Relation Between Concentrations of Polycyclic Aromatic Hydrocarbons, Grain Size, and Organic Matter Content in Lake Ketelmeer (The Netherlands)

1998 ◽  
Vol 62A (1) ◽  
pp. 95-95
Author(s):  
A. A. Bakker
Keyword(s):  
Grain Size ◽  
Organic Matter ◽  
Polycyclic Aromatic Hydrocarbons ◽  
The Netherlands ◽  
Aromatic Hydrocarbons ◽  
Organic Matter Content ◽  
Matter Content ◽  
Polycyclic Aromatic

Multivariate tools to investigate the occurrence of pollutants in a highly anthropised marine area

2020 ◽  
Author(s):  
francesco paolo buonocunto ◽  
nicola cardellicchio ◽  
antonella di leo ◽  
eliana esposito ◽  
luciana ferraro ◽  
...  
Keyword(s):  
Organic Matter ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Organic Matter Content ◽  
Tyrrhenian Sea ◽  
Deep Dive ◽  
Campania Region ◽  
Gulf Of Naples ◽  
Polycyclic Aromatic ◽  
Sarno River

<p>Environmental monitoring of highly anthropised areas demands for deep survey of different environmental compartments (water, sediment, soil and biota) and determination of numerous bio-geo-chemical parameters, due to the huge impact of natural and anthropogenic organic substances constantly released into these environments. However, the interpretation of the large amount of data is not straightforward task due to their complexity that require a very tricky elaboration especially for the decision making processes. Chemo-metrics tools based on the multivariate statistical data analysis seems to be a powerful tool in addressing such complexity (Mali et al., 2017). In this work they are performed to get insight the occurrence of organic pollutants within a highly populated area such as the Gulf of Naples.</p><p>The Gulfs of Naples, located along the Eastern Tyrrhenian Sea, is semi-enclosed by the Ischia-Procida Islands to NW, Campi Flegrei and the Campanian Plain in NE, the Sorrento peninsula in SE, and Capri island in W. The Campania region has one of the highest population densities in Italy. The Gulfs of Naples are the receiving environment for persistent toxic substances from the Campania Plain (Albanese et al., 2010; Arienzo et al., 2017). Montuori and Triassi (2012) reported that the discharges of PAHs from the Sarno River to the Gulf of Naples is approximately 8530 g/d. The main goal of this work is to establish the influence of the Campania Plain on the present sedimentation in the Naples bay continental shelf by evaluating organic matter contribution and pollution. For this purpose, superficial sediment samples collected from 158 sites located offshore the Gulf of Naples between Sarno River and Capri Island, were analyzed for total nitrogen and phosphorus, total organic carbon (TOC), grain size, metals, priority polycyclic aromatic hydrocarbons (PAHs), total petroleum hydrocarbon (TPHs), volatile organic compounds (VOCs), polychlorinated biphenyls (PCBs), pesticides and organotin compounds (OTs). The adopted multivariate approach allowed, through a clear spatial representation of score plots, a deep dive into the large dataset generated by the investigation campaign, highlighting the influence of some main factors controlling the contamination pattern, such as organic matter content and depositional environment.</p><p>References</p><p>Albanese, S., De Vivo, B., Lima, A., Cicchella, D., Civitillo, D., Cosenza, A., 2010. Geochemical baselines and risk assessment of the Bagnoli brownfield site coastal sea sediments (Naples, Italy). J. Geochem. Explor. 105, 19–33.</p><p>Arienzo, M., Donadio, C., Mangoni, O., Bolinesi, F., Stanislao, C., Trifuoggi, M., Toscanesi, M., Di Natale, G., Ferrara, L., 2017. Characterization and source apportionment of polycyclic aromatic hydrocarbons (pahs) in the sediments of gulf of Pozzuoli (Campania, Italy). Mar. Pollut. Bull. 124, 480–487.</p><p>Mali, M., Dell'Anna, M.M., Notarnicola, M., Damiani, L., Mastrorilli, P., 2017. Combining chemometric tools for assessing hazard sources and factors acting simultaneously in contaminated areas. Case study: "Mar Piccolo" Taranto (South Italy). Chemosphere 184, 784-794.</p><p>Montuori, P., Triassi, M., 2012. Polycyclic aromatic hydrocarbons loads into the Mediterranean Sea: estimate of Sarno River inputs. Mar. Pollut. Bull. 64, 512–520.</p>

