear enrichment in rare-earth elements was observed in few samples, caused by admixtures of accessory minerals (being a main carrier of REE). Nevertheless, based on currently obtained data, the Rhaetian–Hettangian concentrations of REE (and other trace elements) in the MPT are low and they are of scientific indicative significance, not of raw material importance.

Geochemical characterization of hydrocarbon source rocks of the Triassic-Jurassic time interval in the Mandawa basin, southern Tanzania: Implications for petroleum generation potential

2020 ◽  
Vol 123 (4) ◽  
pp. 587-596
Author(s):  
A. Emanuel ◽  
C.H. Kasanzu ◽  
M. Kagya
Keyword(s):  
Source Rocks ◽  
Geochemical Data ◽  
Time Interval ◽  
Type I ◽  
Hydrocarbon Generation ◽  
Type Ii ◽  
Geochemical Characterization ◽  
Type Iii ◽  
Petroleum Generation

Abstract Triassic to mid-Jurassic core samples of the Mandawa basin, southern Tanzania (western coast of the Indian Ocean), were geochemically analyzed in order to constrain source rock potentials and petroleum generation prospects of different stratigraphic formations within the coastal basin complex. The samples were collected from the Mihambia, Mbuo and Nondwa Formations in the basin. Geochemical characterization of source rocks intersected in exploration wells drilled between 503 to 4042 m below surface yielded highly variable organic matter contents (TOC) rated between fair and very good potential source rocks (0.5 to 8.7 wt%; mean ca. 2.3 wt%). Based on bulk geochemical data obtained in this study, the Mandawa source rocks are mainly Type I, Type II, Type III, mixed Types II/III and Type IV kerogens, with a predominance of Type II, Type III and mixed Type II/III. Based on pyrolysis data (Tmax 417 to 473oC; PI = 0.02 to 0.47; highly variable HI = 13 to 1 000 mg/gTOC; OI = 16 to 225 mg/g; and VR values of between 0.24 to 0.95% Ro) we suggest that the Triassic Mbuo Formation and possibly the mid-Jurassic Mihambia Formation have a higher potential for hydrocarbon generation than the Nondwa Formation as they are relatively thermally mature.

scholarly journals Natural Enrichment of Trace Elements in Surface Horizons of Calcareous Soils (La Mancha, Spain)

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Sandra Bravo Martín-Consuegra ◽  
Jose A. Amorós Ortíz-Villajos ◽  
Caridad Pérez-de-los-Reyes ◽  
Francisco J. García Navarro ◽  
Rolando Ruedas Luna ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Calcareous Soils ◽  
Major And Trace Elements ◽  
Soil Profiles ◽  
Geochemical Characterization ◽  
Average Value ◽  
La Mancha ◽  
Original Rock

The study of five soil profiles developed on carbonatic sediments of Tertiary Miocene origin has been carried out. The topography of the area was basically flat and the traditional uses of the soils are the cultivation of dry cereals and grapevine. The geochemical characterization of the aforementioned profiles involves a study of the contents of major and trace elements among other pedologic aspects (texture, pH, organic matter, etc.). The results of this study also indicate a superficial enrichment of trace elements due to the leaching of Ca and moderate biological and anthropic activity. We can consider strontium, Sr, as the trace element that characterizes these limy soils (435 mg/kg average content in total soil and 708 mg/kg in the original rock). These contents are similar to the average value in Castilla-La Mancha of 380 mg/kg and are higher than the average in world soils of about 200 mg/kg. High levels of dangerous or pollutant elements (Cd, Hg, Pb, Cu, Zn, or Ni) were not detected. The majority of trace element anomalies are related to calcareous material and the leaching of calcium carbonate (Ca), while the influence of the anthropogenic factor is secondary. Soil quality does not indicate toxicity although surficial enrichment suggests a weak threat from consuming crops.

Geochemical characterization of sedimentary basins by statistical analysis: The Mio-Pliocene sequences of the Vera Basin, SE Spain

1994 ◽  
Vol 116 (3-4) ◽  
pp. 229-243 ◽  
Author(s):  
Angel Sánchez Bellón ◽  
Christine Mosser ◽  
Claude Roquin ◽  
Eduardo Sebastián Pardo
Keyword(s):  
Statistical Analysis ◽  
Sedimentary Basins ◽  
Se Spain ◽  
Geochemical Characterization

Science and Sensitivity: A Geochemical Characterization of the Mauna Kea Adze Quarry Complex, Hawai'I Island, Hawaii

2008 ◽  
Vol 73 (4) ◽  
pp. 743-758 ◽  
Author(s):  
Peter R. Mills ◽  
Steven P. Lundblad ◽  
Jacob G. Smith ◽  
Patrick C. McCoy ◽  
Sean P. Naleimaile
Keyword(s):  
Geochemical Data ◽  
Geological Samples ◽  
Sacred Landscape ◽  
Geochemical Characterization ◽  
Provenance Studies ◽  
The Pacific ◽  
Extreme Altitude ◽  
Geochemical Variation ◽  
Summit Region

The Mauna Kea Adze Quarry Complex is the largest-known prehistoric quarry in the Pacific Basin. The main extraction areas are located at an extreme altitude (3,800 m), near the summit of Hawaii's tallest mountain. The Mauna Kea summit region and the quarry are considered by many Hawaiians to be a sacred landscape and archaeologists must consider the ethical tensions involved in conducting Western science in these areas. Although provenance studies of basalt adzes are integral to the examination of pre-contact Hawaiian economics, former studies of Hawaiian adze distribution have been limited in scope, and conventionally relied on destructive petrography and petrology for the analyses. Published geochemical data on the quarry are derived from only eight samples analyzed with destructive methods. In order to better define the variation within the quarry, and to develop a more culturally sensitive approach, we employed nondestructive energy dispersive X-ray fluorescence (EDXRF) of whole-rock samples to characterize 820 flakes and 47 geological samples from the quarry complex. This study offers the first reliable estimation of the overall range of geochemical variability in the complex. These results suggest that nondestructive EDXRF can be used to differentiate Mauna Kea basalts from other known Hawaiian quarries, but more characterization of other quarries is necessary to confirm exclusive separation of sources. The results further demonstrate that EDXRF is capable of detecting intra-site geochemical variation in Mauna Kea quarry material.

scholarly journals Supplemental Material: LA-ICP-MS U-Pb dating and geochemical characterization of oil inclusion-bearing calcite cements: Constraints on primary oil migration in lacustrine mudstone source rocks

2021 ◽  
Author(s):  
Ao Su ◽  
et al.
Keyword(s):  
Rare Earth ◽  
Rare Earth Element ◽  
Earth Element ◽  
Source Rocks ◽  
Oil Migration ◽  
Geochemical Characterization ◽  
Icp Ms

Table S1: LA-ICP-MS U-Pb contents (ppm), and 238U/206Pb-207Pb/206Pb ratios of the microcrystalline-granular calcite (MGC) and blocky calcite (BC) in vein samples FSX1-1 and FSX1-2; Table S2: LA-ICP-MS rare earth element (REE) data (ppm) for calcite cements in vein samples FSX1-1 and FSX1-2.

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