On the diathermancy of Antimonite

Author(s):  
A. Hutchinson

A determination of the constants of elliptic polarization of light reflected from a fresh cleavage surface of antimonite enabled Professor P. Drude to calculate two of the indices of refraction of this substance as 5.17 and 4.49 respectively. Instead, however, of the symmetry-axes of the crystal, regarded as belonging to the orthorhombic system, coinciding with the principal vibration directions in the plane (010), he found that the latter were inclined to the former lines at angles which varied in different observations between 2.6° and 15.4°. These observations, which indicate that the symmetry of antimonite is of the oblique or anorthie type, stand in opposition to those of Professor O. Mügge, who found that exceedingly thin flakes of antimonite placed between crossed nicols in direct sunlight transmitted sufficient light of a deep red colour to enable him to determine the extinction as straight.

This paper contains an experimental investigation of the phenomena of elliptic polarization resulting from the reflexion of polarized light from metallic surfaces, and the theory on which they are explicable; the analytical results being given in a tabular form, and applied to the cases of the experiments themselves.


1845 ◽  
Vol 135 ◽  
pp. 269-282 ◽  

In a former paper, inserted in the Philosophical transactions, 1843, Part I., I detailed observations on some phenomena of elliptic polarization by reflexion from certain metallic surfaces; but with reference only to one class of comparative results. From these I have been led to pursue the subject into other relations besides those at first contemplated; but, from various causes, have only been able tat this interval to submit to the results to the Royal Society as a sequel to my former observations. The changes in the degree of ellipticity, investigated in my former paper, correspond to certain changes in the thickness of metallic films . If we now consider the case of reflexion from a simple polished metallic surface , and admit that in this case it may be supposed to take place by the penetration of the ray to a certain minute depth, or to some action of a thin transparent lamina of the metal, then, in like manner, —dependent on the law of metallic retardation, —the effect would vary with a difference in the effective thickness of the lamina, produced by changing the inclination of the incident ray; and that this is the case in general is well known, viz. that as the incidence is increased, the ellipticity increases up to a maximum, which occurs for most metals at an incidence between 70° and 80°, beyond which it decreases up to 90°.


1843 ◽  
Vol 133 ◽  
pp. 35-43 ◽  

The peculiar character impressed on light, originally polarized in a plane inclined to that of incidence and reflected from a metallic surface, discovered by Sir D. Brewster, and named by him elliptic polarization, has been since shown to coincide with what, from a different analogy, is termed elliptic polarization in the undulatory theory ; and which is also exhibited by an interposed plate of mica, or by total internal reflexion, as in Fresnel’s rhomb. The most distinct experimental test of the existence of this property and a measure of its amount, is the well-known dislocation of the polarized rings, seen by a plate of calc-spar and a tourmaline, in light of this kind. And this, as in other similar cases, is represented theoretically by a formula for the intensity at any part of the plate, in the case of the rhomb , for circular polarization, as in Mr. Airy’s tract on the undula-tory theory (Art. 160.) ; and for elliptic , as in the same author’s paper on quartz. A general formula for the rings in light of all degrees of ellipticity, not restricted by the peculiar conditions of the rhomb , has not been hitherto published : but I am in­debted to Mr. Airy for the communication of such a formula, which will be given in the sequel, as leading to some remarkable applications.


In a former paper, published in the Philosophical Transactions for 1843, the author gave an account of the observations he had made on the phænomena of elliptic polarization by reflexion from certain metallic surfaces, but with reference only to one class of comparative results. He has since pursued the inquiry into other relations besides those at first contemplated, and the present paper is devoted to the details of these new observations, obtained by va­rying the inclination of the incident rays, and the position of the plane of analysation, and by employing different metals as the re­flecting surfaces. By the application of the undulatory theory of light to the circumstances of the experiments and the resulting phænomena, the law of metallic retardation is made the subject of ana­lytic investigation. A polariscope of peculiar construction, of which a description is given at the conclusion of the paper, was employed in the experiments: and tables are subjoined of the numerical re­sults of the observations.


1991 ◽  
Vol 6 (1) ◽  
pp. 28-30 ◽  
Author(s):  
Y. Laureiro ◽  
M.L. Veiga ◽  
M.L. López ◽  
S. García-Martín ◽  
A. Jerez ◽  
...  

AbstractCd3(BO3)2 was prepared by a solid state reaction between B(OH)3 and Cd(OH)2 at low temperatures ranging between 523° and 623° and at a pressure of 10−4 – 10−5 Hg mm. The crystal structure has been refined by Rietveld analysis of X-ray powder diffraction data. The compound crystallizes in the orthorhombic system, space group Pnnm, Z = 2, with cell parameters of a = 5.967(5) Å, b = 4.78 (0) Å and c = 9.009(5) Å.


The author, by way of introduction, passes in review the labours of various inquirers on the subject of the elliptic polarization of light, and notices more particularly those of Sir David Brewster, who first discovered this curious property, as recorded in the Philosophical Transactions for 1830; of Mr. Airy, in the Cambridge Transactions for 1831 and 1832; and of Professor Lloyd, in the Philosophical Transactions for 1840, and in the Reports of the British Association for 1841. He then proceeds to give an account of his own experimental examination of the phenomena of elliptic polarization in the reflection of light from various surfaces, by observing the modifications of the polarized rings under different conditions, both of surface and of incidence, and by endeavouring to ascertain both the existence and amount of ellipticity, as shown by the dislocation of those rings, and to determine its peculiar chataracter, as indicated by the direction in which the dislocation takes place; the protrusion of the alternate quadrants appearing it certain cases, in one direction, and in others in the opposite. These observations are reducible to two classes; first, those designed to contribute to the inquiry, what substances possess the property of elliptic polarization, by examining the light reflected from bodies; and second, those made on certain cases on of films of several kinds, including those formed on metals by oxidation or other action upon the metal itself, as well as by extraneous deposition. The author found the general result, in all these cases, to be, that from any one tint to another, through each entire order of tints, the form of the rings in the reflected light undergoes certain regular changes, passing from a dislocation in one direction to that in the opposite, through an intermediate point of no dislocation, or of plane polarization; and thus exhibiting a dark and a bright centred system alternately, as long as the order of tints are preserved pure. These changes in the form of the rings, he observes, are precisely those expressed by successive modifications of Mr. Airy's formula, corresponding to the increments in the retardation which belong to the periodical colours of the films. The remaining portion of the paper is occupied by a description of the apparatus and mode of conducting the experiments; and of the observations made on mica, on decomposed glass, plumbago, daguerreotype, and other metallic plates, and on the coloured films produced on steel and on copper by the action of heat, and of voltaic electricity. The author gives, in conclusion, an analytical investigation of Mr. Airy’s general formula.


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