The influence of particle size and structure on the sorption and oxidation behaviour of birnessite: II. Adsorption and oxidation of four polycyclic aromatic hydrocarbons

2014 ◽  
Vol 11 (3) ◽  
pp. 279 ◽  
Author(s):  
Mario Villalobos ◽  
Manuel Carrillo-Cárdenas ◽  
Richard Gibson ◽  
N. Ruth López-Santiago ◽  
Jimmy A. Morales
Keyword(s):  
Particle Size ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Manganese Oxides ◽  
Organic Matter Content ◽  
Matter Content ◽  
Particle Sizes ◽  
Oxidation Reactions ◽  
Deep Aquifers ◽  
Polycyclic Aromatic

Environmental context Sorption and oxidation reactions at mineral surfaces can substantially influence the mobility and toxicity of environmental contaminants. An understanding of the factors that control these reactions is crucial for predicting the fate of contaminant species. We investigate the reactivity of manganese oxides towards polycyclic aromatic hydrocarbons, persistent organic compounds of environmental concern. Abstract Birnessites are ubiquitous components of natural systems and may exert a significant influence on the mobility and toxicity of different types of contaminants, including organic species. Their small particle sizes and internal structure provide them with high sorption capacities and oxidising abilities for redox sensitive species. In the present work, the interactions of two MnIV birnessites (δ-MnO2 and acid birnessite) of different particle sizes and layer vacancy contents were investigated with four hydrophobic polycyclic aromatic hydrocarbons (PAHs) of three and four rings. Fluorene and anthracene were oxidised to produce the corresponding and less toxic quinones by both birnessites, but at a higher rate and extent by δ-MnO2. Phenanthrene and fluoranthene only adsorbed to δ-MnO2 but not to acid birnessite. The higher reactivity of δ-MnO2 is only partly explained by its higher specific surface area (114 v. 39m2g–1), i.e. by its smaller particle size. The repulsive effect of water molecules from hydrated cations sorbed on layer vacant sites is most likely decisive, because acid birnessite shows a considerably larger content of these vacancies. The results presented provide a fundamental understanding of the potential influence of birnessite minerals on the attenuation of low molecular weight PAHs in environments with low organic matter content, such as deep aquifers.

Grain size distribution of metals and polycyclic aromatic hydrocarbons in silt trap sediments from the combined sewer network of Paris (France)

2005 ◽  
Vol 52 (3) ◽  
pp. 111-118 ◽  
Author(s):  
R. Moilleron ◽  
J. Perez ◽  
S. Garnaud
Keyword(s):  
Heavy Metals ◽  
Grain Size ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Size Distribution ◽  
Grain Size Distribution ◽  
Aromatic Hydrocarbons ◽  
Sediment Samples ◽  
Sewer Network ◽  
Combined Sewer ◽  
Polycyclic Aromatic

For three years (2001–2003), sediment samples were extracted from about 100 silt traps (STs) spread out all over the combined sewer network of Paris. These STs, whose volume varied from 21 to 325 m3, were cleaned out as soon as their filling capacities were reached. All these sediment samples were analysed for physicochemical parameters (pH, organic matter (OM) content, grain size distribution), total hydrocarbons (THs), 16 polycyclic aromatic hydrocarbons (PAHs) selected from the priority list of the US-EPA, and heavy metals (Al, Ag, As, Cd, Cu, Cr, Sn, Fe, Mn, Hg, Ni, Pb, Zn). For each silt trap, six sediment samples were extracted before the clean out procedure: three samples were extracted from the sediment surface (5–10 cm depth) and three other samples were extracted from a deeper sediment layer (approximately at 1 m depth). The location of these sampling points allowed us to take into account the possible spatial fluctuation of pollutant loads in each ST. The first results showed that there were some important inter-site variations of pollutant contents. These variations have to be taken into account by the sewer manager for the fate of the ST sediments. Therefore, we decided to assess the grain size distribution of some pollutants. OM, heavy metals and PAHs have been investigated on the five grain size fractions (>20 mm, 8–20 mm, 0.5–8 mm, 50–500 μm, <50 μm) for 9 STs, which have been selected on their heavy metal content basis. This work aims at understanding the distribution of the pollutant contents and at improving the knowledge of the ST sediment pollution.

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